低能离子束方法制备重掺杂Fe的Si∶Fe固溶体

利用质量分离的低能离子束方法 ,以离子能量为 1 0 0 0 e V,剂量为 3× 1 0 1 7cm- 2 ,室温下往 p型 Si(1 1 1 )单晶衬底注入 Fe离子 ,注入的样品在 4 0 0℃真空下进行热处理 .俄歇电子能谱法 (AES)对原位注入样品深度分析表明 Fe离子浅注入到 p型 Si单晶衬底 ,注入深度约为 4 2 nm.X射线衍射法 (XRD)对热处理样品结构分析发现只有 Si衬底的衍射峰 ,没有其他新相 .X射线光电子能谱法 (XPS)对热处理样品表面分析发现 Fe2 p束缚能对应于单质 Fe的峰 ,没有形成 Fe的硅化物 .这些结果表明重掺杂 Fe的 Si∶ Fe固溶体被制备 .电化学 C- V法测量了热处理后样品载流子浓度随深度的分布 ,发现 Fe重掺杂 Si致使 Si的导电类型从 p型转为 n型 ,Si∶ Fe固溶体和 Si衬底形成 pn结 ,具有整流特性

The Effect of the Thickness of Fe2 Al5 Phase Layer at Fe/Al Interface on the Mechanics Behavior of Hot Dip Aluminizing Coating

Hot Dip Aluminized Coatings with different thickness were prepared on Q235 steel in aluminum solutions with different temperature for certain time. Through tensile tests and in-situ SEM observations, the effect of the coating's microstructure on the tensile strength of the samples was studied. It was disclosed at certain aluminum solution temperature,transaction layers mainly composed of Fe2 Al5 phase got thicker with time prolonging, and this changed initial crack's extending direction from parallel with to vertical with stretching direction. The change in crack direction decreased tensile strength of samples, thus made the coating easy to break. It was concluded that the existence of thick Fe2 Al5 phase layer was the basic reason for the lowering of tensile strength of the coating.

EDTA溶胶凝胶法制备La_2Ni_(1-x)M_xO_4(M=Cu,Fe)稀土复合氧化物

本文以EDTA溶胶凝胶法合成K2NiF4型稀土复合氧化物La2Ni1-xMxO4(M=Cu,Fe),并对反应生成粉体分别进行SEM表征与XRD测试。结果表明,选取合适的制备工艺,可以形成La2Ni1-xMxO4(M=Cu,Fe)稀土复合氧化物材料;随着掺杂离子半径增大,生成材料晶格常数a增大同时,c减少,粉体颗粒粒径较大,同时少量杂相存在。

LiNbO3：Fe晶体光栅擦除特性

在光折变过程中，光波对掺杂中心的激发系数S是一个重要的物理量。为了求出光激发系数S对波长A的依赖，研究了在不同的擦除波长条件下，记录在光折变晶体LiNbO3：Fe中的光栅衰减特性。实验结果表明lnP（P为光擦除灵敏度）与擦除波长λ呈线性关系，即波长越短，光栅擦除越快，光擦除灵敏度越高。在单中心电子带传输模型的基础上，理论计算也证实了实验结果。利用带传输模型，给出了理论上光激发系数S对波长的指数依赖关系。同时微观量φμγ（φ为量子效率）也可由光栅擦除实验求出。

组合外加电场提高Fe：LiNbO3中90°记录体全息的衍射效率

针对90°全息记录结构的特殊性，在记录和读出阶段分别施加不同极性的外加电场，实现了Fe：LiNbO3晶体中高衍射效率的全息记录和读出。在库赫塔列夫（Kukhtarev）方程基础上引人两维耦合波理论，对组合外加电场提高掺铁铌酸锂晶体光折变特性的机理进行了探讨。实验和理论计算结果都表明这种分别在记录和读出过程施加不同极性组合的外加电场是在Fe：LiNbO3中实现高衍射效率90°记录结构体全息的有效技术方案。

LiNbO3：Fe：Ni晶体非挥发全息存储研究

采用三种不同的双光记录方案进行了LiNbO3：Fe：Ni晶体全息存储实验．详细研究了饱和衍射效率、固定衍射效率、动态范围和记录灵敏度，以及退火条件对记录的影响。结果表明，氧化LiNbO3：Fe：Ni晶体的饱和衍射效率、固定衍射效率和记录灵敏度比其他报道的双掺杂LiNbO3晶体高。结合掺杂能级图，理论分析了LiNbO3双掺杂晶体深陷阱中心能级的相对位置及其微观光学参量对全息记录性能的影响。LiNbO3：Fe：Ni晶体有望成为一种新的高效率非挥发全息存储材料。

双掺杂LiNbO3：Fe：Ru晶体的全息读出特性

为了解决读出过程中全息数据的擦除问题，研究了新型双掺杂LiNbOa：Fe：Ru晶体的全息读出特性。分析了双中心和单中心记录方案光栅的读出特性，并联立双中心物质方程和耦合波方程进行了模拟计算。结果表明，双中心记录所得到的饱和全息的读出时间常数远低于LiNbO2：Fe：Mn晶体的读出时间常数；单色光记录可以实现有效的全息，且其读出时间常数远大于记录时间常数，表现为准态非挥发读出。分析表明，这可能由于Ru的能级比Mn更靠近Fe，更易被红光激发，从而使得双中心记录所得饱和光栅的存贮持久性降低；单色光记录中红光能够

LiNbO3：Ru：Fe晶体畴反转过程中的电色效应

观察到了双掺杂LiNbO3：Ru：Fe晶体中电色效应伴随畴反转而发生，且与畴反转一样也具有可逆性，两者相辅相成，畴反转导致了晶体变色，电色效应促进了畴反转，系统的实验结果证明了两者的相辅相成性．基于铌酸锂铁电微结构模型，简要解释了其机理．而且发现在极化过程中电色效应促使了畴核的形成，使之不同于非掺杂同成分比铌酸锂晶体的矫顽场大于击穿电场，用恒定直流电场代替脉冲电场也能实现畴反转，这将为周期性极化铌酸锂的制备提供一种新的技术改进．

LiNbO3∶Fe∶Rh晶体近红外非挥发全息记录

采用双中心记录方案在双掺杂LiNbO3∶Fe∶Rh晶体中实现了近红外非挥发全息记录,研究了LiNbO3∶Fe∶Rh晶体在633 nm,752 nm,799 nm波长下的全息记录性能。结果表明,在使用近红外记录光时,其记录灵敏度随敏化光强的变化趋势与双中心短波长记录时的不同。通过和LiNbO3∶Fe∶Mn等传统双掺杂铌酸锂晶体的近红外波段记录效果对比,发现同时掺杂Fe和Rh可增强晶体对近红外光的吸收,获得更高的浅中心Fe光生伏特系数,从而能够在LiNbO3∶Fe∶Rh晶体中实现近红外波段的光折变全息记录。

Nonvolatile holograms in LiNbO3 : Fe : Cu by use of the bleaching effect

We report our observation of a bleaching effect under an ultraviolet exposure in LiNbO3:Fe:Cu crystals. Two three-step recording-transferring-fixing schemes are proposed to record nonvolatile photorefractive holograms in such crystals. In the schemes two red laser beams and an ultraviolet illumination are used selectively to write the charge grating in the shallow-level Fe centers, to develop the charge grating in the deep-level Cu centers by transferring the charge grating in the Fe centers, and to fix only the charge grating in the Cu centers for unerasable read-out. Experimental results, verifications, and an optimal recording scheme are given. A comparison of the lithium niobate crystals of the same double-doping system of Fe:Mn, Ce:Mn, Ce:Cu, and Fe:Cu is outlined. (C) 2002 Optical Society of America.

Prescription for optimizing holograms in LiNbO3 : Fe : Mn

The photorefractive holographic dynamics of grating formation in photochromic doubly doped LiNbO3:Fe:Mn crystal is studied numerically and analytically in terms of the two-center model of Kukhtarev Et al. [Ferroelectrics 22, 949 (1979)]. The relations among the recorded and fixed space-charge fields and the doping densities, the oxidation-reduction states of the fields, and the intensities of UV-sensitizing and red recording beams are studied. Important conditions and effects are feued, and an optimal prescription for material doping and oxidation-reduction processing is suggested in which the crystal can be strongly oxidized and the Mn-doping density is smaller than the Fe-doping density. (C) 2000 Optical Society of America. OCIS codes: 050.7330, 190.5330, 090.2900.

Effect of absorption on the diffraction efficiency in Fe : LiNbO3 crystal with 90 degrees recording geometry

In this paper the saturated diffraction efficiency has been optimized by considering the effect of the absorption of the recording light on a crossed-beam grating with 90 degrees recording geometry in Fe:LiNbO3 crystals. The dependence of saturated diffraction efficiency on the doping levels with a known oxidation-reduction state, as well as the dependence of saturated diffraction efficiency on oxidation-reduction state with known doping levels, has been investigated. Two competing effects on the saturated diffraction efficiency were discussed, and the intensity profile of the diffracted beam at the output boundary has also been investigated. The results show that the maximal saturated diffraction efficiency can be obtained in crystals with moderate doping levels and modest oxidation state. An experimental verification is performed and the results are consistent with those of the theoretical calculation.

Electrochromic effect in domain-inversion process LiNbO3 : Ru : Fe crystals

A reversible electrochromic effect accompanying domain-inversion during the electrical poling process in LiNbO3: Ru: Fe crystals at room temperature has been observed. In electrode area, both electrochromism and domain-inversion occur alternately, and electrochromism is also reversible during back-switch poling, which is experimentally verified and whose mechanism is briefly explained using a microstructure ferroelectric model. In addition, because of the enhancing elcctrochromic effect, different from the undoped LiNbO3 crystals, the coercive riled (21.0 kV/mm or so) measured in LiNbO3: Ru: Fe is lower than its breakdown field, thus providing a possible new technique for realizing the domain-inversion by constant electric field rather than a pulsed one.

Reversible electrochromic effect accompanying domain-inversion in LiNbO3 : Ru : Fe crystals

A reversible electrochromic effect during the electrical poling process in LiNbO3:Ru:Fe crystals at room temperature is observed. In electrode area, both electrochromism and domain-inversion occur mutually and electrochromism is reversible during back-switch poling, which are experimentally verified, and a microstructure model to explain the mechanism is proposed. In addition, different from the undoped LiNbO3 crystals, the breakdown field (> 25.0 kV/mm) is higher than the coercive (21.0 kV/mm) measured in LiNbO3:Ru:Fe, which proves a possible new technique to realize domain-inversion by constant electric field rather than pulsed one. (c) 2005 American Institute of Physics.

敏化光波长对（Fe，Ni）：LiNbO3晶体全息记录性能的影响

分别采用514nm绿光、488nm蓝光和390nm紫外光作为敏化光，633nm红光作为记录光，详细研究了敏化光波长对氧化（Fe，Ni）：LiNbO3晶体全息记录性能的影响。结果表明：随着敏化光波长的逐渐减小，氧化（Fe，Ni）：LiNbO3晶体的非挥发全息记录性能逐渐优化，390nm紫外光是这三种敏化光中最优的敏化光。考虑敏化光的吸收，为了在双中心全息记录中获得最优的性能，应当选择合适波长的敏化光：一方面短波长敏化光能有效地敏化深中心；另一方面短波长敏化光的吸收太强（如对光折变效应无用的基质吸收），不能沿