四苯基丁二烯基稀土五元不饱和环状化合物的合成

本文通过元素分析、红外光谱、核磁共振谱的测定以及对化合物水解产物的分析，确认合成了下述四种新型的稀土金属有机化合物：这些化合物可溶于苯、甲苯及四氢呋喃，不溶于汽油和氯仿等溶剂，对水和空气极为敏感，二价铵的化合物在空气中自燃。化合物的红外光谱图中在3010，1490，700cm~(-1)处出现苯基的特征。吸收峰，在1070cm~(-1)和480cm~(-1)处出现四氢呋喃及稀土—氯键的特征吸收峰。化合物L_nC_4(C_6H_5)_4R·nTHF(R = C_5H_5, C_9H_7)的红外光谱图中在1015cm~(-1)处出现环戊二烯基及茚基的特征吸收峰。对化合物水解产物的分析结果表明，化合物经水解后生成四苯基丁二烯。化合物N_dC_4(C_6H_5)_4ClLiCl·2THF同AlH(i-Bu)_2组成的催化剂可溶于甲苯中形成均相催化体系，对丁二烯有较高的催化聚合活性，而在加氢汽油中催化剂基本不溶，对丁二烯的催化聚合活性明显低于甲苯体系。

基于silica波导光栅的单纤三向器的混合集成研究

通过有源实时监控系统,采用手动和自动相结合的方法,将光纤、silica基阵列波导光栅(AWG)、1310 nm激光器(LD)平台和1490 nm、1550 nm探测器(PD)平台用紫外同化胶混合集成为一新型单纤三向器.在耦合集成过程中,LD在15 mA偏置电流下,三向器的上行出纤功率大约为-4 dBm,LD和波导的耦合效率大约40%;当三向器输入1 550 nm光功率为1 mW,PD在2.6 V反向偏压下,下行输出光电流大约为76 μA,波导和PD的耦合效率大约为42%.三向器中采用了对管PD集成方法.

Triplexers Based on SOI Flattop AWGs

Triplexers are designed based on SOl flattop arrayed waveguide gratings （AWGs）. Three wavelengths （1310, 1490,and 1550nm） operate at three diffraction orders of AWGs. Simulation shows that the 3dB bandwidth,crosstalk, and loss are 6nm,less than -40dB, and 5dB, respectively. The output optical fields of the device fabricated in our laboratory are clear and show a good triplexing function.

一种新型的5GHz自适应偏置及可变增益低噪声放大器

该文提出了一种新型的自适应偏置及可变增益低噪声放大器（LNA），利用电荷泵（亦称电压倍增器）将LNA输出信号转换成与LNA射频输入信号功率成比例变化的直流信号，以此信号同时反馈控制LNA的偏置和增益，来实现自适应偏置以及可变增益低噪声放大器。从而极大地改善了LNA的输入线性范围。鉴于5GHz频率下，Bipolar相对于CMOS更好的频率特性和低噪声特性，该项研究采用了BiCMOS工艺，实现了低于3．0dB的噪声系数（高增益状态下）和大约13dBm的输入三阶交调点ⅡP3的控制范围以及大于15dB的增益控制范围。

MOCVD-Grown AlGaN/AlN/GaN HEMT Structure with High Mobility GaN Thin Layer as Channel on SiC

AlGaN/AlN/GaN high electron mobility transistor (HEMT) structures with a high-mobility GaN thin layer as a channel are grown on high resistive 6H-SiC substrates by metalorganic chemical vapor deposition. The HEMT structure exhibits a typical two-dimensional electron gas (2DEG) mobility of 1944cm2/(V · s) at room temperature and 11588cm2/(V· s) at 80K with almost equal 2DEG concentrations of about 1.03 × 1013 cm-2 High crystal quality of the HEMT structures is confirmed by triple-crystal X-ray diffraction analysis. Atomic force microscopy measurements reveal a smooth AlGaN surface with a root-mean-square roughness of 0. 27nm for a scan area of 10μm × 10μm. HEMT devices with 0.8μm gate length and 1.2mm gate width are fabricated using the structures. A maximum drain current density of 957mA/mm and an extrinsic transconductance of 267mS/mm are obtained.

Wide-Band Polarization-Independent Semiconductor Optical Amplifier Gate with Tensile-Strained Quasi-Bulk InGaAs

A semiconductor optical amplifier gate based on tensile-strained quasi-bulk InGaAs is developed. At injection current of 80mA,a 3dB optical bandwidth of more than 85nm is achieved due to dominant band-filling effect.Moreover, the most important is that very low polarization dependence of gain (＜0. 7dB),fiber-to-fiber lossless operation current (70～90mA) and a high extinction ratio (＞50dB) are simultaneously obtained over this wide 3dB optical bandwidth (1520～1609nm) which nearly covers the spectral region of the whole C band (1525～1565nm)and the whole L band (1570～ 1610nm). The gating time is also improved by decreasing carrier lifetime. The wideband polarization-insensitive SOA-gate is promising for use in future dense wavelength division multiplexing (DWDM) communication systems.

Investigation of high cycle and Very-High-Cycle Fatigue behaviors for a structural steel with smooth and notched specimens

The high cycle and Very-High-Cycle Fatigue (VHCF) properties of a structural steel with smooth and notched specimens were studied by employing a rotary bending machine with frequency of 52.5 Hz. For smooth specimens, VHCF failure did occur at fatigue cycles of 7.1 x 10(8) with the related S-N curve of stepwise tendency. Scanning Electron Microscopy (SEM) was used for the observations of the fracture surfaces It shows that for smooth specimens the crack origination is surface mode in the failure regime of less than 10(7) cycles While at VHCF regime, the material failed from the nonmetallic inclusion lies in the interior of material, leading to the formation of fisheye pattern. The dimensions of crack initiation region were measured and discussed with respect to the number of cycles to failure. The mechanism analysis by means of low temperature fracture technique shows that the nonmetallic inclusion in the interior of specimen tends to debond from surrounding matrix and form a crack. The crack propagates and results to the final failure. The stress intensity factor and fatigue strength were calculated to investigate the crack initiation properties. VHCF study on the notched specimens shows that the obtained S-N curve decreases continuously. SEM analysis reveals that multiple crack origins are dominant on specimen surface and that fatigue crack tends to initiate from the surface of the specimen. Based on the fatigue tests and observations, a model of crack initiation was used to describe the transition of fatigue initiation site from subsurface to surface for smooth and notched specimens. The model reveals the influences of load, grain size, inclusion size and surface notch on the crack initiation transition. (C) 2010 Elsevier Ltd. All rights reserved

同位旋非对称核物质状态方程

为了确定同位旋非对称核物质状态方程,利用同位旋有关的量子分子动力学理论计算和寻找实验上对于中能重离子碰撞中核子-核子碰撞截面或者对称势非常灵敏的物理观测量——探针.结果发现了几种分别对于核子-核子碰撞截面或者对称势非常灵敏的物理观测量.并对这些探针的机理进行了仔细研究,对以上研究结果进行小结和讨论,并为今后继续深入研究工作提出展望.