基于CPLD多路QAC的逻辑电路设计

主要介绍了多道电荷幅度转换器(QAC)的逻辑电路部分。包括积分控制电路和仲裁电路。用可程逻辑器件CPLD来构建这部分电路,和常规的逻辑器件相比其突出特点是:元件少、成本低、功耗低。并且在速度上完全可以替代ECL器件,适合于构建大型的逻辑电路。

HIRFL-CSR主环电子冷却模拟计算

以16O8 + 为例 ,用电子冷却模拟程序计算了冷却时间随离子能量、初始发射度、初始动量分散、离子流强以及离子电荷态的变化规律 ,研究了储存环在冷却段的 β函数和色散函数对冷却时间的影响

CO_2干扰对红松和长白赤松幼苗土壤微生物量C的影响

以不同浓度CO2(700、500μm o l/m o l)处理的红松和长白赤松幼苗土壤为研究对象,在2003年的7~9月的中旬采样,对0~10 cm层土壤微生物生物量C受高浓度CO2影响进行了研究。结果表明,700μm o l/m o l CO2对红松幼苗土壤微生物生物量C起着极显著(p<0.01)抑制效应,其作用大于500μm o l/m o l CO2处理;受高浓度CO2处理的长白赤松幼苗土壤微生物生物量C表现出了与红松土壤微生物生物量C相似的变化规律。此外,500μm o l/m o l CO2条件对红松和长白赤松幼苗土壤微生物生物量C的影响存在着不稳定性。

到达中国陆面的生物有效紫外线辐射强度分布

随着大气臭氧层的日趋变薄,估算到达陆面的太阳紫外线辐射变化,评估对人体健康的影响日趋成为环境健康研究的一个重要课题。基于DISORT辐射传输模型,从生物健康效应的角度提出了估算陆面有效紫外线辐射强度的方法,并采用LibRadtran软件包UVSPEC模型以及GIS空间分析技术模拟了2000年1月和7月到达中国陆面的生物有效紫外线辐射强度空间分布,讨论了臭氧、云量、地表反照率等因素对陆面生物有效紫外线辐射强度的影响,研究了基于云量、海拔数据修正陆面紫外线辐射的方法。另外,还系统分析了2000年1月、7月我国陆面生物有效紫外线辐射强度的空间分布特征,1月份辐射强度是低纬度较高,而7月份是中高纬度较高。UVA和UVB陆面辐射强度分布明显不同,特别是7月份,UVB辐射强度的高值区域较UVA明显偏向低纬度地区。UVB的生物有效辐射强度大约是UVA的6倍。

Electrochemical characteristics of mediated laccase-catalysis and electrochemical detection of environmental pollutants

Laccase has been immobilized on the carbon nanotubes modified glassy carbon electrode surface by adsorption. As-prepared laccase retains good electrocatalytic activity to oxygen reduction by using 2,2'-azino-bis-(3-ethylbenzthiazoline-6-sulfonic acid) as the mediator. It can be used as a biosensor for the determination of catechol with broad linear range.

Alternate assemblies of polyelectrolyte functionalized carbon nanotubes and platinum nanoparticles as tunable electrocatalysts for dioxygen reduction

A novel method based on electrostatic layer-by-layer self-assembly (LBL) technique for alternate assemblies of polyelectrolyte functionalized multi-walled carbon nanotubes (MWNTs) and platinum nanoparticles (PtNPs) is proposed. The shortened MWNTs can be functionalized with positively charged poly(diallyldimethylammonium chloride) (PDDA) based on electrostatic interaction. Through electrostatic layer-by-layer assembly, the positively charged PDDA functionalized MWNTs (PDWNTs) and negatively charged citrate-stabilized PtNPs were alternately assembled on a 3-mercaptopropanesulfonic sodium (NIPS) modified gold electrode and also on other negatively charged surface, e.g. quartz slide and indium-tin-oxide (ITO) plate, directly forming the three-dimensional (3D) nanostructured materials. This is a very general and powerful technique for the assembling three-dimensional nanostructured materials containing carbon nanotubes (CNTs) and nanoparticles. Thus prepared multilayer films were characterized by ultraviolet-visiblenear-infrared spectroscopy (UV-vis-NIR), scanning electron microscopy (SEM) and cyclic voltammetry (CV). Regular growth of the mutilayer films is monitored by UV-vis-NIR.

Studies on the organometallic palladium coordinated carbosillane liquid crystalline dendrimer

A novel complex - palladium-coordinated ate-type liquid crystalline dendrimer was synthesized by a divergent approach, The product showed liquid crystalline properties from 115 degrees C to 187 degrees C, and it belonged to dinuclear species, containing two palladium centers linked by two bridging Cl, each palladium atom completes its coordinations with N atom and a sigma bond to an ortho-carbon in the phenyl ring. The microanalytical values obtained for the product are in agreement with those of compound containing ligand, palladium:and chlorine in a molar ratio of 1 : 1 : 1 and 12 palladium atoms for every scaffold.

用NMR方法研究中药山莨菪碱与磷脂脂质体的相互作用

用核磁共振(NMR)方法研究了中药山莨菪碱(anisodamine)与结构不同的3种磷脂脂质体相互作用,二棕榈酰磷脂酰胆碱(DPPC)极性基团空阻较大,山莨菪碱三级胺端不能与P-O键作用,仍处于水相,苯环只能嵌入到甘油骨架C-2附近。二棕榈酰磷脂酸(DPPA)极性头空间位阻较小,山莨菪碱苯环可以直接插入到靠近脂酰链γ-次甲基的位置,而三级胺端与极性头发生静电作用,并且药物可以提高DPPA脂质体的流动性。山莨菪碱通过三级胺端与鞘磷脂(SPM)极性头静电作用较强,而苯环位于SPM脂双层亲水和疏水区界面。药物对3种磷脂双层结构影响很小。