Multimode Interference Couplers with Different Background Refractive Index *

A novel structure of MMI coupler with different background refractive index has been designed. With stronger optical confinement in multimode waveguides, more guided modes are excited to improve imaging quality. Two-dimensional finite difference beam propagation method (2-D FDBPM) was used to simulate this new structure and had proven that its imaging quality, in terms of power uniformity and excess loss, is much better than conventional structure. This structure can be applied in SOI rib waveguides by deep etching method.

Optical analysis of AlGaInP laser diodes with real refractive index guided self-aligned structure

Optical modes of AlGaInP laser diodes with real refractive index guided self-aligned (RISA) structure were analyzed theoretically on the basis of two-dimension semivectorial finite-difference methods (SV-FDMs) and the computed simulation results were presented. The eigenvalue and eigenfunction of this two-dimension waveguide were obtained and the dependence of the confinement factor and beam divergence angles in the direction of parallel and perpendicular to the pn junction on the structure parameters such as the number of quantum wells, the Al composition of the cladding layers, the ridge width, the waveguide thickness and the residual thickness of the upper P-cladding layer were investigated. The results can provide optimized structure parameters and help us design and fabricate high performance AlGaInP laser diodes with a low beam aspect ratio required for optical storage applications.

基于RS和GIS的四川省土地利用/覆盖变化及可持续利用研究

LUCC是全球变化研究的核心主题之一，也是社会经济可持续发展的关键问题。改革开放后四川的社会经济发展非常快，在各种因素的驱动下，土地利用/覆盖发生了深刻变化。目前四川省缺乏基于实际调查数据的、全域性的、具有连续时间序列的LUCC和驱动力分析及土地可持续利用研究成果，这对我们从全局上把握全省土地利用现状、发展变化趋势，利用土地政策参与宏观调控，实现长期可持续发展目标，建设资源节约型、环境友好型社会极为不利。本研究针对这一问题，选取全川八大土地利用类型作为研究对象，研究了全省1996年到2006年的土地利用/覆盖格局和变化情况，分析了不同尺度的驱动因素，对全省农用地和建设用地的集约利用状况、潜力进行了分析评价，并提出相应的对策措施。 1．1996年-2006年10年来整个省域的土地利用/覆盖格局变化。 （1）1996年-2006年全省的土地利用/覆盖格局 1996年，全省是一个以农用地为主的土地利用/覆盖格局，林地和牧草地属于优势覆盖类型（合占69.17%），居民点及工矿用地和交通用地合占只有3%左右。 2000年的LUCC格局较为明显的特点是耕地所占比重下降0.4个百分点，水域和未利用土地所占比重有所下降，牧草地保持不变，其余地类所占比重有所上升。 与2000年相比，2004年林草地的优势格局进一步得到强化（合占比重达到70.23%）。耕地面积占幅员面积的比重下降0.83个百分点，略有下降的有未利用土地、水域和牧草地。值得关注的是在“退耕还林还草”的大背景下，牧草地占幅员面积的比重下降0.04个百分点。 到2006年，仍为林草地为主导优势的格局，二者合占上升0.15%。在城市化快速推进的背景下，居民点及工矿用地中的城市用地和建制镇用地占比重超过15%，农村居民点占比重降至76%。交通用地中农村道路占比重降至57.8%,公路用地占比重升至37.5%。五个地貌区的土地利用/覆盖格局与全省的变化基本一致。值得关注的是盆西平原区的交通用地上升幅度和盆地丘陵区的未利用土地的开发利用力度明显大于其它地貌区。 （2）1996-2006年10年间土地利用/覆盖格局的变化 1996-2000年4年间，耕地、水域和未利用地三个地类下降，年均减少0.75、0.19和0.32个百分点。其中耕地年均减少49229.0公顷，约一半流向林地，13.77%流向园地，约20%流向建设用地。另外5个地类面积增长，增长绝对量最大的是林地，年均增长40063.7公顷，交通用地增幅最大，4年年均增长达1.95%。 2001-2004年是西部大开发逐步推进、“退耕还林还草”项目全面展开和土地整理深入实施的关键期，LUCC更为深刻。耕地、未利用地、水域和牧草地四个地类面积下降，其余地类按增长幅度依次是园地、交通用地、居民点及工矿用地和林地。耕地加速下降，年均降幅达到1.59%，其减少去向主要是林地（占66.75%）和园地（占19.84%），其增加来源主要是未利用地、园地和水域。交通用地的增幅最大，为3.96%,其增加主要来源于耕地、未利用土地和林地，分别占49.96%、16.63%和13.09%。居民点及工矿用地增长幅度为3.12%。 从1996年到2006年的10年间，耕地、未利用地、水域和牧草地下降幅度分别为10.36%、3.61%、1.34%和0.26%。园地增幅达23.61%。绝对面积增长最大的则是林地，达630733.3公顷。交通用地和居民点及工矿用地增幅也较大，分别为15.00%和9.31%。 10年间年均总变化量为310326.6公顷，2000年-2004年之间变化最大（为356865.8公顷），高于平均变化量，而1996-2000年间和2004-2006年间都小于平均变化量。 （3）10年间不同地貌区的LUCC变化 盆西平原区的特点是园地大幅上升达77%，居民点及工矿用地和交通用地也大幅上升，耕地、未利用地下降幅度大，该区耕地、水域、未利用地的减少强度和园地、居民点及工矿用地、交通用地的上升强度均居五区第一；盆地丘陵区的特点是牧草地下降幅度大，为-36.89%,交通用地、园地和林地上升幅度较大，该区耕地减少、未利用地减少、林地增加、居民点及工矿用地和交通用地增加的变化强度均居五区相应地类增减的第二位；盆周山地区的特点是耕地减少较多，交通用地和园地增长较大，该区林地变化强度居各区第一位，牧草地和水域变化强度居各区第二位，耕地、居民点及工矿用地和未利用地居各区第三位；川西南山地区的特点是园地、耕地、交通用地和居民点及工矿用地变化幅度大，另外四个地类变化较小。该区减少的牧草地占全省牧草地减少的97.91%，变化强度居各个地貌区的第一位，园地相对变化强度居五区的第二位；川西北高山高原区的特点是耕地大幅下降、园地大幅上升，交通用地升幅也较大，其余地类变化不大。值得注意的是，该区牧草地和水域面积增加，与全省该地类的变化相反。其余地类的相对变化强度均是五个地貌区中最小的。 用变化强度分值考量变化强度，盆西平原区的变化强度最大，盆地丘陵区和盆周山地区的变化强度相当，川西北高山高原区的变化强度则要小得多。 （4）1996年及2006年全省土地利用/覆盖格局的景观生态学分析 全省是以自然景观占优势（占约70%）、农业景观为补充、建设用地景观居于从属地位的土地利用景观格局。景观多样性和均匀度不高。到2006年，全省总的景观格局并无大的改变。总体情况是随着时间的推移和人类活动的加强，区内景观优势度上升、多样性和均匀度变小。但斑块数减少，斑块面积和斑块孔隙度有所增大。斑块的形状指数和分维数均有所下降，表明受人为干扰有加剧的趋势。反映景观格局结构的破碎度指数有轻微下降。景观指数的变化表明全省土地利用有缓慢集中、规模聚集的趋势。 （5）三大生态建设工程对土地利用/覆盖变化的影响 1996-2006年间LUCC与三大生态建设工程实施的耦合分析，发现退耕工程对耕地、林地、牧草地等地类覆盖变化的影响最大，天保工程次之，长防工程最小。 2.四川省LUCC驱动力分析 （1）总体分析： 从整体上分析，人为因素对区域整体LUCC的影响从1996年的63.32%增加到2006年的66.99%，变得日益强烈。同时人为因素影响强度表现出明显的区域差异，地势平缓、经济区位条件好的区域其人为影响强度明显较高。 政策体制转变下的经济高速增长、快速的城市化、工业化过程和生态建设是四川省LUCC宏观尺度的驱动因素。区域的LUCC主要受到了由内向外(从城市到乡村)和由外向内(从山顶向平地)两种作用力的共同推动。局部尺度上，如距离交通线、水利线、中心城市的远近，地形凸起、大型独立项目落址、重污染项目的阻隔等，甚至一些乡规民俗等因素也会成为LUCC的驱动影响因素。在较小的尺度上,人类个体行为选择对LUCC的影响也是存在的。 　　根据驱动因子的特性作者将其划分为驱变、阻变、良性、惰性因子等类型。 （2）分地貌区的驱动因子分析 各地貌区都存在城市化、工业化、生态工程实施、自然灾害等驱动因子，但主次不一。对于盆西平原和盆地丘陵区，城市化、工业化是前两位的因子，而对另外三个地貌区，生态工程实施和产业结构调整则成为第第一、二位的驱动因子。 （3）分地类的驱动因子分析（以坡耕地为例） 分坡度的耕地变化分析发现，耕地减少主要集中在2°以下的平地、15°-25°和25°以上三个坡度级，是其它坡度级耕地减幅的三倍左右。这表明耕地减少受城市化进程和“退耕还林还草”工程驱动影响尤为巨大。 3.土地利用格局优化、集约利用评价和可持续利用及对策研究 （1）土地利用格局优化的战略选择及调整预测 土地利用格局调整的战略是农业生产用地、建设用地和生态及其他用地占幅员的比重分别稳定在13%、7%和80%左右，重点是三大类别内部二级和三级地类的合理调整。 （2）全省土地集约利用评价 全省农用地利用集约度为0.46，总体上集约度不高，处于较适度利用阶段。建设用地利用集约度为0.38，处于较适度利用阶段。集约利用提升空间较大。 农用地的潜力主要在于加强土地保育、完善利用制度、提高单产。城市建设用地的包括存量潜力、强度潜力、结构潜力，空间很大。农村居民点整理潜力可以逐步挖掘。 （3）新增建设用地集约利用的统筹安排 据测算，到2020年，四川省城市建设用地需求量在463850-492360hm2之间，城镇各业新增建设用地规模为361276.79hm2，占用耕地200565.94 hm2。2004-2020年间四川省农村居民点整理潜力33.86万hm2。农村居民点建设用地需求量为70.57万公顷。 （4）土地集约利用措施与坡耕地可持续利用战略 提出了土地集约利用的措施。在对坡耕地生态系统结构与功能分析的基础上，提出坡耕地可持续利用战略与生态恢复战略，并从技术和政策层面提出了坡耕地合理利用和生态退耕的措施和建议。 LUCC is one of the key questions of global change and sustainable development of society. After the opening and reform of China, the society and economy of Sichuan Province developed very fast ,the land-use/cover changed very strong droved by many factors .But nowadays we have no constant spatial-temporal study and driving force analysis about the whole province based on investigation. And it is lack of land sustainable utilization study based on correlative study. So we choose all the land resource in Sichuan, combine RS and GIS and field investigation, and take statistic-mathematic means and system analysis, to study the LUCC patterns and different scale driving force of different physiognomy regions, land cover types and periods; to analyze the current situation and potential of land resource intensive utilization, and gave out corresponding measurements. We found that forest and grassland are the dominant cover types of Sichuan provincial land –use/cover pattern, and becoming more and more stronger from 1996 to 2006,the natural landscape is the metric and occupy 70%,the diversity and evenness index are not high; the totally change quantity from 2000 to 2004 is the biggest; cultivated land especially steep cultivated land ,garden plot, forestry land ,settlement and industry land and traffic land changed relative stronger; among five physiognomy regions ,the changing intensity of PEN XI PING YUAN QU is the biggest, CHUAN XI BEI GAO SHAN GAO QU is smallest; under the background of policy system changing, the fast developing of economy, fast urbanization and industrialization and ecology construction are the macro-scale driving force of Sichuan provincial LUCC; to compare the impacts of “TUI GENG GONG CHENG” on LUCC especially to cultivated land ,forestry land and grassland is strongest, “TIAN BAO GONG CHENG ” is stronger,“ HANG FANG GONG CHENG” is smallest; the intensive utilization level of farmland and construction land of whole province is relative moderation, there is huge potential to excavate and fulfill the increasing demand of construction land；we must take synthetic measurements to accelerate the sustainable utilization of land resource, including administrative, economical ,technological and ecological policies.

次生植被下土壤活性有机碳组分季节动态研究

为了揭示不同类型植被下土壤有机碳及其活性组分季节动态变化及其特点，探讨不同的植被恢复模式对土壤有机碳组分的影响，分析影响土壤有机碳组分变化的因素，评估土壤有机活性有机碳组分参数在植被恢复过程中土壤质量监测的可靠性，为植被恢复及低效林改造技术提供理论依据。本研究选择岷江上游大沟流域的几种人工林（云杉林、油松林、华山松林、日本落叶松林）以及次生落叶阔叶灌丛下土壤，通过剖面机械分层取样，测定土壤总有机碳（TOC）和三种活性碳组分微生物碳（SMBC）、水溶性碳（WSOC）、易氧化碳（EOC）等来反映土壤变化特点。主要结果是： 1. 土壤有机碳含量平均在15.48~25.46 g kg-1之间在5月份时含量最低，随生长季的开始，有机碳含量逐渐增加，到9月份时含量达到最大值；由于新形成的凋落物不能被迅速分解利用补充土壤碳库，而原有碳库经历一个生长季的分解利用，因此，生长季末期即11月份的含量较小；土壤微生物碳含量平均在132.78~476.73mg kg-1之间，9月份和11月份含量都比较高；水溶性碳在生长季中逐步增大，含量在51.95~77.18 mg kg-1之间，到11月份时达到最大值；土壤易氧化碳平均含量在3.74~5.79g kg-1之间，含量最低值出现在5月份，但和其他碳组分不同的是其在7月份时含量较高。 2. 土壤有机碳及其活性碳组分大小关系为：TOC>EOC >SMBC>WSOC；比值约为300：70：5：1。 3. 土壤不同层次间比较，土壤碳指标都表现为随土壤深度增加而逐渐减小, 表层积聚作用明显。 4. 对土壤总有机碳量与活性碳组分以及活性碳之间进行了相关分析表明，土壤总有机碳含量与土壤微生物量碳、水溶性碳、易氧化碳之间的相关性均达到显著水平（P<0.05），有机碳总贮量很大程度上制约着土壤活性碳组分。土壤微生物量碳、水溶性碳、易氧化碳两两之间也都存在着显著相关关系（P<0.05），并随着不同植被类型或立地条件因子发生变化而变化。 5. 土壤有机碳及其活性组分与土壤养分状况之间的相关性分析发现，随着海拔、坡向或者植被类型的改变，其林下土壤有机碳及其活性组分与土壤养分的相关性也发生较大的变化。总体而言，岷江上游地区海拔、坡向、土壤自然含水量、植被盖度、凋落物厚度、土壤全N对次生林下土壤有机碳及其组分有重要影响。而AP、AK、C/N对土壤碳变化变化影响较小。 6. 通过不同海拔、坡向以及植被类型之间的综合比较分析发现，土壤微生物碳SMBC和水溶性碳WSOC比TOC和EOC更能敏感地反映出比较敏感的指示林下土壤质量的变化。 In order to reveal seasonal dynamics of soil labile organic carbon under different secondary vegetation, to analyze effect of different vegetation restoration pattern on soil organic carbon and its fractions, and to find the factors influencing changes in soil organic carbon and its fractions, further to estimate those parameters reliability for soil quality monitoring in the process of vegetation restoration. Soils were selected from several plantations, including Picea asperata Pinus tabulaeformis, Pinus armandii and Larix kaempferi and secondary shrub in Dagou Watershed of the upper reach of Minjiang River. The measurement of TOC, SMBC，WSOC and EOC were made, because these parameters can reflect change of soil characteristics. The major results are: 1. There were the lowest soil organic carbon and its labile fractions contents in May. At the time of growth initiation, they increased gradually and reached maximum in September. After that the soil organic carbon content decreased. Because current litter couldn’t be rapidly decomposed, and supplemented into carbon pool, while intrinsic carbon pool experienced decomposition and utilization of growth season, Which led a decrease in soil organic carbon content in November. Average value was 15.48~25.46 g kg-1; average SMBC content was 132.78~476.73mg kg-1.There were higher SMBC content in September and November as compared with other times; Water soluble organic carbon content increased from 51.95 mg kg-1 in May to 77.18 mg kg-1 in November; EOC content was lowest in May y. Average value was 3.74~5.79g kg-1. Differeing from other parameters of carbon fractions, EOC content was higher in July. 2. The content of soil organic carbon and its labile carbon fractions ranked as follows：TOC>EOC >SMBC>WSO，and ratio was about 300：70：5：1. 3. Consider as soil different layers，all of the parameters decreased gradually with increasing soil depth, thus displayed a significant accumulation in the surface layer soil. 4. Correlations coefficient analysis revealed that, TOC significantly correlated with SMBC, WSOC and EOC indicating total storage of organic carbon limited soil labile carbon fractions in great extent. On the other hand, there were significant correlations between SMBC，WSOC and EOC. But these relationships changed with vegetation types and/or environmental conditions. 5. The relationships between soil organic carbon and its labile fractions and soil nutrient traits changed with altitude，slope aspect and vegetations. Therefore our results suggested that altitude，slope aspect，soil natural water content，vegetation coverage, litter thickness and soil total nitrogen play a important role change in soil organic carbon and its fractions in upper reaches of Minjiang River. While AP、AK、C/N slightly influenced soil carbon. 6. Our results, on the other hand suggested that SMBC and WSOC are more sensitive to the change of altitudes, slope aspects, vegetation types than TOC and EOC, thus two parameters may be good index reflecting change of soil quality. These results provide insights into theoretical and technological evidences for the vegetation regeneration restoration and improvement of low-quality and benefit forest in the upper reaches of Minjiang River regions.

菌剂强化处理炼油废水及苯酚冲击下功能菌响应机制研究

近年来，我国炼油行业发展迅速，炼油能力全世界第二，炼油行业已成为污染大户。本研究针对炼油废水生物处理中存在的稳定达标难、抗冲击负荷能力差、建设投资与运行成本高等问题，就菌剂强化处理炼油废水中试与工程应用展开了研究，以期为菌剂的工程应用与推广提供理论参考与技术支持；并以炼油废水中的主要特征污染物苯酚为研究对象，考察了不同浓度苯酚冲击下功能菌的响应机制，并以此为指导研制功能菌激活促进剂，考察其对功能菌生物学指标的调控效果，以期为废水生物处理有毒污染物冲击调控提供理论依据与技术支持。 中试研究表明，菌剂强化处理炼油废水，出水COD、NH4+-N 平均值为86.7、7.6 mg/L，其平均去除率较常规生物处理系统分别提高了35.47%、59.28%，其耐受COD、NH4+-N 容积负荷分别高达2.42、0.139kg/(m3·d)，具有良好的耐冲击能力。工程应用研究表明，菌剂强化处理炼油废水，出水COD、NH4+-N 平均值分别为85.05、8.4mg/L，其去除率较常规生物处理系统提高了25.1%、28.7%，出水水质各项指标均达到了国家《污水综合排放标准GB 8978-1996》一级排放标准。技术经济分析表明，菌剂强化处理炼油废水在建设成本、运行成本上分别降低38%、49%，具有良好的技术经济优势。 苯酚冲击下功能菌响应机制研究表明：不同浓度苯酚冲击下，生物学指标生物量、脱氢酶酶活、1,2-双加氧酶酶活对冲击都有不同程度的响应，其响应敏感程度为脱氢酶酶活＞生物量＞1,2-双加氧酶酶活。1,2-双加氧酶酶活与COD 降解率相关性良好，可表征苯酚降解过程，确认为调控重点。以此为指导研制出苯酚降解功能菌抗冲击激活促进剂，可有效调控功能菌对有毒污染物苯酚的降解效果，1000mg/L 苯酚冲击下，经调控，其COD 去除率较对照提高20%，降解时间缩短16%以上。其对生物学指标的调控效果为1,2-双加氧酶酶活＞生物量＞脱氢酶酶活，验证了功能菌在苯酚冲击下的响应机制。研究表明菌剂强化处理炼油废水切实可行，具有良好的技术经济优势。有毒污染物冲击下废水生物处理系统响应机制研究为抗冲击调控提供了新的研究思路。 Currently, China’s oil refining industry is developing rapidly and has become the second largest all over the world. The oil refining industry is one of the major pollution industries in our country. The pilot scale study and engineering application research were conducted aiming at the problems in refining wastewater such as poor treatment stability and water quality, poor anti-shock capacity and expensive running cost, etc., so as to provide theoretical references and technological supports for the engineering application and popularization of microbial preparation in wastewater treatment. Also, the response mechanism of functional microbe under shock of different phenol concentrations, which is the main pollutants in refinery wastewater, was studied. Based on this result, functional microbe activation accelerator was developed, and the regulation effect of functional microbe biological index under phenol shocking were studied, in order to provide theoretical basis and technological support for regulation of toxic shocking of wastewater biological treatment. The result of pilot scale research indicated: for treatment of refinery wastewater in bioaugmention treatment system of microbial preparation, the COD and NH4+-N average value of effluent was 86.7 and 7.6 mg/L, Comparing with normal biological treatment system, the average removal rates of COD, NH4+-N increased 35.47%,59.28% separately by bioaugmention treatment system, which showed better anti-shocking capacity, the volumetric load r of COD and NH4+-N reached 2.42 kg/(m3·d) and 0.139 kg/(m3·d), respectively. The research on engineering application of refinery wastewater bioaugmentation treatment by microbial preparation indicated:the average concentrations of effluent COD and NH4+-N in the bioaugmentation treatment system were 85.05 and 8.4mg/L, which increased by 25.1% and 28.7% comparing with normal biological treatment system of refinery wastewater, And the effluent quality meets the first grade of discharging standard of National Integrated Wastewater Discharge Standard GB 8978-1996. The economic analysis of technology indicated: the demonstration project of bioaugmentation treatment of refinery wastewater by microbial preparation decreased by 38% in construction cost and 49% in running cost. This technology has economic benefits. The response mechanism of functional microbe under phenol shock indicated: biological index such as the biomass concentration, dehydrogenase and 1,2-dioxygenase had different responses under phenol shocking of different concentrations. The response sensitivity of different biological index under phenol shocking of different concentrations is: dehydogenase activity ＞ biomass ＞1,2-dioxygenase activity, and high correlation of 1,2-dioxygenase and COD degradation percentage is achieved, thus 1,2-dioxygenase could be used to reflect the degradation situation of pollutants. So, 1,2-dioxygenase is the keypoint of regulation. The anti-shock activation accelerator of phenol degradation functional microbe was primarily developed. The results indicated: the activation accelerator could regulate the degradation effect of toxic substance-phenol by functional microbe effectively. For the functional microbe treatment system under phenol shocking of 1000mg/L, the COD degradation rate increased by 20% and the degradation time reduced by more than 16% under regulation of activation accelerator. The regulation effects of biological index are: 1,2-dioxygenase ＞ biomass ＞ dehydrogenase. In this way, the response mechanism of functional microbe under toxic shocking is verified. The result indicated: the augmented microbial preparation treatment of refinery wastewater is applicable. It has many technical and economical advantages. The research results of responses mechanism of wastewater treatment system on toxic pollutants would offer a new idea for regulation of anti-shock.

Radiation-use efficiency and the harvest index of winter wheat at different nitrogen levels and their relationships to canopy spectral reflectance

Radiation-use efficiency (RUE, g/MJ) and the harvest index (HI, unitless) are two helpful characteristics in interpreting crop response to environmental and climatic changes. They are also increasingly important for accurate crop yield simulation, but they are affected by various environmental factors. In this study, the RUE and HI of winter wheat and their relationships to canopy spectral reflectance were investigated based on the massive field measurements of five nitrogen (N) treatments. Crop production can be separated into light interception and RUE. The results indicated that during a long period of slow growth from emergence to regreening, the effect of N on crop production mainly showed up in an increased light interception by the canopy. During the period of rapid growth from regreening to maturity, it was present in both light interception and RUE. The temporal variations of RUEAPAR (aboveground biomass produced per unit of photosynthetically active radiation absorbed by the canopy) during the period from regreening to maturity had different patterns corresponding to the N deficiency, N adequacy and N-excess conditions. Moreover, significant relationships were found between the RUEAPAR and the accumulative normalised difference vegetation index (NDVI) in the integrated season (R-2 = 0.68), between the HI and the accumulative NDVI after anthesis (R-2 = 0.89), and between the RUEgrain (ratio of grain yield to the total amount of photosynthetically active radiation absorbed by the canopy) and the accumulative NDVI of the whole season (R-2 = 0.89) and that after anthesis (R-2 = 0.94). It suggested that canopy spectral reflectance has the potential to reveal the spatial information of the RUEAPAR, HI and RUEgrain. It is hoped that this information will be useful in improving the accuracy of crop yield simulation in large areas.

Separation of ternary systems of hydrophilic ionic liquid with miscible organic compounds by RPLC with refractive index detection

A rapid and simple analytical method was developed for the simultaneous and quantitative determination and separation of hydrophilic imidazolium ionic liquids (ILs) (1-butyl-3-methylimidazolium chloride, [C(4)mim]Cl; 1-hexyl-3-methylimidazolium chloride, [C(6)mim]Cl; 1-octyl-3-methylimidazolium chloride, [C(8)mim]Cl; 1-allyl-3-methylimidazolium chloride, [Amim]Cl; or 1-allyl-3-methylimidazolium bromide, [Amim]Br) with miscible ethyl acetate and EtOH and their mixtures using reverse phase liquid chromatography coupled with refractive index detection (RPLC-RI). The influence of 60 to 100% (volume percentage) methanol in the mobile phase on the IL systems ([C(4)mim]Cl, [C(6)mim]Cl, [C(8)mim]Cl, [Amim]Br, or [Amim]Cl)-ethyl acetate-EtOH was investigated.

White polymeric light-emitting diodes with high color rendering index

The efficient white polymeric light-emitting diodes based on a white emissive polymer doped with a red phosphorescent dopant were fabricated by spin-coating method. The emission spectrum of the device is broadened to cover the full visible region by doping the red phosphorescent dye and thereby realizes white emission with high color-rendering index (CRI). By controlling the contents of the doped electron-transporting 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole and the red phosphorescent dopant, a luminous efficiency as high as 5.3 cd/A and a power efficiency of 3 lm/W were obtained with a CRI of 92.

Study on QSPR of alcohols with a novel edge connectivity index F-m

A novel edge degree f(i) for heteroatom and multiple bonds in molecular graph is derived on the basis of the edge degree delta(e(r)). A novel edge connectivity index F-m is introduced. The multiple linear regression by using the edge connectivity index F-m and alcohol-type parameter delta, alcohol-distance parameter L can provide high-quality QSPR models for the normal boiling points (BPs), molar volumes (MVs), molar refraction (MRs), water solubility(log(1/S)) and octanol/water partition (logP) of alcohols with up to 17 non-hydrogen atoms. The results imply that these physical properties may be expressed as a liner combination of the edge connectivity index and alcohol-type parameter, 6, alcohol-distance parameter, L. For the models of the five properties, the correlation coefficient r and the standard errors are 0.9969,3.022; 0.9993, 1.504; 0.9992, 0.446; 0.9924,0.129 and 0.9973,0.123 for BPs, MVs, MRs, log(1/S) and logP, respectively. The cross-validation by using the leave-one-out method demonstrates the models to be highly reliable from the point of view of statistics.

On characterization of organic structures - A highly discriminating molecular topological index

A new molecular topological index, EATI is proposed based on the extended adjacency matrix, It has a hitherto unheard of power of discrimination and can be applied to discriminate various kinds of organic compounds, such as structures containing heteroatoms, etc.. Thus EATI might be possibly used as supplementary reference for CAS Registry Numbers for structure documentation.

On highly discriminating molecular topological index

A highly discriminating molecular topological index, EAID, is proposed based on the extended adjacency matrix. A systematic search for degeneracy was performed for 3 807 434 alkane trees, 202 558 complex cyclic or polycyclic graphs, and 430 472 structures containing heteroatoms. No counterexamples (two or more nonisomorphic structures with the same EAID number) were found. This is a hitherto unheard of power of discrimination. Thus EAID might be possibly used as supplementary reference for CAS Registry Numbers for structure documentation.

A new topological index for the Changchun institute of applied chemistry C-13 NMR information system

A method to assign a single number representation for each atom (node) in a molecular graph, Atomic IDentification (AID) number, is proposed based on the counts of weighted paths terminated on that atom. Then, a new topological index, Molecular IDentification (MID) number is developed from AID. The MID is tested systematically, over half a million of structures are examined, and MID shows high discrimination for various structural isomers. Thus it can be used for documentation in the Changchun Institute of Chemistry C-13 NMR information system.