大别山高压-超高压带片麻岩锆石的研究

The zircons from gneisses in high and ultrahigh pressure (HP-UHP) metamorphic zones of the Dabie Mountains have been studied on three aspects in this paper, including (1) radiation damage of zircon using Laser Raman spectrum; (2) genesis determination of zircons based on geochemistry; (3) temperature estimate of the HP-UHP metamorphism using Ti-in-zircon thermometer. The zircons have the full widths at half-maximum less than 15 cm-1 at the 1008 cm-1 peak, suggesting that they are well crystallized to moderately damaged. The early inherited zircons from gneisses had undergone significant annealing and recrystallization during the HP-UHP metamorphic event. The α-doses that zircons suffered were accumulated from about 200Ma, indicating that HP-UHP metamorphic rocks have been exhumed to the surface of the earth at this time. The studies from the CL images, mineral inclusions, U-Pb ages and trace elements reveal that metamorphic zircons were formed as two kinds of mechanisms: metamorphic growth and recrystallization. The zircons of metamorphic growth and recrystallization zircons that were completely equilibrated during the HP-UHP metamorphic event have been chosen to carry out for temperature estimate using the Ti-in-zircon thermometer. The result shows that the HP-UHP terrain of the Dabie Mountains can be divided into five zones with temperature gaps, suggesting that the terrain consists of tectonic slices with different metamorphic history.

山东莒南地区韧性剪切带的变形特征与形成演化

Ju Nan of Shandong province is located at southwest of Sulu UHP (ultrahigh-pressure) metamorphic terrane. It is composed of gneiss, paragneiss, eclogites, ultramafic rocks, marble and quartzite. A large ductile shear zone extends east-west has been found at the Zhubian, The south of Junan county. The Zhubian ductile shear zone is composed of high srain rock and mylonites. The mylonites fall into 3 types: Initial gneiss mylonite, mylonite and altramylonit.obvious lineation of penetration,foliation,S-Cfabrics,porphyroclasts,folds,irregularundulatory,extinction,subgrain boundary, dynamic recrystallization microstructure, core-mantle structure and are common in the ductile shear zone. Based on field work and microstructural analyse, a conclution is arrived: The ductile shear zone is an approximately SE trending faults. The Zhubian ductile shear zone formed at Ep ―Hb facies conditions which could be proved by deformaed and metamorphosed mineral aggregates, Deformation behavior, Ternary-feldspar geothermometry and so on. Zircon MC―ICP―MS U-Pb analysis is performed on the mylonite and have an average age ―835.9±13.9Ma, it’s the primary rocks formed age. The Zhubian ductile shear zone maybe formed at 224-242Ma.

内蒙古克什克腾旗小东沟斑岩型钼矿床的成矿作用

In this paper, the Xiaodonggou porphyry molybdenum deposit located in the Xarmoron molybdenum metallogenic belt is chose as the research area. We have analyzed the petrology of the Xiaodonggou pluton in detail and made chemical analysis of the major and trace elements, Rb-Sr and Sm-Nd isotope, common lead isotope and SHRIMP zircon U-Pb dating et al; in the other hand, we use the molybdenite to make common lead analysis and Re-Os isotopic dating. The Xiaodonggou pluton is rich in silicon, potass, zirconium, and low in REE. In addition, it has no minus Eu abnormity and show a isotopic composition high in εNd(t) and low in Sri, indicating its magma origining from the melting of juvenile thicken lower crust. In the meanwhile, it contained the features of high temperature, quick melting, quick segregation and quick emplacement. The common lead analysis of the pluton orthoclase and molybdenite show that the former transfer from orogen to mantle and the latter come from mantle, which is consistent to the molybdenite sulfur isotopic and quartz oxygen isotopic composition, demonstrating that the rock and ore-forming materials of deposit having different sources, magma from the lower crust mixing with mantle fluid. In plus, we use the physical experiments results of the water-magma reaction to explain the interaction of magma and mantle fluid. In the deep crust, these two systems uplifted in a immiscible state; when they reached low depth, the stream film between fluid-magma collapsed, and the magma was broken into small agglomerates by the fluid, then they mixed thoroughly. The SHRIMP zircon U-Pb dating gave a result of 142±2Ma and the molybdenite Re-Os dating result is 138.1±2.8Ma, corresponding to the big tectonic transition period of 140Ma, when the major stress field changing from south and north to west and east. At this time, the Da Hinggan ling ranges area was under an extensive background, underplating proceeded and mantle materials could add into the magmas forming in the lower crust. So, from the above analysis, we propose the following model for the Xiaodonggou porphyry molybdenum deposit: in the early Cretaceous period, the Da Hinggan ling ranges area was under a extensive background, the adding of mantle fluid containing ore materials into heated lower crust made it melting to produce magmas. Following more mantle fluid got into the magma room and urged the magma to segregate from the source quickly. The fluid and magma uplifted together, when they arrived at shallow depth, the fluid-magma became unstable and the latter was broken into many small agglomerates with fluid connecting them in the interspaces. Because of the H+, K+ and various elements existing in the fluid, it would reacted with the magma and the rock through alteration and ore minerals crystallized out, forming the Xiaodonggou porphyry deposit with disseminated mineralization phenomenon.

荣成基底片麻岩原岩岩石成因及其构造意义

Extensive high to ultrahigh pressure metamorphic rocks are outcropped in the the Dabie-Sulu UHP orogenic belt. Disputes still exist about for protolith nature of metamorphic rocks, petrogenesis, tectonic setting, and influence on upper mantle during the Triassic deep subduction. In this study, a combined study of petrology, geochemistry, isotope geochemistry and zircon chronology was accomplished for high-grade gneisses in the basement of the ultrahigh-pressure metamorphic Rongcheng terrane to reveal protolith nature and petrogenesis of the gneisses and to disucss the magmatic succession along the northern margin of the Yangtze block in Neoproterozoic. Gneisses in the Rongcheng terrane are characterized by negative Nb, Ta, P and Ti anomalies, relatively low Sr/Y ratios and relatively high Ba/La, Ba/Nb and Ba/Zr ratios, mostly displaying geochemical affinity to Phanerozoic volcanic arc. Neoproterozoic protolith ages (0.7 ~ 0.8 Ga) and Paleoproterozoic average crustal residence time (1.92 ~ 2.21 Ga) favour a Yangtze affinity. The gneisses mostly display characteristics of enrichment of LREE, flat heavy rare earth elements (REE) patterns, moderately fractionation between LREE and HREE and slight negative or positive Eu anomalies, probably reflecting that melting took place in the middle to low crust (26 ~ 33 km), where amphibole fractionated from the melts and/or inherited from source material as major mineral phases in the source area. Sr-Nd isotopic composition of the gneisses supports this conclusion. According to εNd(t) and εHf(t) values, the gneisses can be divided into three groups. Gneisses of group I have the highest εNd(t) and εHf(t) values, corresponding to the range of -6 ~ -3 and -2.9 ~ 13.4, respectively. This suggests obvious influx of depleted mantle or juvenile crust in the formation of protoliths. Gneisses of group II have medium εNd(t) (-9 ~ -7) and εHf(t) values (-15.8 ~ -1.4), corresponding to relatively high TDM2(Nd) (1.99 ~ 2.31 Ga) and TDM2(Hf) (1.76 ~ 2.67 Ga) , respectively. This suggests these gneisses were formed by partial melting of Paleoproterozoic crust. Gneisses of group III have the lowest εNd(t) (-15 ~ -10) and εHf(t) values (-15.8 ~ -1.4), corresponding to the largest TDM2(Nd) (1.99 ~ 2.31 Ga) and TDM2(Hf) ( 1.76 ~ 2.67 Ga), respectively. This indicates that gneisses of group III were formed by remelting of Archean crustal material and further demonstrates existence of an Archean basement probably of the Yangtze affinity beneath the Rongcheng terrane. Gneisses of three groups have also certain different geochemical characteristics. Contents of REEs and trace elements reduce gradually from group I to group III. Zirconium saturation temperatures also show similar tendency. Compared to gneisses of group II and group III, gneisses of group I display geochemical feature similar to extensional tectonic setting, having relatively little influence by the source area. Therefore, geochemical characteristics for gneisses of group I can indictate that the protoliths of the Rongcheng gneisses formed in an extensional rifting tectonic setting. This conclusion is supported by the results of eclogites and gabbros previously reported in the Dabie-Sulu orogenic belt. Statistical results of the protolith ages of the Rongcheng gneisses show two age peaks around ~728 Ma and ~783 Ma with an about 50 Ma gap. Extensive magatism in abou 750 Ma along the northern margin of the Yangtze block can hardly be observed in the Rongcheng terrane. This phenomenon likely suggests discontinuous Neoproterozoic magmatism along the northern margin of the Yangtze block.

乍得西南部中新生代火山作用与盆地演化

Located in the Central and West African, Chad, which is not well geological explored, is characterized by Mesozoic- Cenozoic intra-continental rift basins. The boreholes exposed that, during Mesozoic-Cenozoic times, volcanic activities were intense in these basins, but study on volcanic rocks is very weak, especially on those embedded in rift basins, and so far systematic and detailed work has still no carried out. Based on the project of China National Oil and Gas Exploration and Development Corporation, “The analysis of reservoir condition and the evaluation of exploration targets of seven basins in block H in Chad”, and the cooperative project between Institute of Geology and Geophysics, CAS and CNPC International (Chad) Co. Ltd., “Chronology and geochemistry studies on Mesozoic-Cenozoic volcanic rocks from southwestern Chad Basins”, systematic geochronology, geochemistry and Sr-Nd-Pb isotopic geochemistry studies on volcanic rocks from southwestern Chad basins have been done in the thesis for the first time. Detailed geochronological study using whole-rock K-Ar and Ar-Ar methods shows the mainly eruption ages of these volcanic rocks are Late Cretaceous- Paleogene. Volcanic rocks in the well Nere-1 and Figuier-1 from Doba basin are products of the Late Cretaceous which majority of the K-Ar (Ar-Ar) ages fall in the interval 95-75 Ma, whereas volcanic rocks in the well Ronier-1 from Bongor Basin and the Well Acacia-1 from Lake Chad Basin formed in the Paleogene which the ages concentrated in 66-52Ma. Two main periods of volcanic activity can be recognized in the study area, namely, the Late Cretaceous period and the Paleogene period. Volcanic activities have a general trend of south to north migration, but this may be only a local expression, and farther future studies should be carried on. Petrology study exhibits these volcanic rocks from southwestern Chad basins are mainly tholeiitic basalt. Major- and trace elements as well as Sr-Nd-Pb isotopic geochemistry studies show that the late Cretaceous and the Paleogene basalts have a definitely genetic relationship, and magmas which the basalts in southwestern Chad basins derived from were produced by fractional crystallization of olivine and clinopyroxene and had not do suffered from crustal contamination. These basalts are prominently enriched light rare earth elements (LREE), large-ion lithophile elements (LILE) and high field strength elements (HFSE) and depleted compatible elements. They have positive Ba, Pb, Sr, Nb, Ta, Zr, Hf anomalies and negative Th, U, P,Y anomalies. It is possible that the basalts from southwestern Chad basins mainly formed by mixing of depleted mantle (DM) and enriched mantle (EMⅡ) sources. The late Cretaceous basalts have higher (87Sr/86Sr)i ratios than the Paleogene basalts’, whereas have lower (143Nd/144Nd)i ratios than the latter, showing a significant temporal evolution. The mantle sources of the Late Cretaceous basalts may have more enriched mantle(EMⅡ) compositions, whereas those of the Paleogene basalts are relatively more asthenospheric mantle (DM) components. The mantle components with temporal change observed in basalts from Chad basins were probably correlated with the asthenospheric mantle upwelling and lithospheric thinning in Central and Western Africa since Mesozoic. Mesozoic- Cenozoic Volcanism in Chad basins probably is a product of intra- plate extensional stress regime, corresponded to the tectonic setting of the whole West and Central African during Cretaceous. Volcanism is closely correlated with rifting. As time passed from early period to late, the basaltic magma of Chad basins, characterized with shallower genetic depth, higher density and smaller viscosity, probably indicates the gradual strengthening evolution of the rifting. In the initial rife stage, volcanic activities are absent in the study area. Volcanic activities are basiccally corresponded with the strong extensional period of Chad basins, and the eruption of basalts was slightly lagged behind the extensional period. In the post-rift stage (30-0Ma), these basins shifted to the thermal sag phase, volcanic activities in the study area significantly decreased and then terminated.

东准噶尔和尔赛斑岩铜矿特征及其形成的构造背景

Hersai porphyry copper deposit(PCD) of eastern junggar, newly discovered copper deposit, is located at the eastern segment of the Xiemisitai-Kulankazigan-Zhifang-Qiongheba Paleozoic island arc, Eastern Junggar. The Hersai PCD is developed in a intrusive complex, characterized by intensive and multiform hydrothermal alteration, including potassic alteration, silification, chloritization，sericitization，kaolinitization and carbonatization. Granodiorite, grandiorite porphyry, granite and concealed explosion breccia are hosts of the ore bodies containing veinlet and disseminated ore. Ore-bearing granite (ZK107-1-9), granodiorite (ZK107-1-9) and Ore-barren granodiorite (HES2-1) are selected to date zircon U-Pb age by SHRIMP method, and have an age of 429.4±6.4Ma ,413.0±3.4Ma and 411.1±4.8Ma, respectively, showing that they were emplaced from Late Silurian to Early Devonian. In addition, sample ZK107-1-9 has some hydrothermal zircons with a weighted mean 206Pb/238U age of 404.9±3.7Ma which is interpreted to be related to the granodiorite porphyry. Re-Os dating of five molybdenite samples yielded a weighted average model age of 408.0±2.9Ma, indicating the metallogenic epoch of the Hersai PCD. The ore-forming age is close to the petrogenic time of garnodiorite (411-413Ma), this suggests the ore-forming porphyry is most possiblely granodiorite porphyry. Systematic major - trace elements and Rb-Sr-Sm-Nd-Pb-Hf isotopic characteristics were studied. Analysis results show that these intrusives have some interesting and special characteristics, as following:1) containing both calc-alkaline rocks and high potassium calc-alkaline rocks ; 2) have some characteristics of adakite, but not totally, such as much lower La/Yb ratios and no Eu anomaly or just faint Eu anomaly; 3) have an initial 87Sr/86Sr ratios(0.703852-0.704565) similar to that of BSE, positive εNd(t) values between 6.1 and 7.4, the initial 206Pb/204Pb values (17.576-17.912), 207Pb/204Pb values (15.400-15.453) , 208Pb/204Pb values (37.252-37.466) , and high εHf(t) values (10.2-15.4) close to the value of depleted mantle. These geochemical features suggest that these igneous rocks in the Hersai area not only have some characteristics of island arc, but also some characteristics that only appear in the continental margin arc. It is suggested that Hersai PCD is formed in the subduction setting by the partial melting of young crust. These works and advancements mentioned in the paper are helpful to understand the deposit geology, geochemistry and metallogenesis of Hersai PCD. It is also significant to understand mineralization and tectonic setting in the Qiongheba area.

新疆谢米斯台中段地区火山岩特征及其含矿性研究

Central Xiemisitai is located on the northwest edge of the Junggar Basin, bounded on the north by Sawuer Mountain, and southward Junggar Basin. Geotectonically, it is within the Chengjisi-Ximisitai-Santanghu island arc of Late Paleozoic, between Siberian and Junggar plates. The volcanics in this area mainly consist of acidic volcanic lava, rock assemblage of esite, dacite, and rhyolite, and the transitional phase is comparatively developed. Besides, Si2O of volcanics here covers a large range of 53.91-79.28t %, K2O of 1.71-6.94t%, and Na2O of 2.29-5.45t%, which is a set of metaluminous- peraluminous high K calc-alkaline to calc alkaline mid-acidic volcanic series. In addition, the volcanics are potassic to high-potassic assemblage, with slight shoshonite in. The REE curve of volcanics in central Xiemisitai is rightward and smooth, inclining to LREE enrichment, which reveals the characteristics of island-arc volcanics. Through the lithology changing from neutral to acidic, the negative anomaly of Eu is increasing. The volcanics here deplete HFSE such as Nb, Ti, P, etc., but relatively rich in LILE like Rb, K, Th, etc., possessing geochemistry characteristics of arc volcanics, which means that the lava source region is watery, under the meta-somatic contamination of subducted components. Moreover, high Ba and Sr show volcanics in epicontinental arc environment, and their contemporaneous granitoid rocks are also marked with the characteristics of volcanic arc granite. In central Xiemisitai, the volcanics zircon age of volcanic rhyolite is 422.5Ma± 1.9Ma, mid-late Silurian. Only one sample zircon has been measured for the present, not very convincing, so volcanics here might not come from Devonian volcanism. Consequently, further confirming the volcanic age will play a key role in the research on the beginning of volcanism in Xiemisitai area and even North Xinjiang. This area includes three copper mineralization types: a) from andesite fracture; b) from rhyolite fracture broken zone, with the copper mineralization distributed by veins along the fissure; and c) from quartz veins. The mineralization of earth surface in S24 ore spot is intensive, and the primary geochemistry reconnaissance anomaly is fairly good. According to display data, the maximum content of Cu is as high as 0.9% and as low as 0.05%. Also, ore-control fracture structure is having a considerable scale in the strike of fracture both horizontally and vertically downwards, and the result of the geophysics stratagem EH-4 system reveals obvious low-resistivity anomaly. As a result, we believe that the S24 plot is expected to be a volcanic copper deposit target area.

内蒙古中部道郎和都格铜多金属矿的地质特征矿床类型及找矿模式研究

Daolangheduge copper polymetallic deposit is located on east edge of Ondor Sum-Bainaimiao metallogenic belt, which is a prospective area of porphyry copper deposit, in Xianghuangqi of central Inner Mongolia. Geotectonically, it occurred in the continental margin accretion belt along the north margin of North China Plate, south of the suture zone between North China Plate and Siberian Plate. The intrusive rocks in this area mainly consist of intermediate-acid magmatic rocks, and the quartz veins, tourmaline veins and the transitional phase are comparatively developed. According to our research, the ore-bearing rock body is mainly quartz diorite while the surrounding rock is mainly biotite granite. Besides, the wall rock alteration are mainly propylitization, pyritization and silicification, which consist of epidotization, actinolitization, chloritzation and so on. The metallic minerals are mainly chalcopyrite and pyrite. In addition, the primary ore is mainly of quartz-chalcopyrite-pyrite type. Above all, Daolangheduge copper polymetallic deposit is suggested to be categorized in the porphyry copper type. With isotopic dating and geochemical research on quartz diorite of ore-bearing rock body, the zircon LA-ICP-MS U-Pb dating of two samples yields an age of 266±2 Ma, falling into the range of late Permian Epoch. It is the first accurate age data in Xianghuangqi area, so it should play a key role in the research of deposit and magmatic rocks in this area. With the major elements and trace elements analysis of 14 samples, the quartz diorite should be among the calc-alkaline series, the geochemical characteristics show higher large-ion lithophile elements of Rb, Sr and LREE, low high-field strength elements of Nb, Ta and high transition elements of Cu, Cr . Also, the REE patterns have negative Eu anomalies. With the same analysis of 4 sample for the biotite granite, the geochemical characteristics show higher Rb, Th,, Zr, Hf and LREE, low Nb, Sm and HREE and Eu has no anomaly. It should be among the calc-alkaline series, over aluminum quality and has characteristics of Adakites. According to isotopic dating and geochemical characteristics of ore-bearing rock body, it is suggested that its materials mainly derived from upper mantle that had fractional crystallization and its magma source region may be affected by fluid metasomatism of paleo-asian ocean. It should be an extensional process of post-orogeny according to regional tectonic evolution. Consequently, because of the decrease of temperature and pressure, the ore forming fluid was raised to surface and mineralized accompanied by magmatic activity which might occur in south of the suture zone. By geological survey, further geophysical and geochemical work is needed. In this area, we have accomplished high precision magnetic prospecting, high density electrical survey, gravity prospecting, soil geochemical prospecting, X-ray fluorescence analyzer prospecting and so on. According to geophysical and geochemical abnormal and surface occurrence, 11 drills are arranged to verification. The type of ores are mainly quartz-chalcopyrite-pyrite ores within 3 drills by drill core logging. Although the grade as well as the scale of already-found Cu deposits are insufficient for industrial exploitation, the mineralization prospect in this region is supposed to be great and the potential in mineral exploration at depth is excellent.

碎屑锆石年龄和Nd-Hf同位素组成对扬子基底演化的制约

The South China craton was formed by the collision of the Yangtze and Cathaysia blocks during the Neoproterozoic Jiangnan orogeny (also termed as the Jingnin or Sibao orogeny in Chinese literature). Basement rocks within the Yangtze block consist mainly of Proterozoic sediments of the Lengjiaxi and Banxi Groups. U-Pb ages of detrital zircons obtained by the LA-ICP-MS dating technique imply that the deposition of the Lengjiaxi Group continued until the Neoproterozoic. The youngest detrital zircons suggest a maximum deposition age of ~830 Ma for the Lengjiaxi Group, consistent with the initiation time of the deposition of the overlying Banxi Group, likely indicating continuous deposition of these two groups and a short temporal hiatus (~10 Ma) between the Neoproterozoic sedimentary rocks distributed in the South China craton. Detrital zircons from both the Lengjiaxi and Banxi Groups have a wide range of εHf(t) values from -12 to 14.2 and a continuous Nd and Hf model age spectrum from ~820 Ma to 2200 Ma. Some grains have model ages ranging up to ca. 2.9-3.5 Ga, indicating that both juvenile mantle material and ancient crust provided sedimentary detritus. This is also consistent with the Nd isotopic signature of sedimentary rocks recorded in the Lengjiaxi Group, suggesting a back-arc tectonic setting. The Banxi Group has slightly enriched Nd isotopic signatures relative to the Lengjiaxi Group, implying a higher percentage of old continental material in the sedimentary source. Combined with previously published data, new results can help us to reconstruct the Neoproterozoic tectonic evolution of the South China craton. The age spectrum of detrital zircons and Nd-Hf isotopic composition suggests a two-stage collision: Between 1000 Ma to 870 Ma, a continental magmatic arc was build up along the eastern margin of the Yangtze block. Convergence led to continent-based back-arc extension, subsidence and formation of a back-arc basin. Detritus originating from arc-related magmatic and old basement rocks was transported into this back-arc basin resulting in formation of the Lengjiaxi Group and its equivalents. At around 870 Ma, a second (oceanic) arc was formed by extension of an inter-arc basin, subduction subsequently led to the first collision and the emplacement of the blueschist mélange. Accretion of the magmatic arc lasted until the closure of an oceanic basin between the Yangtze and Cathaysia blocks at about 830 Ma. Shortly after the collision, subsequent uplift, further extension of the former back-arc basin and post-collisional granitoid magmatism caused a tilting of the Lengjiaxi sediments. Between 830 Ma and 820 Ma, subsequent closure of the oceanic back-arc basin and formation of the Jiangnan orogen took place, leaving a regional unconformity above the Lengjiaxi Group. Above this unconformity the Banxi Group was immediately deposited during the post-tectonic stage.

湘西地区上震旦统上部－下寒武统底部黑色岩系沉积学及地球化学

Widespread black chert-shales occur in the Ediacaran-Cambrian(E-C) boundary successions along the flank of Yangtze Platform, South China, remarkable changes in sedimentology, geochemistry and biology were recorded. Although extensive studies were carried out upon this boundary succession, the origin of black chert-shales still remain controversial. This paper focuses on the E-C black chert-shales in western Hunan, South China, upon which detailed depositional and geochemical changes are documented, accordingly a depositional model for black chert-shales is proposed. Stratigraphic anatomy across the depositional strike demonstrates that the shallow-water Dengying dolostone along the platform margin sharply pass basinward into the Liuchapo chert successions, which indicate syndepositional extensional faulting at depth could have occurred along the platform margin. The deep-water Niutitang phosphorite-rich black shales are either underlain by the Dengying dolostones on the platform margin toward platform interior or directly by the Liuchaopo chert successions farther basinwards. By detailed investigation, silica chimneys are firsly identified approximately in the chert along platform margin; two types of silica chimneys, including mounded and splayed/funnelized chert(generally brecciated) bodies are further sorted out. The mounded chert are exitbited by domed or hummocky surfaces on the top and irregular spongy to digitiform internal fabrics; within the silica mounds, abundant original vesicles/voids and/or channels were mostly plugged by initial chalcedony, quartze crystals with minor dolomite and bladed barite crystals. Splayed/funnelized brecciated chert “intrusion” cross-cut the uppermost dolostones capping to the horizon underneath, and are directly overlain by the Niutitang phosphorite-rich black shales. Their similarities to the silica chimneys reported from the oceanic spreading centres suggest a similar origin responsible for these unique silica bodies which is also supported by the microthermonmetric data and element geochemistry. High P, Ba, Fe contents and positive correlation between Fe and TOC concentrations in the Niutitang black shales indicate a high palaeo-productivity in the Early Cambrian ocean. The low Th/U and the high V/Cr, V/Sc, V/(V+Ni) ratios in the black shales suggest an anoxic water condition during this interval. Furthermore, Positive Eu anomalies and high Ba contents in the sediments also imply a hydrothermal influence on the formation of Niutitang black shales. To better constrain the placement of deep-water successions straddling the E-C boundary and the timing of hydrothermal silica chimneys, sensitive high-resoluton ion microprobe(SHRIMP) U-Pb dating of zircon grains from tuffs within the chert succession of Liuchapo Formation at Ganziping was conducted and yields a weighted-mean 206Pb/238Pb age at 536.6±5.5Ma, younger than E-C boundary age(542.0±0.3Ma). This age combined with carbon isotopic data is then proposed to correspond to the U-Pb age of zircons(538.2±1.5Ma) from the Zhongyicun member of Meishucun Formation at Meishucun in eastern Yunna, thus, the E-C boundary in Gazngziping was placed between the Dengying formations and Liuchapo formatioms. therefore, the silica chimneys took place at the beginning of the Cambrian period. The temporal coincidence of silica chimneys and negative excursions of δ13C and δ34Spy pairs suggest hydrothermal activities were likely responsible for the isotopic changes. Under such a circumstance, vast amounts of greenhouse gases(CO2, CH4, H2S), with highly 13C-depleted carbon and 34S-depleted sulfur would be released into the ocean and atmosphere. A positive shift in δ34Scas and Δ34S values from the late Ediacaran to the Early Cambrian could be a reflection of enhanced bacterial sulfate reduction(BSR), strengthened by the intensified oceanic anoxia stimulated by hydrothermal activities. Based on the analyses of sedimentology and geochemistry, a model- “oceanic anoxia induced by hydrothermal–volcanic activies” was proposed to responsible for the formation of black chert-shales during this E-C transition. Under this case, hydrothermal-volcanic activies could release large large amount of greenhouse into atmosphere and metal micronutrients into the ocean, which may lead to global warming, stratified ocean, thereby a high palaeoproductivity; on the other hand, the massive releasing of reduced hydrothermal fluids with abundant H2S, could have in turn enhanced the ocean anoxia. All of these were favourable the for preservation of organic matter, and subsequent extensive deposition of black silica-shales.

藏北可可西里碰撞后钾质火山作用和岩石成因

Post-collisional, potassic igneous rocks are widely distributed in the Hoh Xil area of the northern Tibetan Plateau. Based on the field work, petrography, mineral chemistry, K-Ar geochronology, element and Sr-Nd-Pb isotope geochemistry, this thesis systematically studied the spatial and temporal distribution of the volcanic rocks, chemical characteristics, formation mechanism and partial melting mechanism of the magma source region, geodynamic setting of magmatism, as well as crustal assimilation and fractional crystallization (AFC). The results show that: 1. The Miocene (7.77-17.82 Ma) volcanic products dominantly are trachandesite and trachy, and subordinate rhyolites, associated with stike-slip faults and thrust faults, formed morphology of small lava platforms and cinder cones. 2. Phenocrysts in the lavas are augite, andesine, sanidine, calcic amphibole and subordinate orthopyroxene, biotite and Ti-Fe oxides, displaying typical quench texture. Equilibrium temperatures and pressures of clinopyroxene phenocrysts indicate the magma chamber is located in upper-middle crust. 3. Rhyolites are the products of crustal melting and fractionation of shoshonitic magmas. The source region of intermediate magmas is enriched continental lithospheric mantle, which contains residual minerals such as phlogopite, rutile and spinel, and enriched by subducted sediments during earlier multi-episodes of subduction. 4. Upwelling of asthenosphere provides heat for source region melting, and faults provide channels for magma eruption. 5. Northward underthrusting of Indian continental lithosphere and southward of backstop of Asian continental lithosphere resulted in upwelling of hot asthenosphere. Geochemical characteristics of the potassic magmatism in North Tibet are dominantly controlled by source region composition, partial melting, and crustal assimilation and fractional crystallization (AFC).

东喜马拉雅构造结新生代碰撞变形与岩石圈演化

The Eastern Himalayan Syntaxis (EHS) is one of the strongest deformation area along the Himalayan belt resulted from the collision between Indian plate and the Eurasian Plate since the 50～60Ma, and has sensitivity tracked and preserved the whole collisional processes. It should depend on the detail geological investigations to establish the deformational accommodate mode, and the uplift history, to elucidate the deep structure and the crust-mantle interaction of the Tibet Plateau of the EHS. The deep-seated (Main Mantle Thrusts) structures were exhumed in the EHS. The MMT juxtapose the Gangdese metamorphic basement and some relic of Gangdese mantle on the high Himalayan crystalline series. The Namjagbawa group which is 1200～1500Ma dated by U/Pb age of zircon and the Namla group which is 550Ma dated by U/Pb age of zircon is belong to High Himalayan crystalline series and Gangdese basement respectively. There is some ophiolitic relic along the MMT, such as metamorphic ocean mantle peridotite and metamorphic tholeiite of the upper part of ocean-crust. The metamorphic ocean mantle peridotites (spinel-orthopyroxene peridotite) show U type REE patterns. The ~(87)Sr/~(86)Sr ratios were, 0.709314～0.720788, and the ~(143)Nd/~(144)Nd ratios were 0.512073～0.512395, plotting in the forth quadrant on the ~(87)Sr/~(86)Sr-~(143)Nd/~(144)Nd isotope diagram. Some metamorphic basalt (garnet amphibolite) enclosures have been found in the HP garnet-kynite granulite. The garnet amphibolites can be divided two groups, the first group is deplete of LREE, and the second group is flat or rich LREE, and their ~(87)Sr/~(86)Sr, ~(143)Nd/~(144)Nd ratios were 0.70563～0.705381 and 0.512468～0.51263 respectively. Trace element and isotopic characteristics of the garnet amphibolites display that they formed in the E-MORB environment. Some phlogolite amphibole harzburgites, which exhibit extensive replacement by Phl, Amp, Tc and Dol etc, were exhumed along the MMT. The Phl-Amp harzburgites are rich in LREE and LILE, such as Rb, K etc, and depletes Eu (Eu~* = 0.36 ～ 0.68) and HFSE, such as Nb, Ta, Zr, Hf, P, Ti etc. The trace element indicate that the Phl-Amp harzburgites have island arc signature. Their ~(87)Sr/~(86)Sr are varied from 0.708912 to 0.879839, ~(143)Nd/~(144)Nd from 0.511993 to 0.512164, ε Nd from- 9.2 to - 12.6. Rb/Sr isochrone age of the phlogolite amphibole harzburgite shows the metasomatism took place at 41Ma, and the Amp ~(40)Ar/~(39)Ar cooling age indcate the Phl-Amp harzburgite raising at 16Ma. There is an intense crust shortening resulted from the thrust faults and folds in the Cayu block which is shortened more 120km than that of the Lasha block in 35～90Ma. With the NE corner of the India plate squash into the Gangdese arc, the sinistral Pai shear fault and the dextral Aniqiao shear fault on the both sides of the Great bent of Yalun Zangbu river come into active in 21～26Ma. On the other hand, the right-lateral Gongrigabu strike-slip faults come into activity at the same period, a lower age bound for the Gongrigabu strike-slip fault is estimated to be 23～24Ma from zircon of ion-probe U/Pb thermochronology. The Gongrigabu strike-slip faults connect with the Lhari strike-slip fault in the northwestern direction and with the Saganing strike-slip at the southeastern direction. Another important structure in the EHS is the Gangdese detachment fault system (GDS) which occurs between the sedimental cover and the metamorphic basement. The lower age of the GDS is to be 16Ma from the preliminary 40Ar/39Ar thermochronology of white mica. The GDS is thought to be related to the reverse of the subducted Indian crust and the fast uplift of the EHS. Structural and thermochronology investigation of the EHS suggest that the eastern Tibet and the western Yunnan rotated clockwise around the EHS in the period of 35～60Ma. Later, the large-scale strike-slip faults (RRD, Gaoligong and Saganing fault) prolongate into the EHS, and connect with the Guyu fault and Gongrigabu fault, which suggest that the Indianchia block escape along these faults. Two kind of magmatic rocks in the EHS have been investigated, one is the mantle-derived amphibole gabbro, dioposide diorite and amphibole diorite, another is crust origin biotit-garnet adamellite, biotit-garnet granodiorite and garnet-amphibole-biotite granite. The amphibole gabbro dioposite diorite and amphibole diorite are rich in LREE, and LILE, such as Ba, Rb, Th, K, Sr etc, depleted in HFSE, such as Nb, Ta, Zr, Hf, Ti etc. The ratio of ~(87)Sr/~(86)Sr are from 0.7044 to 0.7048, ~(143)Nd/~(144)Nd are from 0.5126 to 0.5127. The age of the mantle origin magamatic rocks, which result from the partial melt of the raising and decompression anthenosphere, is 8Ma by ~(40)Ar/~(39)Ar dating of amphibole from the diorite. The later crust origin biotite-garnet adamellite, biotite-garnet granodiorite and garnet-amphibole-biotite granite are characterized by aboudance in LREE, and strong depletion of Eu. The ratios of ~(87)Sr-~(86)Sr are from 0.795035 to 0.812028, ~(143)Nd/~(144)Nd from 0.51187 to 0.511901. The ~(40)Ar/~(39)Ar plateau age of the amphibole from the garnet-amphibole-biotite granite is 17.5±0.3Ma, and the isochrone age is 16.8±0.6Ma. Their geochemical characteristics show that the crust-derived magmatic rocks formed from partial melting of the lower curst in the post-collisional environment. A group of high-pressure kaynite-garnet granulites and enclave of high-pressure garnet-clinopyroxene grnulites and calc-silicate grnulites are outcroped along the MMT. The peak metamorphic condition of the high-pressure granulites yields T=800～960 ℃, P=1.4～1.8Gpa, corresponding the condition of 60km depth. The retrograde assemblages of the high-pressure grnulites occur at the condition of T=772.3～803.3 ℃, P=0.63～0.64Gpa. The age of the peak metamorphic assemblages are 45 ～ 69Ma indicated by the zircon U/Pb ion-plobe thermochronology, and the retrograde assemblage ages are 13～26Ma by U/Pb, ~(40)Ar/~(39)Ar thermochronology. The ITD paths of the high-pressure granulites show that they were generated during the tectonic thickening and more rapid tectonic exhumation caused by the subducting of the Indian plate and subsequent break-off of the subducted slab. A great deal of apatite, zircon and sphene fission-track ages, isotopic thermochronology of the rocks in the EHS show that its rapid raising processes of the EHS can be divided into three main periods. There are 35～60Ma, 13～25Ma, 0～3Ma. 3Ma is a turn in the course of raising in the EHS which is characterized by abruptly acceleration of uplifting. The uplift ratios are lower than 1mm .a~(-1) before 3Ma, and higher than 1mm .a~(-1) with a maximum ratio of 30mm .a~(-1) since 3Ma. The bottom (knick point) of the partial anneal belt is 3.8km above sea level in the EHS, and correspond to age of 3Ma determined by fission-track age of apatite. The average uplift ratio is about 1.4 mm .a~(-1) below the knick point. The EHS has raised 4.3km from the surface of 2.36km above sea level since 3Ma estimated by the fossil partial anneal belt of the EHS. We propose a two-stage subduction model (B+A model) basing on Structural, thermochronological, magmatical, metamorphic and geophysical investigations of the EHS. The first stage is the subduction of the Indian continental margin following after the subduction of the Tethys Ocean crust and subsequent collision with the Gangdese arc, and the second stage is the Indian crust injecting into the lower crust and upper mantle of the Tibet plateau. Slab break-off seems to be occurred between these two stages.

胶东地区金矿床成矿时代及其成矿地球动力学背景-兼论壳幔相互作用与成岩成矿

Jiaodong Peninsula is the largest repository of gold in China. Varieties of studies have been involved in the mechanism of metallogenesis. This thesis is a part of the project "Study of basic geology related to the prespecting of the supra-large deposits" which supported by National Climbing Program of China to Prof. Zhou. One of the key scientific problems is to study the age and metallogenic dynamics of ore deposit and to understand how interaction between mantle and crust constrains on metallogenesis and lithogenesis. As Jiaodong Peninsula to be study area, the Rb-Sr, Sm-Nd and Pb isotopic systematics of pyrite and altered rocks are measured to define the age and origin of gold. The elemental and Sr-Nd-Pb isotopic compositions of dikes and granites was studied to implicate the source and lithogenesis of the dike and granite and removal of lithosphere and the interaction between mantle and crust in the Jiaodong Peninsula. Considering the tectonic of Jiaodong Peninsula, basic on the time and space, this thesis gives a metallogenic dynamics of gold mineralization and discusses the constraints of the interaction between mantle and crust on the metallogenesis and lithogenesis. This thesis reports the first direct Rb-Sr dating of pyrites and ores using sub-sampling from lode gold deposit in Linglong, Jiaodong Peninsula and the results demonstrate this as a useful geochronological technique for gold mineralization with poor age constraint. The Rb-Sr data of pyrites yields an isochron age of (121.6-122.7) Ma, whereas, those of ore and ore-pyrite spread in two ranges from 120.0 to 121.8 Ma and 110.0-111.7 Ma. Studies of characteristic of gold deposit, microscopy of pyrite and quartz indicate that the apparent ages of ore and ore-pyrite are not isochron ages, it was only mixed by two end members, i.e., the primitive hydrothermal fluids and wall rocks. However, the isochron age of pyrite samples constrains the age of gold mineralization, i.e., early Cretaceous, which is in good consistence with the published U-Pb ages of zircon by using the SHRIMP technique. The whole rock Rb-Sr isochron age of altered rocks indicates that the age of gold mineralizing in the Xincheng gold deposit is 116.6 ± 5.3 Ma. The Sr, Nd and Pb isotopic compositions of pyrite and altered rocks indicate that the gold and relevant elements were derived from multi-sources, i.e. dikes derived from enriched lithospheric mantle and granites, granodiorites and metamorphic rocks outcropped on the crust. It also shows that the hydrothermal fluids derived from mantle magma degassing had play an important role in the gold mineralizing. The major and trace elements, Sr-Nd-Pb isotopic data of granites and granodiorites suggest that the Linglong Granite and Kunyushan Granite were derived from partial melting of basement rocks in the Jiaodong Peninsula at post-collision of North China Craton with South China Craton. Guojialing Granodiorite was considered to be derived from a mixture source, that is, mixed by magmas derived from an enriched lithospheric mantle and crust during the delamination of lithosphere induced by the subduction of Izanagi Plate and the movement of Tancheng-Lujiang Fault. There are kinds of dikes occurred in the Jiaodong Peninsula, which are accompanying with gold mineralization in time and space. The dikes include gabrro, diabase, pyroxene diorite, gabrrophyre, granite-porphyry, and aplite. The whole rock K-Ar ages give two age intervals: 120-124 Ma for the dikes that erupted at the gold mineralizing stage, and <120 Ma of the dikes that intruded after gold mineralizing. According to the age and the relationship between the dikes and gold mineralizing, the dikes could be divided into two groups: Group I (t = 120-124 Ma) and Group II (t < 120Ma). Group I dikes show the high Mg and K, low Ti contents, negative Nb anomalies and positive Eu anomalies, high ~(87)Sr/~(86)Sr and negative εNd(t) values and an enrichment in light rare earth elements, large ion lithosphile elements and a depletion in high field strength elements. Thus the elemental and isotopic characteristics of the Group I dikes indicate that they were derived from an enriched lithospheric mantle perhaps formed by metasomatism of the melt derived from the recycled crustal materials during the deep subduction of continent. In contrast, the Group II dikes have high Ti, Mg and K contents, no negative Nb anomalies, high ~(87)Sr/~(86)Sr and positive or little negative εNd(t) values, which indicate the derivation from a source like OIB-source. The geochemical features also give the tectonic constraints of dikes, which show that Group I dikes were formed at continental arc setting, whereas Group II dikes were formed within plate background. Considering the tectonic setting of Jiaodong Peninsula during the period of gold mineralizing, the metallogenic dynamics was related to the subduction of Izanagi Plate, movement of Tancheng-Lujiang Fault and removal of lithopheric mantle during Late Mesozoic Era.

晚中生代松辽盆地形成的大地构造环境及成因机制

Directed by the theory of "Collision Tectonic Facies", the tectonic setting and dynamic mechanism of the formation of Songliao basin in late Mesozoic (J_3-K_1) are studied in the present thesis with the methods of petrology, petrochemistry, geochemistry and isotopic geochronology. The research contents in this paper include as followings. Firstly, the general tectonic frame is made up of different tectonic facies formed from Mid-late Proterozoic to Mesozoic, which are Huabei plate, the Chengde-Siziwangqi melange (Pz_1), the Wenduermiao magmatic arc (Pz_1), the Hegenshan-Chaogenshan melange (Pz_2), the accretion arec (Pz_1-P), the Raohe-Hulin melange (Mz), the magmatic arc (Mz) and the pull-apart basin on the magmatic arc (Mz). Secondly, the volcanic rock assemblages of Songliao basin and its adjacent area in late Mesozoic is the typical calc-alkaline of the magmatic arc. The types of volcanic rocks in the study area include basalts, basaltic andesites, andesites, dacites and rhyolites, and basic-intermediate volcanic rocks have higher alkalinity. The volcanic rock series in this area is the high-K calc-alkaline series. Thirdly, the total REE of volcanic rocks in Songliao basin and its adjacent area is higher than that of the chondrite. The pattern of the REE normalized by the chondrite shows the characteristics similar to that of the typical island arcs or the active continental margins in the earth, that is enrichment of LREE and depletion of Eu. The spider-diagram of the trace element normalized by the primitive mantle also expresses the similar features to that of the typical island arcs or the active continental margins, it has distinctive valleies of Nb, Ta, Sr, P, and Ti, as well as the peaks of La, Ce, Th, U, and K. The incompatible elements show that the high field strength elements, such as Nb, Ta, Ti, and P, are depletion while the low field strength elements, such as K, U, Pb, and Ba, are enrichment. These features are similar to those of orogenic volcanic rocks and imply the formation of the volcanic rocks in this area is related to the subduction. The degrees of both the enrichment of the HFS elements and depletion of the LFS elements become more obvious from basic to acid volcanic rocks, which suggests crustal contamination enhances with the magmatic crystallization and fractionation. The concentration of the compatible elements is W-shape, and anomalies in Cr and Ni suggest there is the contamination during the magmatic crystallization and fractionation. Fourthly, the isotopic age data prove the volcanic activity in the Songliao basin and its adjacent area started in the early-middle Jurassic, and ended in the end of the early Cretaceous-the beginning of the Cretaceous. The volcanism summit was the late Jurassic-the early Cretaceous (100 - 150Ma). Finally, the tectonic setting of volcanism in the late Mesozoic was magmatic arc, which originated the subduction of Raohe-Hulin trench to the northwest Asian plate. The subduction began in the middle Jurassic, and the collision orogenesis between the Sikhote-Alin arc and Asian continent was completed in the end of the early Cretaceous-the beginning of the late Cretaceous. The results of above tectonic processes were finally to format Nadanhada orogenic belt symbolized by the Raohe-Hulin suture or melange belt. The violently oblique movement of the Izanagi plate toward Asian plate in the late Mesozoic was the dynamic mechanism of above tectonic processes. At the same tome, the left-lateral strike-slip shear caused by the oblique movement of the Izanagi plate produced a series of strike-slip faults in east Asian margin, and the large scale displacements of these strike-slip faults then produced the pull-apart basing or grabens on the magmatic arc. Conclusively, the tectonic setting during the formation of the grabens of Songliao basin in the late Mesozoic was magmatic arc, and its dynamic mechanism was the pull-apart. In a word, there was a good coupling relation among the oblique subduction of the oceanic plate, collisional orogene between island arc and continental plate, strike-slip shear of the faults and the formation of the grabens in Songliao basin and its adjacent area in late Mesozoic. These tectonic processes were completed in the unoin dynamic setting and mechanism as above description.

北祁连与块状硫化物矿床有关的早古生代火山岩的地球化学研究

Different conclusions from previous work are made from the geochemical study for the early Paleozoic volcanic rocks hosting massive sulfide deposits in the north Qilian Orogen. The main points are: (1)The geochemical characteristics of the basalts and rhyolites from the Baiyin deposit are not consistent with that of the volcanic rocks in the continental rift setting, but show the relationship with subduction. The basalts and rhyolites from the Baiyin deposit are probably individual tectonic slice piled by subduction, and there is no bimodal volcanic rock suite occurred in the Baiyin deposit. Zircon U-Pb dating constrains the magmatic emplacement of basalts and rhyolites at 475±10Ma and 453±12Ma, respectively. The basalts are characterized by enriched Th and Sr, and depleted Nb, Ta and Ti. They have relatively high Th/Nb ratios between 0.9 and 1.3. Their εNd(T) values vary from -1.2 to +3.4. The chemical and isotopic compositions display a typical subduction-related signature, and they suggest that an enriched component with the isotopic composition of EMII might have contributed to the generation of the Baiyin basalts. The basalts were likely formed in a mature island-arc or a volcanic arc built on comparatively young or thin continental crust in an active continental margin. The rhyoIites have low concentrations of LILE compared to the basalts. They do not seen to have a relationship with the basalts, because of their significantly higher εNd(T) values (+4.3～+7.7). The high and positive εNd(T) values also rule out their derivation from anatexis of the continental crust. A modeling study suggests that the source.of the Zhe-Huo and Xiaotieshan rhyolites is similar to boninite and IAT (island-arc tholeiite), and hence indicating an intra-oceanic arc environment. (2) The formation of the Shangliugou volcanic rocks from .Qilian area is also related to subduction. The basaltic andesite have low TiO_2(0.45～0.63%) and P_2O_5(0.04～0.09) content, and high Th/Nb ratios (0.3～0.6). They show flat REE patterns. Their εNd(T) values vary in a narrow range from +4.8 to +6.4. The chemical and isotopic compositions indicate that they are derived from a slightly depleted mantle source and are fromed in intra-island arc setting. The rhyolites show calc-alkaline trend. They show enriched LREE and fiat HREE patterns with obvious negative Eu anomaly. They have high Th/Ta ratios (5.0 ～ 11.7) and large negative εNd(T) values (-2.6 ～ -8.4). The rhyolites are formed in active continental margin and result from a mixed process of two endmembers, or crust assimilation. (3) The metal elements of the volcanic-hosted massive sulfide deposit have two sources, the copper and zinc are derived from rhyolitic magmas whereas the lead are probably related to old sediments overlying the rhyolites. (4) It is suggested here that the volcanic rocks hosting massive sulfide deposit in the north Qilian orogen, which are previously considered as a bimodal suite of Neo-proterozoic to middle Cambrian age in a continental rift, are virtually related to subduction magmatism in Ordovician age, and there might have no continental rift magmatism of Neo-proterozoic to middle Cambrian in the north Qilian.