CaS:M (M=Ce~(3+), Dy~(3+), Eu~(2+), Cu)和Cas:Ce~(3+), M (M=Dy~(3+), Cu)的合成及其光致发光和热释发光性质研究

本文研究了Ce~(3+), Dy~(3+), Eu~(3+), Cu离子以及它们的共掺杂在硫化钙基质中的光致发光和热释发光性质，并用顺磁共振方法研究了磷光体中缺陷的性质及其对磷光体光致发光的影响。在CaS:Ce~(3＋)磷光体的稳定性影响因素，并经包膜后稳定性有所提高。计算了新的热释发光峰的陷阱参数。确定了热释发光的动力学级数。在Cas: Dy~(3+)磷光体中，研究了合成条件对磷光体发光性质的影响，讨论了新的热释发光峰的陷阱参数，确定了热释发光的动力学级数。在CaS:Dy~(3+)磷光体中，发现基质对Dy~(3+)离子具有敏化作用，讨论了黄兰比随Dy~(3+)离子浓度变化出现最大值的原因。计算了热释发光峰的陷阱参数，确定了热释发光的动力学级数。在CaS:Ce~(3+)，Dy~(3+)磷光体中，研究了Ce~(3+)离子的发光随Dy~(3+)离子浓度的变化，可能具有Dy~(3+) → Ce~(3+)的能量传递。计算了热释发光峰的陷阱参数，确定了热释发光的动力学级数。在CaS:Cu磷光体中，确定了不同Cu~+离子格位所产生的发射峰。根据磷光体中缺陷的转化过程解释了光致发光和热释发光性质随Cu离子浓度增加所呈现的规律性变化。通过实验证明磷光体有可能用作紫外剂量材料。本文还首次研究了CaS:Cu磷光体在UV（3bb nm)辐照下，发生Cu~+→Cu~(2+)的光氧化反应，通过EPR实验证明在Cu'_(Ca)→Cu_i~+处发生光氧化反应。在CaS:Ce~(3+),Cu磷光体中，观察到了Cu离子对Ce~(3+)离子的能量传递现象。在CaS:Eu~(2+)光体中，发光强度随Eu~(2+)离子浓度变化，显示浓度猝灭特性。本文还研究了CaS:Ce~(3+), CaS:Dy~(3+), CaS:Cu以及CaS:Ce~(3+), Cu磷光体中缺陷的性质，在CaS:Ce~(3+)中存在V_S~(2+)空位，并根据这一空位的性质，解释了发光光谱，并且选择适当的助熔剂使发光效率提高。在CaS:Dy~(3+)磷光体中，存在V_S~(2+)-V_(Ca)~(2-)空位对；在CaS:Cu和CaS:Ce~(3+), Cu磷光体中，存在V_S~(2+)空位和Cu'_(Ca)缺陷。

SELF-CONSISTENT TREATMENT OF 3-DIMENSIONAL - 2-DIMENSIONAL AND 2-DIMENSIONAL - 2-DIMENSIONAL RESONANT-TUNNELING IN DOUBLE-BARRIER STRUCTURES

By using a transfer-matrix method on the basis of two-dimensional (2D) Bloch sums in accordance with a tight-binding scheme, a self-consistent calculation on the resonant tunneling in asymmetric double-barrier structures is presented, in which contributions to resonant tunneling from both three-dimensional (3D) electrons in the contacts and 2D electrons in the spacer or accumulation layers are considered simultaneously. The charge buildup effect on the current versus voltage (I-V) curves is evaluated systematically, showing quantitatively how it results in the I-V bistability and enhanced differences between I-V curves for positive and negative bias in an asymmetric double-barrier structure. Special attention is focused on the interaction between 3D-2D and 2D-2D resonant-tunneling processes, including the suppression of 2D-2D resonant tunneling by the charge buildup in the well accompanying the 3D-2D resonant tunneling. The effects of the emitter doping condition (doping concentration, spacer thickness) on the presence of two types of quasi-2D levels in the emitter accumulation layers, and on the formation of a potential bulge in the emitter region, are discussed in detail in relation to the tunneling process.

Summer monsoon intensity controls C-4/C-3 plant abundance during the last 35 ka in the Chinese Loess Plateau: Carbon isotope evidence from bulk organic matter and individual leaf waxes

IEECAS SKLLQG

Three-body force effect on P-3 F-2 neutron superfluidity in neutron matter, neutron star matter, and neutron stars

We investigate the effect of microscopic three-body forces on the P-3 F-2 neutron superfluidity in neutron matter, beta-stable neutron star matter, and neutron stars by using the BCS theory and the Brueckner-Hartree-Fock approach. We adopt the Argonne V18 potential supplemented with a microscopic three-body force as the realistic nucleon-nucleon interaction. We have concentrated on studying the three-body force effect on the P-3 F-2 neutron pairing gap. It is found that the three-body force effect considerably enhances the P-3 F-2 neutron superfluidity in neutron star matter and neutron stars.

Synthesis and characterization of novel biodegradable poly(carbonate ester)s with photolabile protecting groups

Novel biodegradable poly(carbonate ester)s with photolabile protecting groups were synthesized by ring-opening copolymerization Of L-lactide (LA) with 5-methyl-5-(2-nitro-benzoxycarbonyl)-1,3-dioxan-2-one (MNC) with diethyl zinc (Et2Zn) as catalyst. The poly(L-lactide-co-5-methyl-5-carboxyl-1,3-dioxan-2-one) (P(LA-co-MCC)) was obtained by UV irradiation Of poly(L-lactide acid-co-5-methyl-5-(2-nitro-benzoxycarbonyl)-1,3-dioxan-2-one) (P(LA-co-MNC)) to remove the protective 2-nitrobenzyl group.

Novel aliphatic poly(ester-carhonate) with pendant allyl ester groups and its folic acid functionalization

A series of novel poly(ester-carbonate)s bearing pendant allyl ester groups P(LA-co-MAC)s were prepared by ring-opening copolymerization Of L-lactide (LA) and 5-methyl-5-allyloxycarbonyl-1,3-dioxan-2-one (MAC) with diethyl zinc (ZnEt2) as initiator. NMR analysis investigated the microstructure of the copolymer. DSC results indicated that the copolymers displayed a single glass-transition temperature (T-g), which was indicative of a random copolymer, and the Tg decreased with increasing carbonate content in the copolymer.

Five supramolecular compounds of water-soluble sulfonylcalix[4]arenetetrasulfonate showing two calixarene conformations

Five new compounds of sulfonylcalix[4]arenetetrasulfonate (SC4AS), [H7Na(H2O)(3)(SC4AS)(phen)(5)](H2O)(11.9) (1), [H6Mn(H2O)(4)(SC4AS)(phen)(5)] (H2O)(12.7) (2), [Cu-4(SC4AS) (phen)(6)] (H2O)(4.5) (3), {[Cu (2)(SC4AS) (bpy)(2)][Cu(bpy)(2)(H2O)](2)} (H2O)(6.6) (4), and {[Zn-2(SC4AS) (phen)(2)][Zn(phen)(2)(H2O)(2)](2)} (H2O)(7) (5) (where phen 1,10-phenanthroline and bpy = 2,2'-bipyridine), were synthesized by a hydrothermal method and structurally determined by single crystal X-ray diffraction. The SC4AS ligand adopts partial cone conformation in compounds 1 and 2 and 1,2-alternate form in compounds 3-5. According to the structural analysis and density functional theory (DFT) calculations, we suggest that the metal can affect the conformation of SC4AS.

Cinnamate-Functionalized Poly(ester-carbonate): Synthesis and Its UV Irradiation-Induced Photo-Crosslinking

A functionalized. cyclic carbonate monomer containing a cinnamate moiety, 5-methyl-5-cinnamoyloxymethyl-1,3-dioxan-2-one (MC), was prepared for the first time with 1,1,1-tri(hydroxymethyl) ethane as a starting material. Subsequent polymerization of the new cyclic carbonate and its copolymerization with L-lactide (LA) were successfully performed with diethyl zinc (ZnEt2) as initiator/catalyst. NMR was used for microstructure identification of the obtained monomer and copolymers. Differential scanning calorimetry (DSC) was used to characterize the functionalized poly(ester-carbonate). The results indicated that the copolymers displayed a single glass transition temperature (T-g) and the T, decreased with increasing carbonate content and followed the Fox equation, indicative of a random microstructure of the copolymer. The photo-crosslinking of the cinnamate-carrying copolymer was also demonstrated.

Phase conversion and spectral properties of long lasting phosphor Zn-3 (PO4)(2): Mn2+, Ga3+

A red long lasting phosphor Zn-3(PO4)(2): Mn2+ Ga3+ (ZPMG) was prepared by ceramic method, and phase conversion and spectral properties were investigated. Results indicated that the phase conversion from alpha-Zn-3(PO4), beta-Zn-3(PO4)(2) to gamma-Zn-3(PO4)(2) occurs with different manganese concentration incorporated and sinter process. The structural change induced by the phase transformation results in a remarkable difference in the spectral properties. The possible luminescence mechanism for this red LLP with different forms has been illustrated.

Sugars-grafted aliphatic biodegradable poly(L-lactide-co-carbonate)s by click reaction and their specific interaction with lectin molecules

A novel biodegradable aliphatic poly(L-lactide-co-carbonate) bearing pendant acetylene groups was successfully prepared by ring-opening copolymerization of L-lactide (LA) with 5-methyl-5-propargyloxycarbonyl-1,3-dioxan-2-one (PC) in the presence of benzyl alcohol as initiator with ZnEt2 as catalyst in bulk at 100 degrees C and subsequently used for grafting 2-azidoethyl beta-D-glucopyranoside and 2-azidoethyl beta-lactoside by the typical "click reaction," that is Cu(I)-catalyzed cycloaddition of azide and alkyne. The density of acetylene groups in the copolymer can be tailored by the molar ratio of PC to LA during the copolymerization. The aliphatic copolymers grafted with sugars showed low cytotoxicity to L929 cells, improved hydrophilic properties and specific recognition and binding ability with lectins, that is Concanavalin A (Con A) and Ricinus communis agglutinin (RCA). Therefore, this kind of sugar-grafted copolymer could be a good candidate in variety of biomedical applications.

Syntheses, structures, and characterizations of four new silver(I) sulfonate coordination polymers with neutral ligands

In this paper, four novel silver(I) sulfonate coordination polymers containing neutral ligands, namely, [Ag(2)Ll (biim)(2)]center dot 2H(2)O (1). AgL2(biim) (2), [Ag(HL3)(Pic)(2)]center dot H2O (3), and [Ag-3(L3)(HL3)(4,4'-bipy)(3)(H2O)(2)]center dot 4H(2)O (4), have been synthesized [L1 = 3-carboxy-4-hydroxybenzenesulfonate, L2 = p-aminobenzenesulfonate, H(2)L3 = p-hydroxybenzenesulfonic acid, biim = 1,1'-(1.4-butanediyl)-bis(imidazole), Pic = beta-picoline, 4,4'-bipy = 4,4'-bipyridine]. For compounds 1 and 2, Ag(I) cations are bridged by biim ligands to form a one-dimensional (1D) "zigzag" chain, and L1 and L2 sulfonate ligands are not coordinated to the silver cation. Compound 3 has a dimeric structure in which two silver cations are bridged by two HL3 ligands. For compound 4, L3 ligand coordinates to a silver cation as a monodentate ligand, and Ag(l) cations are bridged by 4,4'-bipy ligands to form a ID chain. Compound 1 contains water dimers, while compound 4 contains water trimers. Compounds 1-3 display room-temperature photoluminescence.