在πh_(11/2)νi_(13/2)扁椭球转动带中观测到旋称反转

利用160Gd(35Cl,5nγ)190Tl反应研究了双奇核190Tl的高自旋态,建立了由πh9/2?νi13/2扁椭球转动带和一个具有单粒子激发特征的级联组成的190Tl能级纲图.确定地指定了190Tl扁椭球转动带的自旋值,首次发现了190Tlπh9/2?νi13/2扁椭球转动带的低自旋旋称反转.基于双奇核Tl能级结构的相似性,重新指定了双奇核192~200Tlπh9/2?νi13/2扁椭球转动带能级自旋值,在这些扁椭形变核中均出现了低自旋旋称反转.考虑了p-n剩余相互作用的2-准粒子-转子模型能够定性地解释πh9/2?νi13/2扁椭球转动带出现的低自旋旋称反转现象.

Species；valve size；and pretreatment effects on delta O-18 and delta C-13 values of ostracod valves from Lake Qinghai；Qinghai-Tibet Plateau

IEECAS SKLLQG

Contribution of inherent organic carbon to the bulk delta C-13 signal in loess deposits from the arid western Chinese Loess Plateau

IEECAS SKLLQG

双奇核~(184)Au中πi_(913/2)νi_(13/2)转动带的结构特征研究

利用重离子熔合蒸发反应和在束γ谱学实验方法 ,研究了双奇核184 Au的高自旋态能级结构 .扩展了基于πh9/ 2 ν7/ 2 - [5 14 ]和πi13/ 2 νi13/ 2 2准粒子组态下的转动带能级纲图 ,建立了两个转动带之间以及πh9/ 2 ν7/ 2 - [5 14 ]带与基态的谱学连接 .从而确定了πi13/ 2 νi13/ 2 带能级的自旋和宇称 ,证实了此转动带在低自旋区出现旋称反转 .分析了πi13/ 2 νi13/ 2 带和相邻核转动带的准粒子顺排特征 ,指出此带的第一回弯以及相邻核转动带在低频观测到的顺排异常可能与h9/ 2 质子顺排有关 .

delta C-13 variation of C-3 and C-4 plants across an Asian monsoon rainfall gradient in arid northwestern China

IEECAS SKLLQG

Search for signature inversion in the pi i(13/2) circle times upsilon i1(3/2) bands in Au-182,Au-184,Au-186

Search for low-spin signature inversion in the pi i(13/2) circle times nu i(13/2) bands in odd-odd Au-182,Au-184,Au-186 has been conducted through the standard in-beam gamma-spectroscopy techniques. The experiments for Au-182 and 186Au have been performed in the Japan Atomic Energy Agency (JAEA) via the Sm-152(Cl-35,5n)Au-182 and Yb-172(F-19,5n)Au-186 reactions, respectively. A study of Au-184 has been made using a multi-detector array GASP in LNL, Italy, via the Tb-159(Si-29,4n)Au-184 reaction. The pi i(13/2) circle times nu i(13/2) bands in these three nuclei have been identified and extended up to high-spin states. In particular, the inter-band connection between the pi i(13/2) nu i(13/2) band and the ground-state band in 184 Au has been established, leading to a firm spin-and-parity assignment for the pi i(13/2) circle times nu i(13/2) band. The low-spin signature inversion is found in the pi i(13/2) circle times nu i(13/2) bands in Au-182,Au-184,Au-186 according to our spin-assignment and the signature crossing observed at high-spin states.

Search for signature inversion in the pi i(13/2)circle times nu i(13/2) bands in Au-182,Au-184,Au-186

Search for low-spin signature inversion in the pi i(13/2) circle times nu i(13/2) bands in odd-odd Au-182,Au-184,Au-186 has been conducted through the standard in-beam gamma-spectroscopy techniques via the Sm-152(Cl-35,5n) Au-182, Yb-172(F-19,5n) (186)An, and Tb-159(Si-29,4n) (184)An reactions, respectively. The pi i(13/2) circle times nu i(13/2) bands in these three nuclei have been identified and extended up to high-spin states. In particular, the inter-band connection between the pi i(13/2) circle times nu i(13/2) band and the ground-state band in Au-184 has been established, leading to a firm spin-and-parity assignment for the pi i(13/2) circle times nu i(13/2) band. The low-spin signature inversion is found in the pi i(13/2) circle times nu i(13/2) bands according to our spin-assignment and-the signature crossing observed at high-spin states.

Observation of a pi h(9/2) circle times nu i(13/2) oblate band in Tl-188

Excited states in Tl-188 have been studied experimentally using the Gd-157(Cl-35;4n) reaction at a beam energy of 170 MeV. A rotational band built on the pi h(9/2) x nu i(13/2) configuration with oblate deformation has been established for Tl-188. Based on the structure systematics of the oblate pi h(9/2) x nu i(13/2) bands in the heavier odd-odd Tl nuclei, we have tentatively proposed spin values for the new band in Tl-188. The pi h(9/2) x nu i(13/2) oblate band in Tl-188 shows low-spin signature inversion, and it can be interpreted qualitatively by the two-quasiparticle plus rotor model including a J-dependent p-n residual interaction.

奇奇核170Re在束g谱学和176Ir EC/b+衰变研究

本论文在 166MeV 的束流能量下，利用重离子熔合蒸发反应 142 Nd（32 S， 1p3nγ ）170 Re 布居了 170 Re 的高自旋激发态，用 12 套带 BGO反康普顿抑制的高 纯锗探测器阵列进行了在束 X-γ 和γ γ − 符合测量。在 210MeV 的束流能量下， 利用重离子熔合蒸发反应 146 Nd（35 Cl，5nγ ）176 Ir 产生具有 β+ / EC 衰变性质的 核素 176 Ir, 由氦喷嘴快速带传输系统将反应产物送到低本底区，用一台小平面探 测器、一台轴对称型高纯锗探测器和一台 CLOVER 探测器进行了γ γ − 符合和 t γ − 单谱测量。基于这些测量结果，研究了 170 Re 的高自旋态和 176 Ir 的 β+ / EC 衰变性质。 本工作基于γ−γ符合关系及周围邻近核已知信息的综合分析，首次建立了包 括 16 个能级 26 条γ 跃迁的双奇核 170 Re 的转动带能级纲图，并利用推转壳模型、 粒子转子模型等对其进行了分析和讨论。根据实验提取出的准粒子顺排、 Routhian、旋称劈裂等结构信息和邻近双奇核带结构系统学知识的比较分析，指 出该带的两准粒子组态是 11/213/2 hi π ν ⊗ ，并且该带在低自旋出现旋称反转。 基于对 176 Ir 核 β+ / EC衰变实验数据的离线处理分析，对早先发表的 176 Ir 衰 变γ 跃迁进行确认的同时又发现了 4 个新能级和 13 条新的γ 射线，丰富了 176 Os 核的低位激发态能级纲图。根据典型γ 射线的衰变时间谱建议了 176 Ir核的一个长 寿命低自旋同核异能态，同时通过两准粒子耦合的半经验计算建议了其组态。

Analysis of quinolizidine alkaloids in Sophora flavescens Ait. by capillary electrophoresis with tris(2,2 '-bipyridyl) ruthenium (II)-based electrochemiluminescence detection

A capillary electrophoresis method coupled with electrochemiluminescence detection for the analysis of quinolizidine alkaloids was established, especially, oxymatrine (OMT) which could not be measured by previous electrochemiluminescence methods was detected sensitively herein. Complete separation of sophoridine (SR), matrine (MT) and OMT was achieved within 13 min using a background electrolyte of 50mM phosphate buffer at pH 8.4 and a separation voltage of 15 kV. The calibration curves showed a linear range from 2.8 x 10(-8) to 4.4 x 10(-7) M for SR, 2.7 x 10(-8) to 4.4 x 10(-7) M for MT.

Studies on the stability of diester-diterpenoid alkaloids from the genus Aconitum L. by high performance liquid chromatography combined with electrospray ionisation tandem mass spectrometry (HPLC/ESI/MSn)

The stability of diester-diterpenoid alkaloids (DDA) from plants of the genus Aconitum L. has been studied in different solvents and pH buffers. The HPLC/ESIMS method for analysing the concentration of DDA was established and DDA's decomposition products were elucidated by HPLC/ESI-MS/MSn. In different solvents, e.g. dichloromethane, ether, methanol and distilled water, the decomposition pathways of DDA are quite different and their difference in stabilities depends on the difference of their structures, in which substituents at the N atom and substituents at C-3 are different. The pyrolytic products of DDA, such as deacetoxy aconitine-type alkaloids, have been observed in the above solvents, whereas 8-methoxy-14-benzoyl aconitine-type alkaloids have been obtained only in methanol.

Studies on alkaloids binding to GC-rich human survivin promoter DNA using positive and negative ion electrospray ionization mass spectrometry

Electrospray ionization mass spectrometry (ESI-MS) was used to investigate the binding of 13 alkaloids to two GC-rich DNA duplexes which are critical sequences in human survivin promoter. Negative ion ESI-MS was first applied to screen the binding of the alkaloids to the duplexes. Six alkaloids (including berberine, jatrorrhizine, palmatine, reserpine, berbamine, and tetrandrine) show complexation with the target DNA sequences. Relative binding affinities were estimated from the negative ion ESI data, and the alkaloids show a binding preference to the duplex with higher GC content. Positive ion ESI mass spectra of the complexes were also recorded and compared with those obtained in negative ion mode.

A study of Aconitum alkaloids from aconite roots in Aconitum carmichaeli Debx using matrix-assisted laser desorption ionization mass spectrometry

In the present paper a study of C-19-diterpene type of aconitum alkaloids, extracted from aconite roots in Aconitum carmichaeli Debx has been made using matrix-assisted laser desorption/ionization time of Eight mass spectrometry (MALDI-TOFMS), The results demonstrated that the aconitum alkaloids from aconite roots can be determined simultaneously by this method, which was found to be superior to other analytical methods with regard to speed and sensitivity. Fourteen known aconitum alkaloids, including aconitines, benzoylaconitines and lipoaconitines, were assigned in the methanol extract and three compounds not reported before have been targeted separation. The evaluation of the efficiency of different extractions has been studied. These results suggested that the differences of the polarity and basicity of aconitine, and benzoylaconitines and lipoaconitines result from the C-8 constituent groups that are easily lost under MALDI, (C) 1998 John Wiley & Sons, Ltd.

Compatibilization effect of graft copolymer on immiscible polymer blends: 1. LLDPE/SBS/LLDPE-g-PS systems

compatibilizing effect of graft copolymer, linear low density polyethylene-g-polystyrene (LLDPE-g-PS), on immiscible blends of LLDPE with styrene-butadiene-styrene triblock copolymer (SBS) has been investigated by means of C-13 CPMAS n.m.r. and d.s.c. techniques. The results indicate that LLDPE-g-PS is an effective compatibilizer for LLDPE/SBS blends. It was found that LLDPE-g-PS chains connect two immiscible components, LLDPE and SBS, through solubilization of chemically identical segments of LLDPE-g-PS into the amorphous region of LLDPE acid PS block domain of SBS, respectively. It was also found that LLDPE-g-PS chains connect the crystalline region of LLDPE by isomorphism, with serious effects on the supermolecular structure of LLDPE. The effect of LLDPE-g-PS on the supermolecular structure of LLDPE in the LLDPE/SBS blends obviously depends on the composition of the blends, but has little dependence on the PS grafting yields of LLDPE-g-PS. (C) 1998 Elsevier Science Ltd. All rights reserved.

Compatibilization effect of graft copolymer on immiscible polymer blends .2. LLDPE/PS/LLDPE-g-PS systems

The compatibilizing effect of graft copolymer, linear low density polyethylene-g-polystyrene (LLDPE-g-PS), on immiscible LLDPE/PS blends has been studied by means of C-13 CP-MAS NMR and DSC techniques. The results indicate that LLDPE-g-PS is an effective compatibilizer for LLDPE/PS blends, and the compatibilizing effect of LLDPE-g-PS on LLDPE/PS blends depends on the PS grafting yield and molecular structure of the compatibilizers and also on the composition of the blends. It was found that LLDPE-g-PS chains connect two immiscible components, LLDPE and PS, through solubilization of chemically identical segments of LLDPE-g-PS into the noncrystalline region of the LLDPE and PS domain, respectively. Meanwhile, LLDPE-g-PS chains connect the crystalline region of LLDPE by isomorphism, resulting in an obvious change in the crystallization behavior of LLDPE. (C) 1996 John Wiley & Sons, Inc.