Crystallization process and morphology structure of poly(aryl ether ether ketone ketone) containing meta-phenyl links

The crystallization process and morphology of poly(aryl ether ether ketone ketone) containing meta-phenyl links (PEEKmK) have been investigated by transmission electron microscopy and electron diffraction. The results indicate that the thin films of PEEKmK isothermally crystallized from both the glassy state and the melt at the temperature range of 180 similar to 250 degrees C consist of two kinds of morphological forms, i. e. large (order of mu m), flat-on single crystals and narrow, lath-like, edge-on lamellae, The latter consists of the spherulites. Meanwhile, the growing process of the two kinds of morphological forms has been discussed.

Rifting process and formation mechanisms of syn-rift stage prolongation in the deepwater basin, northern South China Sea

Based on the latest seismic and geological data, tectonic subsidence of three seismic lines in the deepwater area of Pearl River Mouth Basin (PRMB), the northern South China Sea (SCS), is calculated. The result shows that the rifting process of study area is different from the typical passive continental margin basin. Although the seafloor spreading of SCS initiated at 32 Ma, the tectonic subsidence rate does not decrease but increases instead, and then decreases at about 23 Ma, which indicates that the rifting continued after the onset of seafloor spreading until about 23 Ma. The formation thickness exhibits the same phenomenon, that is the syn-rift stage prolonged and the post-rift thermal subsidence delayed. The formation mechanisms are supposed to be three: (1) the lithospheric rigidity of the northern SCS is weak and its ductility is relatively strong, which delayed the strain relaxation resulting from the seafloor spreading; (2) the differential layered independent extension of the lithosphere may be one reason for the delay of post-rift stage; and (3) the southward transition of SCS spreading ridge during 24 to 21 Ma and the corresponding acceleration of seafloor spreading rate then triggered the initiation of large-scale thermal subsidence in the study area at about 23 Ma.

An application of the analytic hierarchy process and fuzzy logic inference in a decision support system for forage selection

Forage selection plays a prominent role in the process of returning cultivated lands back into grasslands. The conventional method of selecting forage species can only provide attempts for problem-solving without considering the relationships among the decision factors globally. Therefore, this study is dedicated to developing a decision support system to help farmers correctly select suitable forage species for the target sites. After collecting data through a field study, we developed this decision support system. It consists of three steps: (1) the analytic hierarchy process (AHP), (2) weights determination, and (3) decision making. In the first step, six factors influencing forage growth were selected by reviewing the related references and by interviewing experts. Then a fuzzy matrix was devised to determine the weight of each factor in the second step. Finally, a gradual alternative decision support system was created to help farmers choose suitable forage species for their lands in the third step. The results showed that the AHP and fuzzy logic are useful for forage selection decision making, and the proposed system can provide accurate results in a certain area (Gansu Province) of China.

细沟侵蚀过程与细沟水流水力学参数的关系研究

利用供沙土槽和试验土槽的双土槽径流小区 ,定量研究了在不同降雨强度下上方来水来沙对陡坡地细沟侵蚀产沙过程和细沟水流水力学参数的影响及其细沟水流水力学特征参数与细沟侵蚀产沙量的关系。结果表明 :坡面细沟侵蚀过程以侵蚀—搬运过程为主 ,坡上方来沙不仅被径流全部搬运 ,且上方来水在坡下方引起了另外的侵蚀产沙量 ,其值随上方来水含沙量的减少和降雨强度的增加而增大。上方来水的汇入或降雨强度的增大可使细沟水流流态由层流转化为紊流。上方来水对细沟水流水力学参数 (流速、水力半径、雷诺数、弗劳德数和阻力系数 )有重要影响。定量分析了细沟水流水力学特征参数 (流速、雷诺数和阻力系数 )与上坡来水引起坡下方净侵蚀产沙量的关系 ,建立了净侵蚀产沙量与细沟水流流速、雷诺数和阻力系数统计模型。

三峡库区巴东组泥灰岩溶蚀作用与岩体力学性质弱化研究

Abstract The karsrt erosion engineering geology became a highlight problem in recent years, in particularly, the karst erosion of marlite of Badong formation made the rock mechanics weaken in Three Gorges Reservoir area, which reduces the safety of slope. During the immigrant construction, many high slopes have been formed, whose instabilities problems pose serious threats to the safety of the people and properties. The accidents of the slope failure take place now and then. By testing, it has been found that the karst erosion pattern and dissolution rate of marlite are not weaker than that of the pure limestone. Furthermore, owning to the weathering and unloading, the karst erosion of the marlite will reach certain depth of the slope, which is named infiltrated karst erosion. The karst erosion made the rock mass quality of slope or foundation worse in a large scale. The karst erosion geological disasters, taken place or not, has become the main restrictive factors to the social stability and economic development. Thus the karst erosion process and mechanism of marlite of Badong formation are studied as the main content of this dissertation. The weakening characteristic of rock mass mechanics parameters are studied along with the rock mass structure deformation and failure processes in the course of the karst erosion. At first, the conditions and influencing factors of the karst erosion are analyzed in the investigative region, on the basis of different karst erosion phenomenon of the marlite and different failure modes of slope. Then via indoor the karst erosion tests, it is analyzed that the karst erosion will change the rock mass composition and its structure. Through test, the different karst erosion phenomena between micro and macro have been observed, and the karst erosion mechanism of the marlite has been summarized. Damage theory is introduced to explain the feature of dissolution pore and the law of crack propagation in the marlite. By microscope and the references data, it can be concluded that the karst erosion process can be divided into rock minerals damage and rock structural damage. And the percent of karst erosion volume is named damage factor, which can be used to describe the quantify karst erosion degree of marlite. Through test, the rock mechanical properties in the different period of karst erosion are studied. Based on the damage mechanics theory and the test result, the relation between the karst erosion degree of marlite and weakening degree of mechanical properties is summarized. By numerical simulations, the karst erosive rock mass mechanics is verified. The conclusion is drawn as below: to the rock mass of marlite, the karst erosion damage made mechanics parameters variation, the deformation modulus, cohesion, and inter friction angle reduce as the negative exponent with the increasing of the karst erosion volume, however, the Poisson ratio increases as the positive exponent with the karst erosion volume increasing. It should be noticed that the deduced formulations are limited to the test data and certain conditions. It is suitable to the rock mass parametric weakening process after the karst erosion of marlite in Three Gorges Reservoir area. Based on the failure types of marlite slope in the field, the karst erosion and weathering process of rock mass are analyzed. And the evolution law of deformation and failure of the marlite mass is studied. The main failure feature of the marlite slope is the karst erosive structure subsidence mode in Three Gorges Reservoir area. The karst erosive structure subsidence mode is explained as follows: the rock mass undergoes the synthetic influence, such as weathering, unloading, corrosion, and so on, many pores and cavities have been formed in the rock mass interior, the rock mass quality is worsen and the rock mass structure is changed, and then the inherent structure of rock mass is collapsed under its gravity, therefore, the failure mode of compaction and subsidence take place. Finally, two examples are used to verify the rock mass parameters in Three Gorges Reservoir area, and the relationship between the marlite slope stability and the time of karst erosion is proposed.

Using the RBFN model and GIS technique to assess wind erosion hazard of inner Mongolia, China

Soil wind erosion is the primary process and the main driving force for land desertification and sand-dust storms in and and semi-arid areas of Northern China. While many researchers have studied this issue, this study quantified the various indicators of soil wind erosion, using the GIS technology to extract the spatial data and to construct a RBFN (Radial Basis Function Network) model for Inner Mongolia. By calibrating sample data of the different levels of wind erosion hazard, the model parameters were established, and then the assessment of wind erosion hazard. Results show that in the southern parts of Inner Mongolia wind erosion hazards are very severe, counties in the middle regions of Inner Mongolia vary from moderate to severe, and in eastern are slight. Comparison of the results with other research shows conformity with actual conditions, proving the reasonability and applicability of the RBFN model. Copyright (C) 2007 John Wiley & Sons, Ltd.

A Simulation Model for Unified Interrill Erosion and Rill Erosion on Hillslopes

A mathematical model was developed for simulating runoff generation and soil erosion on hillslopes. The model is comprised of three modules: one for overland flow, one for soil infiltration, and one for soil erosion including rill erosion and interrill er

Two-Dimensional Hillslope Scale Soil Erosion Model

On a hillslope, overland flow first generates sheet erosion and then, with increasing flux, it causes rill erosion. Sheet erosion (interrill erosion) and rill erosion are commonly observed to coexist on hillslopes. Great differences exist between both the intensities and incidences of rill and interrill erosion. In this paper, a two-dimensional rill and interrill erosion model is developed to simulate the details of the soil erosion process on hillslopes. The hillslope is treated as a combination of a two-dimensional interrill area and a one-dimensional rill. The rill process, the interrill process, and the joint occurrence of rill and interrill areas are modeled, respectively. Thus, the process of sheet flow replenishing rill flow with water and sediment can be simulated in detail, which may possibly render more truthful results for rill erosion. The model was verified with two sets of data and the results seem good. Using this model, the characteristics of soil erosion on hillslopes are investigated. Study results indicate that (1) the proposed model is capable of describing the complex process of interrill and rill erosion on hillslopes; (2) the spatial distribution of erosion is simulated on a simplified two-dimensional hillslope, which shows that the distribution of interrill erosion may contribute to rill development; and (3) the quantity of soil eroded increases rapidly with the slope gradient, then declines, and a critical slope gradient exists, which is about 15-20 degrees for the accumulated erosion amount.

A fast-settling frequency-presetting PLL frequency synthesizer with process variation compensation and spur reduction

This paper proposes a fast-settling frequency-presetting PLL frequency synthesizer. A mixed-signal VCO and a digital processor are developed to accurately preset the frequency of VCO and greatly reduce the settling time. An auxiliary tuning loop is introduced in order to reduce reference spur caused by leakage current. The digital processor can automatically compensate presetting frequency variation with process and temperature, and control the operation of the auxiliary tuning loop. A 1.2 GHz integer-N synthesizer with 1 MHz reference input Was implemented in a 0.18μm process. The measured results demonstrate that the typical settling time of the synthesizer is less than 3μs,and the phase noise is -108 dBc/Hz@1MHz.The reference spur is -52 dBc.

Estimation of wind erosion rates by using Cs-137 tracing technique: A case study in Tariat-Xilin Gol transect, Mongolian Plateau

Wind erosion is one of the major environmental problems in semi-arid and arid regions. Here we established the Tariat-Xilin Gol transect from northwest to southeast across the Mongolian Plateau, and selected seven sampling sites along the transect. We then estimated the soil wind erosion rates by using the Cs-137 tracing technique and examined their spatial dynamics. Our results showed that the Cs-137 inventories of sampling sites ranged from 265.63 +/- 44.91 to 1279.54 +/- 166.53 Bq.m(-2), and the wind erosion rates varied from 64.58 to 419.63 t.km(-2).a(-1) accordingly. In the Mongolia section of the transect (from Tariat to Sainshand), the wind erosion rate increased gradually with vegetation type and climatic regimes; the wind erosion process was controlled by physical factors such as annual precipitation and vegetation coverage, etc., and the impact of human activities was negligible. While in the China section of the transect (Inner Mongolia), the wind erosion rates of Xilin Hot and Zhengxiangbai Banner were thrice as much as those of Bayannur of Mongolia, although these three sites were all dominated by typical steppe. Besides the physical factors, higher population density and livestock carrying level should be responsible for the higher wind erosion rates in these two regions of Inner Mongolia.

Preparation and Luminescence Properties of YVO4:Ln and Y(V, P)O-4:Ln (Ln = Eu3+, Sm3+, Dy3+) Nanofibers and Microbelts by Sol-Gel/Electrospinning Process

One-dimensional YVO4:Ln and Y(V, P)O-4:Ln nanofibers and quasi-one-dimensional YVO4:Ln microbelts (Ln = Eu3+, Sm3+, Dy3+) have been prepared by a combination method of sol-gel process and electrospinning. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric and differential thermal analysis (TG-DTA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence (PL), low-voltage cathodoluminescence (CL), and time-resolved emission spectra as well as kinetic decays were used to characterize the resulting samples.

Preparation and characterization of luminescent thin films doped with rare earth (Tb3+, Eu3+) complexes derived from a sol-gel process

Sol-gel derived luminescent thin films doped with rare earth (RE) complexes were prepared using an in-situ synthesis method with a two-step hydrolysis process and the luminescence spectra were measured. Fluorescence Lifetime and thermal stability were investigated. The results show that a broad excitation band indicates the formation of RE complexes in the solid thin films. RE ions, which are restrained in a silica matrix, present longer lifetime and higher thermal stability than that in DMF/PVB films containing the corresponding pure complexes. (C) 2000 Elsevier Science B.V. All rights reserved.