Gas-phase ion-molecule reactions of C-60 with methyl ethers CH3OCnH2n+1

Gas-phase ion-molecule reactions of buckminsterfullerene (C-60) with the ion systems generated from the self-chemical-ionization of alkyl methyl ethers(CH3OCnH2n+1, n =2 , 3, 4) were studied in the ion source of a mass spectrometer. The adduct cation [C60C2H5O](+) and protonated molecular ion [C60H](+) were observed as the major products, The former was produced by the reactions.of C-60 with the methoxymethyl ion [CH3O = CH2](+) , the latter corresponded to the proton transfer reactions from the protonated alkyl methyl ethers to C60 It is suggested that the [3+2] cycloadduct is the most favorable structure among the probable isomers with special chemical properties, Our investigation provides the guidance for the synthesis of this compound in condensed phase.

Gas-phase ion-molecule reactions of neutral C-60 with alkyl methyl ethers under chemical ionization conditions

Gas-phase ion-molecule reactions of buckminsterfullerene (C-60) with the ion systems generated from the self-chemical ionization of alkyl methyl ethers (CH3OR, R = n-C2H5, n-C3H7, n-C4H9) were studied in the ion source of a mass spectrometer. The adduct cation [C60C2H5O](+) and protonated molecule [C60H](+) were observed as the major products. The former adduct ion was produced by the reactions of C-60 with the methoxymethyl ion [CH3OCH2](+), and the latter resulted from the proton transfer reactions from protonated alkyl methyl ethers to C-60 It is suggested that the [3+2] cycloadduct to a 6-6 bond of C-60 (a C-C bond common to two annulated six-membered rings) is the most favorable structure among the probable isomers of [C60C2H5O](+). (C) 1998 John Wiley & Sons, Ltd.

Gas phase derivations of endohedral metallofullerenes by ion-molecular reactions

Gas phase ion-molecular reactions of endohedral metallofullerenes with the self-chemical ionization ion system of vinyl acetate, benzene and acetone in the ion source of the mass spectrometer have been studied. Several derivatized endohedral metallofullerene cations [M@C-82-C2H3O](+), [M-2@C-80-C2H3O](+), [M@C-82-C6H6](+) and [M@C-82-CO-CH3](+) are observed as the major products. The experimental results indicate that endohedral metallofullerenes have active gas phase reactivities and can be efficiently derivatized by some small organic cations.

Gas-phase ion-molecule reactions of C-60 and theoretical studies of [C60C2H3O](+) adduct cations

Gas-phase ion-molecule reactions of buckminsterfullerene (C-60) with the acetyl cation CH3-C-+=O (m/z 43) and formylmethyl cation (CH2)-C-+-CH=O (m/z 43, or oxiranyl cation), generated from the self-chemical ionization of acetone and vinyl acetate, respectively, were studied in the ion source of a mass spectrometer. Adduct cations [C60C2H3O](+) (m/z 763) and protonated C-60, [C60H](+) (m/z 721), were observed as the major products. AM1 semiempirical molecular orbital calculations on the possible structures, stabilities and charge locations of the isomers of the adducts [C60C2H3O](+) were carried out at the restricted Hartree-Fock level. The results indicated that the sigma-addition product [C-60-COCH3](+) is the most stable adduct for the reaction of C-60 with CH3-C-+=O rather than that resulting from the [2+2] cycloaddition. The [2+3] cycloadduct and the sigma-adduct [C60CH2CHO](+) might be the most possible coexisting products for the reactions of C-60 with (CH2)-C-+-CH=O or oxiranyl cation. Other [C60C2H3O](+) isomers are also discussed. (C) 1997 by John Wiley & Sons, Ltd.

A STUDY OF ION KINETIC-ENERGY SPECTROMETRY OF ORTHO-DICHLORO, META-DICHLORO AND PARA-DICHLORO BENZENE DOUBLY CHARGED IONS [C6H4CL2]2+ AND [C6H3CL]2+ IN GAS-PHASE

The unimolecular Charge separation reactions of the doubly charged ions [C6H4Cl2]2+, [C6H3Cl]2+ produced in the ion source by electron impact from o-, m-, and p-dichloro benzene have been studied using mass analysed ion kinetic energy spectrometry. The values of kinetic energy releases (T) can be calculated from the energy dispersion of product ions. As T essentially reflects the release of coulombic energy, which can be used to calculate the approximate distances R between the two charges immediately before decomposition of the ions. From these data, some structural information about transiton states could be provided. The ECID and CID processes of above doubly charged ions, have also been studied. We found that the CID reactions of (C6H4Cl2)2+ could be used to distinguish three dichloro benzene isomers.

A STUDY OF ION KINETIC ENERGY SPECTROMETRY OF FERROCENE DOUBLY CHARGED IONS IN GAS PHASE

The unimolecular charge separation reactions of the doubly charged ions FeC10H102+, FeC10H theta 2+, FeC10H82+ produced in the ion source by electron impact from ferrocene have been studied using Mass analyzed Ion Kinetic Energy Spectrometry (MIKES) technique. From the values of the kinetic energy releases (T), the intercharge distances (R) of the exploding doubly charged ions in their transition structures have been estimated and some structural informations about the transition states can be obtained. The collision induced reactions of the FeC10H102+ ion with Ar have been studied using MIKES, we postulate a new type of continuing reaction which may be "collisional charge separation induced dissociation".

激光点热源作用下动态微变形的数值模拟与校验

采用MSC．Marc非线性有限元软件，对试件在激光点热源作用下动态微变形过程进行了数值模拟。通过激光反射放大系统测量了试件在激光点热源作用下的动态微变形过程。模拟值与实测值的结果表明：热应力和相变应力的共同作用使得试件产生微变形，最终试件的变形方向取决于热应变和相变共同作用的结果，朝向激光束或背向激光束。比较实验值和模拟值，发现变形的最大值相近，变形过程却略有不同。考虑到激光点热源作用下有限厚度的试件内，温度场分布出现的反常效应，即内部的温度大于边界温度，提出采用波动理论修正经典的热传导计算模型，可望有效地提高模拟过程的计算精度。结论为进一步研究薄板激光弯曲的变形机理及变形过程莫定了基础。

激光同步辐射作为阿秒X射线辐射源的特性研究

研究了逆流相对论电子与激光脉冲相互作用获得激光同步辐射的频率上移、微分散射截面等特性.发现逆流相对论电子与短脉冲激光相互作用,可以获得阿秒X射线辐射脉冲.短脉冲激光条件下得到的后向散射光的频率上移与长脉冲激光条件下得到的后向散射光的频率上移是完全一致的,同时发现随着入射电子初始能量的增加,散射光的准直性越来越好,后向散射光脉冲的脉宽越来越短.

高强度飞秒激光脉冲在空气中的自压缩

利用高重复频率(1kHz)、吉瓦级飞秒激光脉冲实验验证了高强度飞秒脉冲在空气中的自压缩现象，研究了入射脉冲在不同初始啁啾情况下经空气中聚焦成丝后，时域及频域特性随入射脉冲能量的变化规律．实验结果表明，在无需后继色散补偿情况下，高强度飞秒脉冲仅通过在空气中的非线性传输过程就可以实现脉冲压缩；在入射脉冲为负啁啾情况下，实验观察到脉冲光谱及时域宽度同时得到压缩，并可获得比激光源所能提供的更短的近双曲正割型变换限脉冲．

Generation of 5 fs, 0.7 mJ pulses at 1 kHz through cascade filamentation

Two-cycle optical pulses with duration of 5 fs and energy of 0.7 mJ have been generated at 1 kHz by compressing the 38 fs laser pulses from a carrier-envelope phase (CEP) controlled Ti:sapphire laser system through a cascade filamentation compression technique. A simple and effective method is developed to suppress multiple filament formation and stabilize a single filament by inserting a soft aperture with an appropriate diameter into the driving laser beam prior to focusing, resulting in an excellent compressed beam quality. The good beam quality and potentially higher peak power make this ultrashort laser pulse source a significant tool for high-field physics applications. (C) 2007 Optical Society of America.

离子辅助沉积中离子束流密度的作用

测量了End-Hall离子源在不同条件下的离子束流密度，在不同离子束流密度下进行了心离子辅助沉积ZrO2薄膜的实验，研究了离子束流密度对薄膜折射率、晶相的影响．根据动量传递模型分析了离子束流密度对薄膜折射率的作用；根据热尖峰理论证明了一定条件下离子束流密度不会影响薄膜晶体结构。

光学薄膜中界面层和表面吸附层对相位延迟的影响

多层介质反射镜在非正入射的时候，两个不同的偏振态之间会产生不同的相移．根据空气与膜层、膜层之间的实际情况，建立了界面层和表面吸附层模型，并运用它分析相位延迟产生误差的原因．通过优化设计，入射角为54°，在1285～1345nm之间p，s波获得了270±1°的相移，同时也使反射率在99．5％以上．用离子束溅射技术制备相位延迟膜，用分光光度计测试了光谱特性和用椭偏仪测试了相位特性，在相应波段获得了262．4±1．8°的相移，同时也使反射率在99．6％以上．误差的主要来源是离子源工作特性会产生不均匀的过渡层和最

Analysis of the additional modulation of semiconductor lasers using optical heterodyne techniques

In this letter, the power spectrum of a cooled distributed feedback laser module is measured using the self-heterodyne technique. Periodical oscillation peaks have been observed in the measurement. Further investigation shows that the additional modulation signal is coupled from the thermal electric cooler (TEC) controller to the laser driver, and then applied to the laser diode. The additional modulation can be eliminated by properly isolating the laser driving source from the TEC controller.

Narrow-channel-spacing 32-channel arrayed-waveguide-grating multiplexer with an innovative alignment method

A 32-channel 50-GHz spaced arrayed-waveguide grating with our innovative configuration has been designed and fabricated. The performance of the device has been fully tested by using a tunable laser light source, optical power meter, and polarization controller. The insertion loss (IS) of the device is 4.2 similar to 7.4 dB. The crosstalk is about -28 clB. The IS uniformity is less than 3.2 dB. With our configuration, the performance of the device has been enhanced effectively and the difficulty in alignment process has been decreased obviously. (c) 2005 Society of Photo-Optical Instrumentation Engineers.

Micro-fabricated Al0.3Ga0.7As pyramids for potential SPM applications

A novel technique of manufacturing Al0.3Ga0.7As pyramids by liquid phase epitaxy (LPE) for scanning probe microscopy (SPM) sensors is reported Four meticulously designed conditions-partial oxidation, deficient solute, air quenching and germanium doping result in defect-free homogeneous nucleation and subsequent pyramid formation. Micrometer-sized frustums and pyramids are detected by scanning electron microscopy (SEM). The sharp end of the microtip has a radius of curvature smaller than 50 nm. It is believed that such accomplishments would contribute not only to crystal growth theory, but also to miniature fabrication technology.