Noncovalent functionalization of multiwalled carbon nanotubes: Application in hybrid nanostructures

We developed a reproducible, noncovalent strategy to functionalize multiwalled carbon nanotubes (MWNTs) via embedding nanotubes in polysiloxane shells. (3-Aminopropyl)triethoxysilane molecules adsorbed to the nanotube surfaces via hydrophobic interactions are polymerized simply by acid catalysis and form a thin polysiloxane layer. On the basis of the embedded MWNTs, negatively charged gold nanoparticles are anchored to the nanotube surfaces via electrostatic interactions between the protonated amino groups and the gold nanoparticles. Furthermore, these gold nanoparticles can further grow and magnify along the nanotubes through heating in HAuCl4 aqueous solution at 100 degrees C; as a result these nanoparticles are joined to form continuous gold nanowires with MWNTS acting as templates.

Reinforcement of silica with single-walled carbon nanotubes through covalent functionalization

Single-walled carbon nanotubes (SWCNTs) as reinforcing components were extended into silica monoliths and thin films via covalent functionalization for the first time. Silica materials have poor mechanical attributes, which limit their applications. Because of the extreme flexibility of SWCNTs and their large interfacial area, they may be very intriguing as reinforcing fillers for the silica matrix. To get more uniform dispersion and stronger interfacial interaction, SWCNTs were covalently functionalized with silane, and then integrated into silica via a sol - gel process, and their properties were also compared with those of pristine SWCNTs. Results show that the silane-functionalized nanotubes resulted in better mechanical properties ( for example, 33% increase in stress, and 53% increase in toughness), as well as higher electron-transfer kinetics.

Liquid-liquid phase behavior of toluene/polyethylene oxide/poly(ethyleneoxide-b-dimethylsiloxane) polymer-containing ternary mixtures

The experimental data of phase diagrams for both polyethylene oxide/poly(ethylene oxide-b-dimethylsiloxane) binary and toluene/polyethylene oxide/poly(ethylene oxide-b-dimethylsiloxane) ternary polymer-containing systems was obtained at atmosphere pressure by light scattering method. The critical points for some pre-selected compositions and the pressure effect on the phase transition behavior of ternary system were investigated by turbidity measurements. The chosen system is a mixture of ternary which is one of the very few abnormal polymer-containing systems exhibiting pressure-induced both miscibility and immiscibility. This unusual behavior is related to the toluene concentration in the mixtures. The effect of toluene on the phase transition behavior of the ternary polymer-containing mixture was traced. Such behavior can make it possible to process composite materials from incompatible polymers.

Preparation and luminescence properties of ormosil material doped with Eu(TTA)(3)phen complex

The europium complex, Eu(TTA)(3)phen (TTA = thenoyltrifluoroacetone, phen = 1,10-phenanthroline) was successfully doped into organically modified silicate (ormosil) matrix-SiO2/(VTMOS+PMMA) (VTMOS = vinyltrimethoxysilane, PMMA = polymethylmethacrylate) via sol-gel process, and the luminescence properties of the resultant ormosil composite phosphors [ormosil: Eu(TTA)(3)phen were investigated compared with those of the pure Eu(TTA)(3)phen complex powder. The ormosil composite materials incorporated with Eu(TTA)(3)phen show the characteristic red emission of Eu3+ ion. The Eu3+ possesses fewer emission lines and longer lifetime in the hybrid phosphor than in the pure Eu(TTA)(3)phen complex. This has been explained from the viewpoint of the surrounding environment where the Eu3+ ion lies. (C) 2000 Elsevier Science B.V. All rights reserved.

Confined crystallization behavior of PEO in silica networks

Poly(ethylene oxide) (PEO) and silica (SiO2) organic-inorganic hybrid materials have been synthesized by sol-gel approach. The crystallization behavior of PEO in silica networks has been investigated by differential scanning calorimeter (DSC) and scanning electron micrograph (SEM). The degree of PEO crystallinity in PEO/SiO2 hybrid networks reduces with the increase of SiO2. PEO is in amorphous state when the concentration of PEO is lower than 50 wt% in the hybrid materials. The melting points of PEO in the networks are lower than that of pure PEG, but the melting point of PEO in the networks almost has the same melting point. WAXD and SEM results show that the crystalline behavior of PEO in PEO/SiO2 hybrid system is sternly confined. (C) 1999 Elsevier Science Ltd. All rights reserved.

Crystallization behavior of PCL in hybrid confined environment

Poly(epsilon -caprolactone) (PCL) and silica (SiO2) organic-inorganic hybrid materials have been synthesized by the sol-gel method. The crystallization behavior of PCL in silica networks has been investigated using differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The degree of PCL crystallinity in PCL/SiO2 hybrid networks reduces with increase of SiO2. PCL is in an amorphous state when the concentration of PCL is lower than 40wt% in the hybrid system. The melting point of PCL in the networks is lower than, but close to that of pure PCL. WAXD and SEM results show that the crystalline behavior of PCL in PCL/SiO2 hybrid system is strictly confined. (C) 2001 Elsevier Science Ltd. All rights reserved.

Dielectric responses of anisotropic graded granular composites having arbitrary inclusion shapes

The transformation field method (TFM) originated from Eshelby's transformation field theory is developed to estimate the effective permittivity of an anisotropic graded granular composite having inclusions of arbitrary shape and arbitrary anisotropic grading profile. The complicated boundary-value problem of the anisotropic graded composite is solved by introducing an appropriate transformation field within the whole composite region. As an example, the effective dielectric response for an anisotropic graded composite with inclusions having arbitrary geometrical shape and arbitrary grading profile is formulated. The validity of TFM is tested by comparing our results with the exact solution of an isotropic graded composite having inclusions with a power-law dielectric grading profile and good agreement is achieved in the dilute limit. Furthermore, it is found that the inclusion shape and the parameters of the grading profile can have profound effect on the effective permittivity at high concentrations of the inclusions. It is pointed out that TFM used in this paper can be further extended to investigate the effective elastic, thermal, and electroelastic properties of anisotropic graded granular composite materials.

自动化制造系统的产生与发展

探讨了自动化与制造业的产生和互促发展过程 ,论述了自动化制造系统的形成和不同发展阶段的内涵及重大作用 ,指出自动化技术与制造技术是驱动自动化制造系统发展的两个轮子 ,不能忽视任何一个侧面 ,自动化研究与制造技术研究相结合是发展先进制造技术的必由之路

我国制造业面临的内外形势及对策研究──抓住机遇,参加全球化敏捷生产体系

：本文从信息时代对人们认识上的影响，讨论了信息时代对生产、对统一的世界市场、对社会的影响。列举了世界经济进入新的繁荣期的特征。讨论了世界生产的形成和发展，市场竞争的三准则，市场竞争的各个历史阶段及全球化敏捷制造体系迅速发展的原因。分析了二十一世纪制造业面临的形势。详细地讨论了我国国有大中型企业的主要问题：1．产品问题；2．企业结构不合理；3．管理问题；4．质量问题；5．工艺手段和装备落后；6．历史包袱沉重等。提出了利用世界全球化生产体系发展的大好形势的三条对策：1．利用敏捷制造原理对企业进行重组；2．加速产品设计队伍的重建，增强新产品的设计能力；3．利用现代化手段实现现代化管理。

机器人及机器人学中的控制问题

机器人已成为进一步实现制造业、非制造业、军事活动以至家庭服务自动化的重要工具.机器人学则是更综合地研究如何使机器或系统具有“思想、感知或动作功能的一门交叉性新学科”.机器人的发展是波浪式的,经历了多次的曲折.目前工业机器人中除装配机器人外,其他点焊、弧焊、喷漆及搬运机器人,由于应用范围限制,以及工业生产装备更新速度和投资规模的影响,市场日趋饱和.以美国为例.制造商订单1984年达到高峰6046台.至1986年下降至5713台,不过对机器人未来市场大都持乐观态度.但进一步开拓市场.有待于推出适用于各种环境作业的各式各样的机器人.日本东京大学教授认为机器人当前处于又一次高潮的前夜(Nightmare),正是需要大力加强研究开发的时期.我国正在着手建立工业机器人产业,这一情况值得我们注意.本文着重从研究角度来介绍当前机器人及机器人学中的控制问题的现状及主要问题.