Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in sol-gel-derived ceramic-carbon nanotube nanocomposite film

The sol-gel-derived ceramic-carbon nanotube (SGCCN) nanocomposite film fabricated by doping multiwall carbon nanotubes (MWNTs) into a silicate get matrix was used to immobilize protein. The SGCCN film can provide a favorable microenvironment for horseradish peroxidase (HRP) to perform direct electron transfer (DET) at glassy carbon electrode. The HRP immobilized in the SGCCN film shows a pair of well-defined redox waves and retains its bioelectrocatalytic activity to the reduction of O-2 and H2O2, which is superior to that immobilized in silica sol-gel film.

Influence of the earth rotation on the interfacial wave solutions and wave-induced tangential stress in a two-layer fluid system

Interfacial waves and wave-induced tangential stress are studied for geostrophic small amplitude waves of two-layer fluid with a top free surface and a flat bottom. The solutions were deduced from the general form of linear fluid dynamic equations of two-layer fluid under the f-plane approximation, and wave-induced tangential stress were estimated based on the solutions obtained. As expected; the solutions derived from the present work include as special cases those obtained by Sun et al. (2004. Science in China, Set. D, 47(12): 1147-1154) for geostrophic small amplitude surface wave solutions and wave-induced tangential stress if tire density of the upper layer is much smaller than that of the lower layer. The results show that the interface and the surface will oscillate synchronously, and the influence of the earth's rotation both on the surface wave solutions and the interfacial wave solutions should be considered.

The effects of random surface waves on the steady Ekman current solutions

The response of near-surface current profiles to wind and random surface waves are studied based on the approach of Jenkins [1989. The use of a wave prediction model for driving a near surface current model. Dtsch. Hydrogr. Z. 42,134-149] and Tang et al. [2007. Observation and modeling of surface currents on the Grand Banks: a study of the wave effects on surface currents. J. Geophys. Res. 112, C10025, doi:10.1029/2006JC004028]. Analytic steady solutions are presented for wave-modified Ekman equations resulting from Stokes drift, wind input and wave dissipation for a depth-independent constant eddy viscosity coefficient and one that varies linearly with depth. The parameters involved in the solutions can be determined by the two-dimensional wavenumber spectrum of ocean waves, wind speed, the Coriolis parameter and the densities of air and water, and the solutions reduce to those of Lewis and Belcher [2004. Time-dependent, coupled, Ekman boundary layer solutions incorporating Stokes drift. Dyn. Atmos. Oceans. 37, 313-351] when only the effects of Stokes drift are included. As illustrative examples, for a fully developed wind-generated sea with different wind speeds, wave-modified current profiles are calculated and compared with the classical Ekman theory and Lewis and Belcher's [2004. Time-dependent, coupled, Ekman boundary layer solutions incorporating Stokes drift. Dyn. Atmos. Oceans 37, 313-351] modification by using the Donelan and Pierson [1987. Radar scattering and equilibrium ranges in wind-generated waves with application to scatterometry. J. Geophys. Res. 92, 4971-5029] wavenumber spectrum, the WAM wave model formulation for wind input energy to waves, and wave energy dissipation converted to currents. Illustrative examples for a fully developed sea and the comparisons between observations and the theoretical predictions demonstrate that the effects of the random surface waves on the classical Ekman current are important, as they change qualitatively the nature of the Ekman layer. But the effects of the wind input and wave dissipation on surface current are small, relative to the impact of the Stokes drift. (C) 2008 Elsevier Ltd. All rights reserved.

Second-order solutions for random interfacial waves under steady uniform currents

In the present research, the study of Song (2004) for random interfacial waves in two-layer fluid is extended to the case of fluids moving at different steady uniform speeds. The equations describing the random displacements of the density interface and the associated velocity potentials in two-layer fluid are solved to the second order, and the wave-wave interactions of the wave components and the interactions between the waves and currents are described. As expected, the extended solutions include those obtained by Song (2004) as one special case where the steady uniform currents of the two fluids are taken as zero, and the solutions reduce to those derived by Sharma and Dean (1979) for random surface waves if the density of the upper fluid and the current of the lower fluid are both taken as zero.

Second-order solutions for random interfacial waves in N-layer density-stratified fluid with steady uniform currents

In the present paper, the random inter facial waves in N-layer density-stratified fluids moving at different steady uniform speeds are researched by using an expansion technique, and the second-order a symptotic solutions of the random displacements of the density interfaces and the associated velocity potentials in N-layer fluid are presented based on the small amplitude wave theory. The obtained results indicate that the wave-wave second-order nonlinear interactions of the wave components and the second-order nonlinear interactions between the waves and currents are described. As expected, the solutions include those derived by Chen (2006) as a special case where the steady uniform currents of the N-layer fluids are taken as zero, and the solutions also reduce to those obtained by Song (2005) for second-order solutions for random interfacial waves with steady uniform currents if N=2.

Depth inversion in coastal water based on SAR image of waves

Wave-number spectrum technique is proposed to retrieve coastal water depths by means of Synthetic Aperture Radar (SAR) image of waves. Based on the general dispersion relation of ocean waves, the wavelength changes of a surface wave over varying water depths can be derived from SAR. Approaching the analysis of SAR images of waves and using the general dispersion relation of ocean waves, this indirect technique of remote sensing bathymetry has been applied to a coastal region of Xiapu in Fujian Province, China. Results show that this technique is suitable for the coastal waters especially for the near-shore regions with variable water depths.

Numerical Simulation of Waves Generated by Seafloor Movements

Waves generated by vertical seafloor movements are simulated by use of a fully nonlinear two-dimensional numerical wave tank. In the source region, the seafloor lifts to a designated height by a generation function. The numerical tests show that file linear theory is only valid for estimating the wave behaviors induced by the seafloor movements with a small amplitude, and the fully nonlinear numerical model should be adopted in the simulation of the wave generation by the large amplitude seafloor movements. Without the background surface waves, many numerical tests on the stable maximum elevations eta(max)(0) are carried out by both the linear theory and the fully nonlinear model. The results of two models are compared and analyzed. For the fully nonlinear model, the influences of the amplitudes and the horizontal lengths on eta(max)(0) are stronger than that of the characteristic duration times. Furthermore, results reveal that there are significant differences between the linear theory and the fully nonlinear model. When the influences of the background surface waves are considered, the corresponding numerical analyses reveal that with the fully nonlinear model the eta(max)(0) near-linearly varies with the wave amplitudes of the surface waves, and the eta(max)(0) has significant dependences on the wave lengths and the wave phases of the surface waves. In addition, the differences between the linear theory and the fully nonlinear model are still obvious, aid these differences are significantly affected by The wave parameters of the background surface waves, such as the wave amplitude, the wave length and the wave phase.

Second-order Stokes wave solutions for intefacial waves in three-layer stratified fluid with background current

In this paper, interfacial waves in three-layer stratified fluid with background current are investigated using a perturbation method, and the second-order asymptotic solutions of the velocity potentials and the second-order Stokes wave solutions of the associated elevations of the interfacial waves are presented based on the small amplitude wave theory, and the Kelvin-Helmholtz instability of interfacial waves is studied. As expected, for three-layer stratified fluid with background current, the first-order asymptotic solutions (linear wave solutions), dispersion relation and the second-order asymptotic solutions derived depend on not only the depths and densities of the three-layer fluid but also the background current of the fluids, and the second-order Stokes wave solutions of the associated elevations of the interfacial waves describe not only the second-order nonlinear wave-wave interactions between the interfacial waves but also the second-order nonlinear interactions between the interfacial waves and currents. It is also noted that the solutions obtained from the present work include the theoretical results derived by Chen et al (2005) as a special case. It also shows that with the given wave number k (real number) the interfacial waves may show Kelvin-Helmholtz instability.

Fine sediment resuspension dynamics in Moreton Bay

A comprehensive field study has been undertaken to investigate sediment resuspension dynamics in the Moreton Bay, a large semi-enclosed bay situated in South East Queensland, Australia. An instrumented tripod, which housed three current meters, three OBS sensors and one underwater video camera, was used to collect the field data on tides, currents, waves and suspended sediment concentrations at four sites (Sites 1, 2, 4, and 5) in the bay. Site I was located at the main entrance, Site 2 at the central bay in deep water, and Sites 4 and 5 at two small bays in shallow water. The bed sediment was fine sand (d(50) = 0. 2 mm) at Site 1, and cohesive sediment at the other three sites. Based on the collected field data, it is found that the dominant driving forces for sediment resuspension are a combination of ocean swell and tidal currents at Site 1, tidal currents at Site 2, and wind-waves at Sites 4 and 5. The critical bed shear stress for cohesive sediment resuspension is determined as 0. 079 Pa in unidirectional flow at Site 2, and 0. 076 Pa in wave-induced oscillatory flow at Site 5.

南海文昌海域内波特征研究

2005年中科院海洋所对琼东文昌海域进行了精细内波观测。本文对此次观测所获得的资料进行分析，研究了观测海域内孤立波、内潮、内波波致流和内波传播方向的统计特征，得到观测海域内波的基本特征。首先，观测海域内孤立波频繁发生。在149天的观测当中，一共出现140个孤立波列，出现频率达到了0.94次/天。出现频率最高的振幅是32米，最常见的内孤立波持续时间时20分钟。80%的内孤立波都在以下范围之内：持续时间从13分钟到32分钟，振幅从16米到46米。在这一区间范围之类，内孤立波的持续时间和振幅并没有明显的函数关系，表现出随机分布的特征。同时内孤立波的振幅有着明显的季节变化特征。从4月中旬到6月中旬内孤立波频繁出现且振幅较大，振幅超过35米的内孤立波相当常见；而6月中旬到9月中旬，内孤立波的发生频率明显下降，振幅也偏低，振幅超过35米的内孤立波属于少数情况。其次，观测地的内潮以日频率的振动为主，间隔有半日频率的内潮出现，与当地天文潮情况相似。其振幅小于内孤立波的振幅，在每个观测日都能观测到。内潮的振幅有着明显的季节变化，7月是内潮振幅最小的一个月。再次，观测地内波波致流的大小和剪切层位置有着明显的季节变化。在4月和5月内波波致流流速较大而且靠近海底。而在6月以后，内波波致流较弱，并且剪切层也更为靠近海面。最后，观测地内波可能在局地生成，由于主要呈现全日频率可以排除在吕宋海峡生成的可能。同时传播方向同样随季节变化。4月和5月观测到的内波传播方向主要与等深线线平行，极少被卫星遥感图片观测到。6月、7月、8月和9月传播方向与等深线垂直。

Mixing process in estuaries

A theoretical expression for vertical profile-of horizontal velocity in terms of its depth-average is derived based on oscillatory boundary layer theory and estuarine flow characteristics. The derived theoretical profile is then incorporated into a vertical quasi-two-dimensional model, which is proved advantageous in more physical implications and less CPU time demand. To validate the proposed model, the calculated results are compared to the field data in the Yangtze River Estuary, exhibiting good agreement with observations. The proposed quasi-two-dimensional vertical model is used to study mixing process, especially dependence of salinity distribution and salt front strength on runoff and tides in estuaries.

Three-Dimensional Propagation of the Transmitted Shock Wave in a Square Cross-Sectional Chamber

An investigation into the three-dimensional propagation of the transmitted shock wave in a square cross-section chamber was described in this paper, and the work was carried out numerically by solving the Euler equations with a dispersion-controlled scheme. Computational images were constructed from the density distribution of the transmitted shock wave discharging from the open end of the square shock tube and compared directly with holographic interferograms available for CFD validation. Two cases of the transmitted shock wave propagating at different Mach numbers in the same geometry were simulated. A special shock reflection system near the corner of the square cross-section chamber was observed, consisting of four shock waves: the transmitted shock wave, two reflection shock waves and a Mach stem. A contact surface may appear in the four-shock system when the transmitted shock wave becomes stronger. Both the secondary shock wave and the primary vortex loop are three-dimensional in the present case due to the non-uniform flow expansion behind the transmitted shock.

An investigation of electromagnetic wave propagation in plasma by shock tube

This paper presents the electromagnetic wave propagation characteristics in plasma and the attenuation coefficients of the microwave in terms of the parameters n(e), v, w, L, w(b). The phi800 mm high temperature shock tube has been used to produce a uniform plasma. In order to get the attenuation of the electromagnetic wave through the plasma behind a shock wave, the microwave transmission has been used to measure the relative change of the wave power. The working frequency is f = (2 similar to 35) GHz (w = 2pif, wave length lambda = 15 cm similar to 8 mm). The electron density in the plasma is n(e) = (3 x 10(10) similar to 1 x 10(14)) cm(-3). The collision frequency v = (1 x 10(8) similar to 6 x 10(10)) Hz. The thickness of the plasma layer L = (2 similar to 80) cm. The electron circular frequency w(b) = eB(0)/m(e), magnetic flux density B-0 = (0 similar to 0.84) T. The experimental results show that when the plasma layer is thick (such as L/lambda greater than or equal to 10), the correlation between the attenuation coefficients of the electromagnetic waves and the parameters n(e), v, w, L determined from the measurements are in good agreement with the theoretical predictions of electromagnetic wave propagations in the uniform infinite plasma. When the plasma layer is thin (such as when both L and lambda are of the same order), the theoretical results are only in a qualitative agreement with the experimental observations in the present parameter range, but the formula of the electromagnetic wave propagation theory in an uniform infinite plasma can not be used for quantitative computations of the correlation between the attenuation coefficients and the parameters n(e), v, w, L. In fact, if w < w(p), v(2) much less than w(2), the power attenuations K of the electromagnetic waves obtained from the measurements in the thin-layer plasma are much smaller than those of the theoretical predictions. On the other hand, if w > w(p), v(2) much less than w(2) (just v approximate to f), the measurements are much larger than the theoretical results. Also, we have measured the electromagnetic wave power attenuation value under the magnetic field and without a magnetic field. The result indicates that the value measured under the magnetic field shows a distinct improvement.

The magnetostatic relations including fluctuation fields

The influences of the fluctuation fields are important in many astrophysical environments as shown by the observations, and can not be neglected. On the basis of the first-order smoothing approximation, in the present paper, we demonstrate the magnetostatic equations for both the cases of the conventional turbulence aud the random waves, and discuss the consistent conditions of the equations. In the static problem, the fluctuation Lorentz force(▽×δB)×δB influences the large-scale configurations of magnetic field. To study this influence in detail is quite necessary for the explanations of the observation features, especially for the astrophysical environments where the magnetic fields, including the fluctuation fields, are the dominant factors in the equilibrium of momentum and energy.

Numerical Simulation of R-M Instability

In order to capture shock waves and contact discontinuities in the field and easy to program with parallel computation a new algorithm is developed to solve the N-S equations for simulation of R-M instability problems. The method with group velocity control is used to suppress numerical oscillations, and an adaptive non-uniform mesh is used to get fine resolution. Numerical results for cylindrical shock-cylindrical interface interaction with a shock Mach number Ms=1.2 and Atwood number A=0.818, 0.961, 0.980 (the interior density of the interface/outer density p(1)/p(2) = 10, 50, 100, respectively), and for the planar shock-spherical interface interaction with Ms=1.2 and p(1)/p(2) = 14.28are presented. The effect of Atwood number and multi-mode initial perturbation on the R-M instability are studied. Multi-collisions of the reflected shock with the interface is a main reason of nonlinear development of the interface instability and formation of the spike-bubble structures In simulation with double mode perturbation vortex merging and second instability are found. After second instability the small vortex structures near the interface produced. It is important factor for turbulent mixing.