462 resultados para capillary electrochromatography
Resumo:
We investigate the surface deformations of buoyant-thermocapillary convection in a rectangular cavity clue to gravity and temperature gradient between the two sidewalls. The cavity is 52mm x 42mm in horizontal cross section, the thickness of liquid layer h is changed from 2.5mm to 6.5mm. Surface deformations of h = 3.5mm and 6.0mm are discussed and compared. Temperature difference is increased gradually, and the flow in the liquid layer will change from stable convection to unstable convection. Two kinds of optical diagnostic system with image processor are developed for study of the kinetics of buoyant-thermocapillary convection, they give out the information of liquid free surface. The quantitative results are calculated by Fourier transform and correlation analysis, respectively. With the increasing temperature gradient, surface deformations calculated are more declining. It is interesting phenomenon that the inclining directions of the convections in thin and thick liquid layers are different. For a thin layer, the convection is mainly controlled by thermocapillary effect. However, for a thick layer, the convection is mainly controlled by buoyancy effect. The surface deformation theoretically analysed is consistent with our experimental results. The present experiment proves that surface deformation is related to temperature gradient and thickness of the liquid layer. In other words, surface deformation lies on capillary convection and buoyancy convection.
Resumo:
A set of scaling criteria of a polymer flooding reservoir is derived from the governing equations, which involve gravity and capillary force, compressibility of water, oil, and rock, non-Newtonian behavior of the polymer solution, absorption, dispersion, and diffusion, etc. A numerical approach to quantify the dominance degree of each dimensionless parameter is proposed. With this approach, the sensitivity factor of each dimensionless parameter is evaluated. The results show that in polymer flooding, the order of the sensitivity factor ranges from 10(-5) to 10(0) and the dominant dimensionless parameters are generally the ratio of the oil permeability under the condition of the irreducible water saturation to water permeability under the condition of residual oil saturation, density, and viscosity ratios between water and oil, the reduced initial oleic phase saturation and the shear rate exponent of the polymer solution. It is also revealed that the dominant dimensionless parameters may be different from case to case. The effect of some physical variables, such as oil viscosity, injection rate, and permeability, on the dominance degree of the dimensionless parameters is analyzed and the dominant ones are determined for different cases.
Resumo:
Singular perturbation theory of two-time-scale expansions was developed in inviscid fluids to investigate patternforming, structure of the single surface standing wave, and its evolution with time in a circular cylindrical vessel subject to a vertical oscillation. A nonlinear slowly varying complex amplitude equation, which involves a cubic nonlinear term, an external excitation and the influence of surface tension, was derived from the potential flow equation. Surface tension was introduced by the boundary condition of the free surface in an ideal and incompressible fluid. The results show that when forced frequency is low, the effect of surface tension on the mode selection of surface waves is not important. However, when the forced frequency is high, the surface tension cannot be neglected. This manifests that the function of surface tension is to cause the free surface to return to its equilibrium configuration. In addition, the effect of surface tension seems to make the theoretical results much closer to experimental results.
Resumo:
Die swell is an important, phenomenon. in polymer processing, and is explained usually by rheological properties of the fluid. Because of the nonuniform of temperature distribution on the free surface of the liquid jet, the thermo capillary convection driven by surface tension gradient exists. The rheological fluid flowing out of a die and painting on a moving solid wall is studied by the numerical finite element method of a two-dimensional and unsteady model in the present paper, and both the rheological effect of a non-Newtonian fluid and the thermocapillary effect are considered. The results show that both,effects; will enlarge the cross-section of the fluid jet, and the rheological effect of non-Newtonian fluid dominates the process in general.
Resumo:
Capillary forces are dominant in adhesive forces measured with an atomic force microscope (AFM) in ambient air, which are thought to be dependent on water film thickness, relative humidity and the free energy of the water film. In this paper, besides these factors, we study the nature of the 'pull-off' force on a variety of atmospheres as a function of the contact time. It is found that capillary forces strongly depend on the contact time. In lower relative humidity atmosphere, the adhesion force is almost independent of the contact time. However, in higher relative humidity, the adhesion force increases with the contact time. Based on the experiment and a model that we present in this paper, the growth of the liquid bridge can be seen as undergoing two processes: one is water vapour condensation; the other is the motion of the thin liquid film that is absorbed on the substrate. The experiment and the growth model presented in this paper have direct relevance to the working mechanism of AFM in ambient air.
Resumo:
In this paper, the effect of the surface tension is considered carefully in the study of non-propagating solitary waves. The parameter plane of the surface tension and the fluid depth is divided into three regions; in two of them a breather soliton can be produced. In literature the parameters of breather solitons are all in one of the parameter regions. The new region reported here has been confirmed by our experiments. In the third region, the theoretical solution is a kink soliton, but a kind of the non-propagating solitary wave similar to the breather soliton was found in our experiments besides the kink soliton.
Resumo:
This paper deals with the steady axi-symmetric thermo-capillary motion in a short meltingcolumn.with the assumptions that the Marangoni number M<<1, the Reynolds number Re<<1 andthe capillary number C<<1, at the leading order, the solutions of the problem are obtained inthe form of series. For two kinds of typical cases, symmetric and anti-symmetric distributionof air temperature, the numerical calculations are made. The results describe the effect ofendwalls on thermo-capillary flow.
Resumo:
空间探索计划的需求对空间流体管理技术提出了新的挑战.流体管理设备的内角是主要的流体传输"管道",因此研究微重力下容器内角处的毛细驱动流具有重要的意义.由于设计和制造等原因,完美的尖角并不常见,而是带有一定圆角过渡的内角.笔者设计不同的带有圆形过渡内角的容器,选用10cSt硅油为实验流体介质,通过一系列的落塔实验,研究了容器内角处不同的圆角半径对毛细驱动流的影响,并分析得到了有价值的实验规律.
Resumo:
在竖直振动的圆柱形容器中,利用理想流体中两时间尺度奇摄动展开法,研究了包括表面张力影响的自由面单一表面驻波的运动.通过求解势流方程,获得了一个包含三阶非线性项、外激励及表面张力影响的非线性振幅方程.结果表明当驱动频率较低时,表面张力对表而波模式选择不重要;然而,当驱动频率较高时,表面张力的影响是不可忽略的.说明表面张力具有使得自由面返回到平衡位置的作用.另外,由于考虑了表面张力的影响,使得理论结果比无表面张力时更加接近先前的实验结果.
Resumo:
An optical diagnostic system consisting of Michelson interferometer with image processor has been developed for study of the kinetics of thermal capillary convection and buoyancy convection. This optical interferometer has been used to observe and measure surface deformation and surface wave of capillary convection and buoyancy convection in a rectangular cavity with different temperature’s sidewalls. Fourier transformation is used to image processing. The quantitative results of surface deformation and surface wave have been calculated from the interference fringe pattern. With the increasing of temperature gradient, the liquid surface slant gradually. It’s deformation has been calculated, which is related directly with temperature gradient. This is one of the characters introducing convection. Another interesting phenomenon is the inclining direction, which is different when the liquid layer is thin or thick. When the liquid layer is thin, convection is mainly controlled by thermocapillary effect. However, When the liquid layer is thick, convection is mainly controlled by buoyancy effect. Surface deformation in the present experiment are more and more declining in this process. The present experiment proved that surface deformation appears before the appearance of surface wave on fluid convection, it is related with temperature gradient, and the height of liquid layer, and lies on capillary convection and buoyancy convection. The present experiment also demonstrates that the amplitude of surface wave of thermocapillary-buoyancy convection is much smaller than surface deformation, the wave is covered by deformation.
Resumo:
A dynamic 3D pore-scale network model is formulated for investigating the effect of interfacial tension and oil-water viscosity during chemical flooding. The model takes into account both viscous and capillary forces in analyzing the impact of chemical properties on flow behavior or displacement configuration, while the static model with conventional invasion percolation algorithm incorporates the capillary pressure only. From comparisons of simulation results from these models. it indicates that the static pore scale network model can be used successfully when the capillary number is low. With the capillary increases due to the enhancement of water viscosity or decrease of interfacial tension, only the quasi-static and dynamic model can give insight into the displacement mechanisms.
Resumo:
The microgravity research, as a branch of the advanced sciences and a spe- cialized field of high technology, has been made in China since the late 1980's. The research group investigating microgravity fluid physics consisted of our col- leagues and the authors in the Institute of Mechanics of the Chinese Academy of Sciences (CAS), and we pay special attention to the floating zone convection as our first research priority. Now, the research group has expanded and is a part of the National Microgravity Laboratory of the CAS, and the research fields have been extended to include more subjects related to microgravity science. Howev- er, the floating zone convection is still an important topic that greatly holds our research interests.
目录
1.1 floating-zone crystal growth
1.2 physical model
1.3 hydrodynamic model
1.4 mathematical model
references
2. basic features of floating zone convection
2.1 equations and boundary conditions
2.2 simple solutions of fz convection
2.3 solution for two-layers flow
2.4 numerical simulation
2.5 onset of oscillation
references
3. experimental method of fz convection
3.1 ground-based simulation experiments for pr≥1
3.2 temperature and velocity oscillations
3.3 optical diagnostics of free surface oscillation
3.4 critical parameters
3.5 microgravity experiments
3.6 ground-based simulation experiment for pr《1
4. mechanism on the onset of oscillatory convection
4.1 order of magnitude analysis
4.2 mechanism of hydrothermal instability
4.3 linear stability analysis
4.4 energy instability of thermocapillary convection
4.5 unsteady numerical simulation of 2d and 3d
4.6 two bifurcation transitions in the case of small pr number fluid
4.7 two bifurcation transitions in the case of large pr number fluid
4.8 transition to turbulence
references
5. liquid bridge volume as a critical geometrical parameter
5.1 critical geometrical parameters
5.2 ground-based and mierogravity experiments
5.3 instability analyses of a large prandtl number (pr≥1)fluid
5.4 instability analyses of a small prandtl number (pr《1)fluid
5.5 numerical simulation on two bifurcation process
references
6. theoretical model of crystal growth by the floating zone method
6.1 concentration distribution in a pure diffusion process
6.2 solutal capillary convection and diffusion
6.3 coupling with phase change convection
6.4 engineering model of floating zone technique
references
7. influence of applied magnetic field on the fz convection
7.1 striation due to the time-dependent convection
7.2 applied steady magnetic field and rotational magnetic field
7.3 magnetic field design for floating half zone
7.4 influence of magnetic field on segregation
references
8. influence of residual acceleration and g-jitter
8.1 residual acceleration in microgravity experiments
8.2 order of magnitude analyses (oma)
8.3 rayleigh instability due to residual acceleration
8.4 ground-based experiment affected by a vibration field
8.5 numerical simulation of a low frequency g-jitter
8.6 numerical simulation of a high frequency g-jitter
references
Resumo:
Poly(dimethylsiloxane) (PDMS) is usually considered as a dielectric material and the PDMS microchannel wall can be treated as an electrically insulated boundary in an applied electric field. However, in certain layouts of microfluidic networks, electrical leakage through the PDMS microfluidic channel walls may not be negligible, which must be carefully considered in the microfluidic circuit design. In this paper, we report on the experimental characterization of the electrical leakage current through PDMS microfluidic channel walls of different configurations. Our numerical and experimental studies indicate that for tens of microns thick PDMS channel walls, electrical leakage through the PDMS wall could significantly alter the electrical field in the main channel. We further show that we can use the electrical leakage through the PDMS microfluidic channel wall to control the electrolyte flow inside the microfluidic channel and manipulate the particle motion inside the microfluidic channel. More specifically, we can trap individual particles at different locations inside the microfluidic channel by balancing the electroosmotic flow and the electrophoretic migration of the particle.
Resumo:
The development and growth of microfluidics has stimulated interest in the behaviour of complex liquids in micro-scale geometries and provided a rich platform for rheometric investigations of non-Newtonian phenomena at small scales. Microfluidic techniques present the rheologist with new opportunities for material property measurement and this review discusses the use of microfluidic devices to measure bulk rheology in both shear and extensional flows. Capillary, stagnation and contraction flows are presented in this context and developments, limitations and future perspectives are examined. (C) 2008 Elsevier Ltd. All rights reserved.
Resumo:
Electrowetting on dielectrics has been widely used to manipulate and control microliter or nanoliter liquids in micro-total-analysis systems and laboratory on a chip. We carried out experiments on electrowetting on a lotus leaf, which is quite different from the equipotential plate used in conventional electrowetting. This has not been reported in the past. The lotus leaf is superhydrophobic and a weak conductor, so the droplet can be easily actuated on it through electrical potential gradient. The capillary motion of the droplet was recorded by a high-speed camera. The droplet moved toward the counterelectrode to fulfill the actuation. The actuation speed could be of the order of 10 mm/s. The actuation time is of the order of 10 ms.