流媒体分发与传输关键技术研究

随着Internet技术的飞速发展，流媒体分发技术取得了长足的进步，同时，日益增加的用户、视频数据和流媒体交互式需求，也给大规模流媒体分发服务带来了新的挑战。另外一方面，随着宽带无线接入技术发展的日新月异，如何有效利用多种接入方式为用户提供更高质量的流媒体服务是当前通信技术领域迫切需要解决的问题。本文对基于应用层支持交互式的P2P流媒体分发技术及基于传输层支持Multihoming的SCTP流媒体传输技术进行了相关研究，主要贡献和创新点如下： 第一、提出了一种支持随机访问的协作式P2P流媒体分发方案。该方案采用平衡二叉树将媒体对象进行分布式分段预取缓存，用于媒体流快速定位，利用缓存重叠机制构建非结构化网络，用于节点间常规媒体流分发。分别设计了媒体预取算法及邻居节点搜索算法，给出了节点失效恢复策略及支持随机访问的协作过程。仿真试验结果表明，在随机访问及网络波动过程中，该方案能够提供高平滑质量的P2P媒体流服务。 第二、提出了一种基于数据驱动及分布式存储的P2P VoD解决方案。该方案融合了平衡多叉树与基于数据驱动的随机图网络两种拓扑。利用gossip算法构建和维护随机图网络中的邻居节点关系，采用数据驱动机制进行邻居节点间媒体流的分发，进一步降低了源服务器的负载。设计了一种基于平衡多叉树的分布式预取缓存算法，提高了随机访问的搜索效率。仿真试验结果和分析表明，两种网络拓扑的协作机制有效地解决了P2P VoD中视频传输及交互式操作问题。 第三、设计和实现了一种基于Trace驱动及SCTP的MPEG-4视频传输评估平台Evalvid-SCTP。Evalvid-SCTP提供了在仿真环境下SCTP流媒体实时传输及视频质量评估的解决方案。在Multihoming环境下，Evalvid-SCTP可以有效地分析SCTP在不同网络条件和负载下的流媒体传输行为特征和传输质量。 第四、提出了SCTP流媒体单路径传输最佳协议参数配置策略及多路径并行传输策略。评估了在单路径传输机制下快速重传策略、超时重传策略、路径故障检测门限值设置，三者配合时在多种网络条件下的流媒体传输性能，并综合以上各种发现提出了在不同的路径条件下应该采取的重传路径选择策略以及路径故障检测门限值设置方案。评估了在多路径并行传输下融合SCTP部分可靠特性的流媒体传输性能，提出了针对流媒体传输，多路径并行传输应采取的策略。

Biodegradable Interpolyelectrolyte Complexes Based on Methoxy Poly(ethylene glycol)-b-poly(alpha,L-glutamic acid) and Chitosan

We synthesized methoxy poly(ethylene glycol)-b-poly(alpha,L-glutamic acid) (mPEGGA) diblock copolymer by ring-opening polymerization of N-carboxy anhydride of gamma-benzyl-L-glutamate (NCA) using amino-terminated methoxy polyethylene glycol (mPEG) as macroinitiator. Polyelectrolyte complexation between mPEGGA as neutral-block-polyanion and chitosan (CS) as polycation has been scrutinized in aqueous solution as well as in the solid state.

A Biodegradable Diblcok Copolymer Poly(ethylene glycol)-block-poly(L-lactide-co-2-methyl-2-carboxyl-propylene carbonate): Docetaxel and RGD Conjugation

A diblcok copolymer monomethoxy poly (ethylene glycol)-block-poly(L-lactide-co-2-methyl-2-carboxyl-propylene carbonate) (MPEG-b-P(LA-co-MCC)) was obtained by copolymerization of L-lactide (LA) and 2-methyl-2-benzoxycarbonyl-propylene carbonate (MBC) and subsequent catalytic hydrogenation. The pendant carboxyl groups of the copolymer MPEG-b-P(LA-co-MCC) were conjugated with antitumor drug docetaxel and tripeptide arginine-glycine-aspartic acid (RGD), respectively.

The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents

For the films and powder of polymers containing conductive oligomer are usually obtained from solution, the choice of better solvents for the regular arrangement of oligomers is very important for the higher conductivity. Because of the poor solubility of the oligomers, it is difficult to study the arrangement directly in most common solvents, so, we synthesized a triblock copolymer, mPEG2k-aniline pentamer-mPEG2k, as the model to investigate the arrangement-solvent relationship. For the poor solubility of the AP block in common solvents, the copolymer self-assembled into spheric micelles in toluene and into lamellar crystals in water and THF. The crystallinity (X-c) and crystallization temperature (T-c) values of mPEG blocks in powders prepared from different solvents differed obviously, which may be the effect of different self-assembled structures. From the two-phase model of one-dimensional electron density correlation function of SAXS, the long period of copolymer prepared from THF was presumably equal to the long period of pure mPEG plus the chain length of AP, which demonstrates that the AP blocks arrange regularly in the noncrystalline regions.

SYNTHESIS AND CHARACTERIZATION OF A CROSSLINKING POLYETHYLENIMINE AS SMART GENE CARRIER AND EFFECTS OF PEGYLATION DEGREE

A smart biodegradable cationic polymer (CBA-PEI) based on the disulfide bond-containing cross-linker cystamine bisacrylamide (CBA) and low molecular weight branched polyethylenimine (1800-Da, PEI1800) was successfully synthesized by Michael addition reaction in our recent study. Furthermore, a series of copolymers (CBA-PEI-PEG) with different PEGylation degree were obtained by the mPEG-SPA (5000-Da) reacting with CBA-PEI at various weight ratios directly. The molecular structures of the resulting polymers CBA-PEI and CBA-PEI-PEG were evaluated by nuclear magnetic resonance spectroscopy (H-1-NMR) and capillary viscosity measurements, all of which had successfully verified formation of the copolymers. The polymer/DNA complexes based on CBA-PEI and CBA-PEI-PEG were measured by dynamic light scattering and gel retardation assay. The results showed that the particle size and zeta potential of complexes were reduced with increasing amount of PEG grafting, even no particle formation. The particle size of CBA-PEI/DNA complexes was in range of 103.1 to 129.1 nm, and the zeta potential was in range of 14.2 to 24.3 mV above the 2:1 weight ratio. In the same measure condition, the particle size of CBA-PEI-PEG complexes was reduced to a range of 32.2 to 55 nm, and the zeta potential was in range of 9.3 to 13.8 mV at the 2:1 weight ratio.

Physical diffusion and electron-transfer dynamics of electroactive solutes in polymer electrolytes .2. Effect of the ionic size of supporting electrolytes

The diffusion coefficients(D-app) and the heterogeneous electron-transfer rate constants(k(s)) for ferrocene in MPEG/salt electrolytes were determined by using steady-state voltammetry. The temperature dependence of the two parameters obeys the Arrhenius equation. The effect of the ionic size of six supporting electrolytes on diffusion and electron transfer dynamics of ferrocene was discussed.

Physical diffusion and electron-transfer dynamics of electroactive solutes in polymer electrolytes .1. Effect of the nature of electroactive solutes

The diffusion coefficients(D-app) and the heterogeneous electron-transfer rate constants(k(s)) for ferrocene and its seven derivatives in MPEG/LiClO4 electrolyte were determined by using steady-state voltammetry. The two parameters increase with increasing temperature, indicating Arrhenius behavior. The effects of the nature of electroactive solute molecules on D-app, k(s), and the half-wave potentials(E-1/2) are discussed.