41 resultados para 681.3.06


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Submitted by zhangdi (zhangdi@red.semi.ac.cn) on 2009-06-04T08:36:34Z No. of bitstreams: 1 dspace.cfg: 33388 bytes, checksum: ac9630d3fdb36a155287a049e8b34eb7 (MD5)

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Submitted by zhangdi (zhangdi@red.semi.ac.cn) on 2009-06-04T08:36:34Z No. of bitstreams: 1 dspace.cfg: 33388 bytes, checksum: ac9630d3fdb36a155287a049e8b34eb7 (MD5)

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A resonant-cavity enhanced reflective optical modulator is designed and frabricated, with three groups of three highly strained InGaAS/GaAs quantum wells in the cavity, for the low voltage and high contrast ratio operation. The quantum wells are positioned in antinodes of the optical standing wave. The modulator is grown in a single growth step in an molecular beam epitaxy system, using GaAs/AIAs distributed Bragg reflectors as both the top and bottom mirrors. Results show that the reflection device has a modulation extinction of 3 dB at -4.5 V bias.

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High structural and optical quality 1.3 mu m GaInNAs/GaAs quantum well (QW) samples with 42.5% indium content were successfully grown by molecular beam epitaxy. The growth of well layers was monitored by reflection high-energy electron diffraction (RHEED). Room temperature photoluminescence (PL) peak intensity of the GaIn0.425NAs/GaAs (6 nm / 20 nm) 3QW is higher than, and the full width at half maximum (FWHM) is comparable to, that of In0.425GaAs/GaAs 3QW, indicating improved optical quality due to strain compensation effects by introducing N to the high indium content InGaAs epilayer. The measured (004) X-ray rocking curve shows clear satellite peaks and Pendellosung fringes, suggesting high film uniformity and smooth interfaces. The cross sectional TEM measurements further reveal that there are no structural defects in such high indium content QWs. (c) 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Submitted by 阎军 (yanj@red.semi.ac.cn) on 2010-06-04T08:15:32Z No. of bitstreams: 1 Large-Signal Performance of 1.3 mu m InAs-GaAs quantum-dot lasers.pdf: 281494 bytes, checksum: 1ebcdfdc887e3a3b279e07b3f655167b (MD5)

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We have investigated the hydride vapor-phase epitaxy growth of (10 (1) over bar(3) over bar)-oriented GaN thick films on patterned sapphire substrates (PSSs) (10 (1) over bar0). From characterization by atomic force microscopy, scanning electron microscopy, double-crystal X-ray diffraction, and photoluminescence (PL), it is determined that the crystalline and optical qualities of (10 (1) over bar(3) over bar) GaN epilayers grown on the cylindrical PSS are better than those on the flat sapphire. However, two main crystalline orientations (10 (1) over bar(3) over bar) and (11 (2) over bar2) dominate the GaN epilayers grown on the pyramidal PSS, demonstrating poor quality. After etching in the mixed acids, these (10 (1) over bar(3) over bar) GaN films are dotted with oblique pyramids, concurrently lining along the < 30 (3) over bar2 > direction, indicative of a typical N-polarity characteristic. Defect-related optical transitions of the (10 (1) over bar(3) over bar) GaN epilayers are identified and detailedly discussed in virtue of the temperature-dependent PL. In particular, an anomalous blueshift-redshift transition appears with an increase in temperature for the broad blue luminescence due to the thermal activation of the shallow level.

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We report highly efficient and stable organic light-emitting diodes (OLEDs) with MoO3-doped perylene-3, 4, 9, 10-tetracarboxylic dianhydride (PTCDA) as hole injection layer (HIL). A green OLED with structure of ITO/20 wt% MoO3: PTCDA/NPB/Alq(3)/LiF/Al shows a long lifetime of 1012 h at the initial luminance of 2000 cd/m(2), which is 1.3 times more stable than that of the device with MoO3 as HIL. The current efficiency of 4.7 cd/A and power efficiency of 3.7 lm/W at about 100 cd/m(2) have been obtained. The charge transfer complex between PTCDA and MoO3 plays a decisive role in improving the performance of OLEDs.

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铬系催化剂是合成1,2-聚丁二烯和3,4-聚异戊二烯的一种主要催化剂体系,1,2-聚丁二烯和3,4-聚异戊二烯是制造高性能轮胎的重要原料。本论文研究了以含氮化合物和含磷化合物为配体的铬催化剂合成1,2-聚丁二烯和3,4-聚异戊二烯的反应规律。 1. 以邻菲咯啉为配体的铬催化剂在己烷中50℃下可获得1,2-结构、顺-1,4-结构和反-1,4-结构单元含量分别约为50%、30%和20%,分子量呈双峰分布的聚丁二烯。改变聚合温度,可有效控制聚合物的1,2-结构含量和分子量及分布。催化剂通过预陈化方式,可有效抑制低聚物的生成。 2. 以亚磷酸二烷基酯为配体的铬催化剂是合成1,2-聚丁二烯的高效催化剂,所得聚合物具有高的1,2-结构含量(> 78%)。改变烷基铝和亚磷酸二烷基酯的结构,可以得到高熔点或低熔点间同1,2-聚丁二烯和无规1,2-聚丁二烯。催化剂以现配方式的活性最高。 3. 以磷酸三苯酯为配体的铬催化剂可获得间同1,2-聚丁二烯,而聚合物中含有低聚物。催化剂以现配方式的活性最高。聚合物的熔点,低聚物的含量与磷酸三苯酯的结构有一定的关系。 4. 以邻菲咯啉为配体的铬催化剂在50℃下聚合异戊二烯,具有高的催化活性,可获得3,4-结构含量约67%的高分子量无规3,4-聚异戊二烯。催化剂的组成对聚合物的微观结构无明显影响。改变聚合温度,可有效控制聚合物的3,4-结构含量和分子量及分布。

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叶酸是B族维生素的一员,参与体内一系列重要的生命过程包括DNA,氨基酸的合成,调控细胞周期,参与一碳单位供体循环,调节DNA,蛋白质甲基化等。叶酸的许多功能都和叶酸结合蛋白有关,体内有多种跨膜形式的叶酸结合蛋白,比如Folbp1,RFC,HCP等。以前的研究表明这些不同的叶酸结合蛋白具有不同的功能。分泌型叶酸结合蛋白是另外一类叶酸结合蛋白,在人类,小鼠,猪中都有序列报道,但是其功能却知之甚少。 我们在非洲爪蛙中鉴定出一个全新的分泌型叶酸结合蛋白并命名为Secreted Folate Binding Protein(sFBP)。在胚胎和转染细胞系中我们都证明该蛋白是分泌性的,表面等离子共振实验发现sFBP能够结合叶酸。在胚胎早期这个基因表达于粘液腺和神经板区域,神经管闭合后在神经管、粘液腺、眼睛,头部以及鳃弓都有表达。特异morpholino 阻断sFBP翻译后发现粘液腺发育异常,神经管闭合缺陷,前后体轴聚集延伸运动受到抑制,尾芽期胚胎表现出体轴缩短,无眼,小头或无头的表型。进一步研究发现显微注射sFBP morpholino 的胚胎神经板区域细胞发生凋亡,中胚层和神经外胚层的一系列粘附分子表达异常,神经细胞的正常分化也受到抑制。通过显微移植实验我们还发现抑制sFBP的翻译后,神经嵴细胞的正常分化和迁移都受到抑制。但是,显微注射叶酸及其类似物或者显微注射甲基供体S-腺苷甲硫氨酸或者亮氨酸甲基转移酶都不能挽救阻断sFBP造成的表形,由此提示sFBP可能不是通过叶酸传统的参与营养合成或者甲基化的途径发挥作用。我们发现注射sFBP morpholino可以抑制Islet-1mRNA和蛋白质的表达,Islet-1的表达区域与sFBP类似。共同注射Islet-1 mRNA和sFBP morpholino可以极大的挽救sFBP morpholino的表型。最后通过morpholino特异阻断Islet-1的表达后,我们发现其表现出与sFBP morpholino类似的粘液腺发育缺陷,神经板细胞凋亡,小头无眼的表形。由此叶酸是B族维生素的一员,参与体内一系列重要的生命过程包括DNA,氨基酸的合成,调控细胞周期,参与一碳单位供体循环,调节DNA,蛋白质甲基化等。叶酸的许多功能都和叶酸结合蛋白有关,体内有多种跨膜形式的叶酸结合蛋白,比如Folbp1,RFC,HCP等。以前的研究表明这些不同的叶酸结合蛋白具有不同的功能。分泌型叶酸结合蛋白是另外一类叶酸结合蛋白,在人类,小鼠,猪中都有序列报道,但是其功能却知之甚少。 我们在非洲爪蛙中鉴定出一个全新的分泌型叶酸结合蛋白并命名为Secreted Folate Binding Protein(sFBP)。在胚胎和转染细胞系中我们都证明该蛋白是分泌性的,表面等离子共振实验发现sFBP能够结合叶酸。在胚胎早期这个基因表达于粘液腺和神经板区域,神经管闭合后在神经管、粘液腺、眼睛,头部以及鳃弓都有表达。特异morpholino 阻断sFBP翻译后发现粘液腺发育异常,神经管闭合缺陷,前后体轴聚集延伸运动受到抑制,尾芽期胚胎表现出体轴缩短,无眼,小头或无头的表型。进一步研究发现显微注射sFBP morpholino 的胚胎神经板区域细胞发生凋亡,中胚层和神经外胚层的一系列粘附分子表达异常,神经细胞的正常分化也受到抑制。通过显微移植实验我们还发现抑制sFBP的翻译后,神经嵴细胞的正常分化和迁移都受到抑制。但是,显微注射叶酸及其类似物或者显微注射甲基供体S-腺苷甲硫氨酸或者亮氨酸甲基转移酶都不能挽救阻断sFBP造成的表形,由此提示sFBP可能不是通过叶酸传统的参与营养合成或者甲基化的途径发挥作用。我们发现注射sFBP morpholino可以抑制Islet-1mRNA和蛋白质的表达,Islet-1的表达区域与sFBP类似。共同注射Islet-1 mRNA和sFBP morpholino可以极大的挽救sFBP morpholino的表型。最后通过morpholino特异阻断Islet-1的表达后,我们发现其表现出与sFBP morpholino类似的粘液腺发育缺陷,神经板细胞凋亡,小头无眼的表形。由此我们认为sFBP结合叶酸后可能通过细胞膜上的受体传递信号,并且Islet-1可能在sFBP的下游发挥作用。 神经嵴是脊椎动物特有的一群多潜能干细胞,产生于表皮和神经板的边界,在原肠运动之后这群细胞通过表皮间充值转换从神经管背侧迁移到不同的区域,分化成不同的细胞类型,包括外周神经系统,色素细胞,软骨等。神经嵴的发生是一个多步骤多基因参与的精细调控过程。目前理论认为最初由一些分泌性信号分子又叫形态生成素比如BMP,Wnt,FGF,Notch等通过不同浓度梯度的相互作用调节一组在表皮和神经板边界的转录因子(Msx、Pax3/7、Zic1、Dlx3/5等)的表达,即边界决定。这些边界决定因子进一步在预定形成神经嵴的区域激活神经嵴特化基因比如Slug/Snail、FoxD3、Twist、Sox9/10的表达完成神经嵴的特化(Specification)。 Nkx6.3是Nkx6家族的一个转录因子,RT-PCR显示其呈现母源性表达。特异抗体显示Nkx6.3蛋白第9期在整个胚胎都表达,大部分蛋白集中在细胞核,有少部分蛋白定位于细胞膜上;神经板时期主要定位于神经嵴区域的细胞膜上。过表达Nkx6.3会影响细胞粘连分子的表达,由此干扰正常的胚胎原肠运动和Activin诱导的动物帽聚集延伸运动。显微注射Nkx6.3特异morpholino阻断其蛋白表达会抑制神经嵴的marker基因Wnt8,Fgf8,Pax3,Msx1,Zic1,FoxD3,Slug的转录,阻碍神经嵴的发育。在动物帽中单独注射Nkx6.3可以在mRNA水平上诱导Wnt8、Fgf8另一方面抑制BMP4的表达进而诱导神经嵴基因Pax3,Zic1,Slug的表达。报告基因实验也显示Nkx6.3能够激活Wnt信号而在动物帽中抑制BMP信号。Nkx6.3蛋白功能域分析发现其EH1结构域(domain)参与对Wnt8信号的激活,而EH1结构域和HD结构域之间的连接区域(linker domain)参与对FGF的激活和对BMP的抑制。进一步在动物帽和胚胎中分析发现Nkx6.3对Wnt8的激活依赖于FGF家族受体信号但是不依赖于Fgf8。有趣的是4细胞时期过表达Nkx6.3促进Fgf8和Wnt8 mRNA表达,但是抑制边界决定基因Msx1、Pax3和神经嵴特化基因Slug的转录。在32细胞时期显微注射Nkx6.3可以在内源神经嵴发生区域抑制Slug的表达,而异位却诱导Slug的mRNA。我们发现与动物帽中对BMP的调节不同,在胚胎中,过表达Nkx6.3会强烈的激活Smad1蛋白在细胞核中的表达即BMP信号被激活,高的BMP信号会抑制神经嵴的发生。另外我们发现过表达Nkx6.3在胚胎中抑制Dlx5而在动物帽中却不影响Dlx5的表达水平,Morpholino阻断Dlx5会抑制Msx1、Pax3和Slug的表达。BMP信号和Dlx5在动物帽和在整体胚胎中对Nkx6.3的不同响应可以一定程度上解释过表达Nkx6.3在2个系统中对神经嵴基因Slug相反的影响结果。

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A 1.3μm low-threshold edge-emitting AlGaInAs multiple-quantum-well(MQW) laser with AlInAs-oxide confinement layers is fabricated.The Al-contained waveguide layers upper and low the active layers are oxidized as current-confined layers using wet-oxidation technique.This structure provides excellent current and optical confinement,resulting in 12.9mA of a low continuous wave threshold current and 0.47W/A of a high slope efficiency of per facet at room temperature for a 5-μm-wide current aperture.Compared with the ridge waveguide laser with the same-width ridge,the threshold current of the AlInAs-oxide confinement laser has decreased by 31.7% and the slope efficiency has increased a little.Both low threshold and high slope efficiency indicate that lateral current confinement can be realized by oxidizing AlInAs waveguide layers.The full width of half maximum angles of the Al-InAs-oxide confinement laser are 21.6° for the horizontal and 36.1° for the vertical,which demonstrate the ability of the AlInAs oxide in preventing the optical field from spreading laterally.

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Resonant cavity enhancement (RCE) typed optical detector and modulator which operating at wavelength band of 1.06 μm is reported. The peak quantum efficiency of detector is reasonably high as 50% without bias, and the photocurrent contrast ratio of modulator is 3.6 times at -3.5 V as compared to 0 V. The incident angle dependence of RCE device's photoelectric response is investigated carefully.

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An ultracompact 3-dB coupler is designed and fabricated in silicon-on-insulator,based on 12 line tapered multimode interference(MMI) coupler.Comparing with the conventional straigth MMI coupler,the device is-40% shorter in length.The device exhibits uniformity of 1.3dB and excess loss of 2.5dB

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采用室内好气培养方法,以DCD为参比对象研究了新型硝化抑制剂1-羟甲基-3,5-二甲基吡唑(DMHMP)对土壤硝化作用的影响。研究结果表明,DMHMP同DCD一样对土壤硝化作用有明显的抑制效应,主要表现在三个方面:(1)可使土壤NH4+-N含量在整个培养期内显著高于不添加抑制剂的对照处理(P<0.01);(2)使土壤NO3--N含量显著低于对照处理(P<0.01);(3)添加硝化抑制剂处理土壤的pH下降幅度和速度均较对照处理有所降低.当添加DMHMP的量与DCD相等时,其硝化抑制作用不如DCD,而当其添加量为DCD的2倍时,其硝化抑制效果明显优于DCD.在培养的第7天至第21天之间,DMHMP具有最优的硝化抑制效应。

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采用室内培养试验方法,从3,5-二甲基吡唑施用后土壤硝化作用潜势、参与氮转化的主要生理菌群、土壤微生物群落的数量及其生理活性等的动态变化入手,研究了新型硝化抑制剂3,5-二甲基吡唑(DMP)的施用对土壤硝化作用及生物学质量的影响。结果表明,适量DMP的施用可在一定时间内显著降低土壤的硝化作用潜势和土壤氨氧化菌的数量,刺激土壤三大微生物群落的增殖,但细菌、真菌和放线菌对DMP的剂量反应不同。土壤细菌数量呈现随DMP用量增加而增加的趋势,真菌和放线菌数量在培养28d之前则以中等剂量处理的为最高。超高量DMP的施用则强烈抑制土壤氨氧化菌的生长,土壤硝化作用潜势在整个培养期间一直维持在一个较稳定的低水平状态,且在施用前期对真菌和放线菌的增殖及总的微生物生理活性表现了一定的抑制效应,微生物商降低,qCO2值增大;在施用14d后,这种负效应逐渐缓解,进而表现出一定的刺激效应。DMP施用对土壤反硝化细菌影响不大。