Construction of coordination networks with high connectivity: a new 8-connected self-penetrating network based on tetranuclear metal clusters

Two highly connected cobalt(II) and zinc(II) coordination polymers with tetranuclear metal clusters as the nodes of network have been prepared, being the first example of an 8-connected self-penetrating net based on a cross-linked alpha-Po subnet.

Metal-organic frameworks based on the pyridine-2,3-dicarboxylate and a flexible bispyridyl ligand: syntheses, structures, and photoluminescence

Three new metal-organic coordination polymers, [Cu(2,3-pydc)(bpp)]center dot 2.5H(2)O (1), [Zn(2,3-pydc)(bpp)]center dot 2.5H(2)O (2) and [Cd(2,3-pydc)(bpp)(H2O)]center dot 3H(2)O (3) (2,3-pydcH(2) = pyridine-2,3-dicarboxylic acid, bpp 1,3-bis(4-pyridyl)propane), have been synthesized at room temvperature. All complexes have metal ions serving as 4-connected nodes but represent two quite different structural motifs. Complexes 1 and 2 are isomorphous, both of which feature 2D -> 3D parallel interpenetration. Each two-dimensional (2D) layer with (4, 4) topology is interlocked by two nearest neighbours, one above and one below, thus leading to an unusual 3D motif. Complex 3 has a non-interpenetrating 3D CdSO4 framework with cavities occupied by uncoordinated water molecules.

Study on computer perception of topological symmetry

A new algorithm for computer perception of topological symmetry is proposed. A node library containing various kinds of nodes is built, and the index number of the library is used as initial atom class identifier (CI) to discriminate the different types of non-hydrogen atoms. The path index (PI) and ringindex (RI) are calculated from the CI, and the global topological enviroment is defined as the sum of PIs and RIs. The topological symmetry can be detected by the iterative calculation of the global topological enviroment.

ALGORITHM FOR COMPUTER PERCEPTION OF TOPOLOGICAL SYMMETRY

For the exhaustive and irredundant generation of candidate structures in ESESOC (Expert System for the Elucidation of the Structures of Organic Compounds), a new algorithm for computer perception of topological equivalence classes of the nodes (non-hydrog

Studies on two coordination polymers [M(mu(4)-pz25dc)](n) (M = Cd or Zn, pz25dc=pyrazine-2,5-dicarboxylato) with three-dimensional pillared-layer three-nodal framework: Synthesis, structural characterization, strong optical non-linearities and optical limiting properties

Two isomorphous new candidates [M(mu(4)-pz25dc)](n) (M = Cd, 1; Zn, 2; pz25dc = pyrazine-2,5-dicarboxylato)for nonlinear optical (NLO) materials have been synthesized hydrothermally and characterized crystallographically as pillared-layer three-nodal frameworks with one four-connected metal nodes and two crystallographically different four-connected ligand nodes. Their optical non-linearities are measured by the Z-Scan technique with an 8 ns pulsed laser at 532 nm. These two coordination polymers both exhibit strong NLO absorptive abilities [alpha(2) = (63 +/- 6) x 10 (12) mW (1) 1, ( 46 +/- 6) x 10 (11) mW (1) 2] and effective self-focusing performance [n(2) = (67 +/- 5) x 10 (18) 1, (13 +/- 3) x 10 (18) m(2) W (1) 2] in 1.02 x 10 (4) 1 and 1.05 x 10 (4) mol dm (3) 2 DMF solution separately. The values of the limiting threshold are also measured from the optical limiting experimental data. The heavy atom effect plays important role in the enhancement of optical non-linearities and optical limiting properties. (C) 2009 Elsevier B. V. All rights reserved.

移动机器人路径规划方法研究

针对室内动态非结构化环境下的移动机器人路径规划问题,提出了一种能够将全局路径规划方法和局部路径规划方法相结合、将基于反应的行为规划和基于慎思的行为规划相结合的路径规划方法.全局路径规划器采用A*算法生成到达目标点的子目标节点序列;局部路径规划器采用改进的人工势场方法对子目标节点序列中相邻两节点进行路径平滑和优化处理.在考虑了移动机器人运动学约束的前提下,该方法不但能够充分利用已知环境信息生成全局最优路径,而且还能及时处理所遇到的随机障碍信息.仿真研究与在室内复杂环境下的实际运行结果验证了该方法的有效性.

一种面向无线传感器网络协同任务分配的动态联盟更新机制

在面向目标追踪等应用的无线传感器网络研究中,协同任务分配机制的研究是很重要的。基于动态联盟机制的协同任务分配方法是事件触发的,适用于任务出现频率相对较低的大规模无线传感器网络。本文在基于动态联盟机制研究的基础上,首先引入了联盟覆盖范围和休眠盟员的概念,进一步消除针对同一任务的检测传感器节点的冗余,降低系统的能量消耗;而后又给出了一种动态联盟的更新机制,以保证动态联盟执行任务时的连续性,在一定程度上保证网络的检测性能。最后通过仿真,从系统总能耗、目标捕获率和检测误差标准差等方面检验了算法的性能,并给出了缓冲带宽度等参数对能耗和网络检测性能的影响。

一种高效覆盖的水下传感器网络部署策略

传感器节点的部署直接关系到水下传感器网络的成本和性能。考虑到传感器节点间具有很强的协同能力,该文提出一种基于检测融合的部署策略。采用Neyman-Pearson准则融合单元网格内所有传感器节点的检测信息,实现正方形和正三角形两种单元网格的高效覆盖,进而分别给出针对两种单元网格的监测区域网格划分方法,从而确定监测区域需要的传感器节点数量以及放置的具体位置。通过仿真实验验证了该部署策略的有效性。结果表明,与不采用检测融合时相比,降低了传感器节点冗余度。使用相同数量的传感器节点,新的部署策略能够在保证一定感知质量的基础之上获得更大的覆盖范围。

传感器网络中无线电干涉定位系统的多径误差分析

根据多径信号的物理特性,从理论上推导了镜反射的多径误差简便模型,基于该模型进行了无线电干涉定位系统的多径误差分析.讨论了衰减因子、天线高度和水平距离等多径参数对测量结果的影响,并且进行了仿真计算和分析.结果表明,高精度定位必须考虑多径效应.

节能有效的无线传感器网络状态信息收集算法

网络状态信息收集协议既要保证信息收集的准确性、实时性,又要保证协议算法的轻量级特性。为解决上述矛盾问题,提出了一种轻量级的、能量有效的、基于无损聚合的层次分簇数据收集机制(QTBDC)。QTBDC首先对网络节点编码并在节点间建立起一个逻辑层次簇结构,然后利用各个子簇状态数据的相似性和编码的连续性,实现了网内无损聚合。该监测机制使得网络状态信息的收集在不丢失数据细节信息的情况下,数据通信量大大减少。经过仿真分析表明,该方法与现有经典数据收集方法相比,实现了节能,延长了网络的生命期。

无线传感器网络中一种启发式最小连通支配集算法

针对最小连通配集问题设计了一种具有较高能量效率的启发式算法。算法首先把网络中所有的节点作为最小连通支配集的一个初始解,然后利用启发式修剪策略剔除冗余节点从而减小最小连通支配集的大小,直到没有冗余节点存在。文中将算法分成集中式和分布式两种情况进行了详细讨论。仿真结果表明,由于实现简便,该算法与其他已有算法相比较,在算法复杂性和算法稳定运行时间上有一定的优势。

基于DSP的动态传感器网络实验平台的设计和开发

介绍了一种基于DSP2812的动态传感器网络实验平台的设计与开发.该实验平台的设计由配备各种低成本、低功耗的传感器和无线通信模块的可移动的传感器节点组成.在介绍动态传感器网络实验平台的各个组成部分之后,对系统进行了的基本实验测试,并给出了测试结果.*

基于TOA的无线传感器网络自定位技术的研究

提出一种基于TOA(tim e of arrival)测距、利用节点之间的几何关系实现传感器网络中未知节点自定位的算法.该方法计算量小、算法简单且定位精度高.仿真实验证明了该方法的有效性.*

轮桨腿一体化两栖机器人控制系统设计

为满足轮桨腿一体化两栖机器人控制系统各模块间信息交换的实时性、灵活性、可扩展性和可靠性的要求,将CAN总线应用于轮桨腿一体化两栖机器人控制系统中。从硬件和软件两方面,介绍了CAN总线在轮桨腿一体化两栖机器人中的应用方案,设计了基于ARM7处理器的CAN总线控制节点,提出了适用于两栖机器人的CAN总线应用层协议方案。

载人潜水器数据采集与监控系统

介绍了基于工业以太网的载人潜水器的数据采集与监控系统。简要地阐述了载人潜水器的重要性。详细地描述了该系统的硬件结构及各智能节点的特点,并对系统中各层所实现的功能进行了详细的介绍。目前,该系统已在实验室进行了实验,实验效果良好。