306 resultados para transparent glass ceramics


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Transparent polycrystalline Yb:YAG ceramics were fabricated by solid-state reactive sintering a mixture of commercial Al2O3, Y2O3, and Yb2O3 powders. The powders were mixed in ethanol and doped with 0.5 wt% tetraethoxysilane, dried, and pressed. Pressed samples were sintered at 1730 degrees C in vacuum. Transparent fully dense samples with grain sizes of several micrometers were obtained. The phase from 1500 degrees to 1700 degrees C was important for the grain growth, in which the grains grew quickly and a mass of pores were eliminated from the body of the sample. Annealing was an important step to remove the vacancies of oxygen and transform Yb2+ to Yb3+. The 1 at.% Yb:YAG ceramic sample was pumped by a diode laser to study the laser properties. The maximum output power of 1.02 W was obtained with a slope efficiency of 25% at 1030 nm. The size of the lasering sample was 4 mm x 4 mm x 3 mm.

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采用传统无压烧结工艺制备Nd^3 +掺杂的氧化镧钇透明激光陶瓷,测试了其吸收和荧光光谱.采用Judd-Ofelt理论对Nd^3 +掺杂量为1 .5at %的样品光谱参量进行了计算.根据吸收光谱,拟合得到三个强度参量分别为:Ω2=6 .57×10^-20cm^2,Ω4=2 .04×10^-20cm^2,Ω6=4 .38×10^-20cm^2.根据这三个参量计算了样品的辐射寿命,跃迁几率,荧光分支比,量子效率和品质因子,并对结果作了分析.

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用碳酸盐共沉淀法制备一种新的掺钕氧化镧钇(Nd:Y1.84La0.16O3)纳米粉体,得到颗粒细小、均匀、分散性好、粒径为50~60nm的Nd:Y1.84La0.16O3纳米粉体.分别采用Nd:Y1.84La0.16O3纳米粉料和商业粉料,用传统陶瓷无压烧结工艺制备Nd:Y1.84La0.16O3透明陶瓷.Nd:Y1.8vLa0.16O3纳米粉制备的陶瓷样品的组分均匀、几乎不存在第二相,具有较高的透过率.商业粉制备的陶瓷样品因混料不均匀而在晶界处存在部分第二相,降低了陶瓷的透过率.此外,还运用体视学法预测

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制备了高质量的Yb:YAG透明陶瓷.Yb:YAG透明陶瓷的晶粒尺寸为10μm左右且分布均匀,晶界处和晶粒中没有杂质、气孔的存在.Yb:YAG样品中所有元素分布均匀,不同的晶粒间,晶粒和晶界间成分是一致的,没有出现成分的偏析.4mm厚样品的透过率为80%.LD泵浦获得了波长为1030nm,最大功率为268mW的连续激光输出.

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采用传统无压烧结工艺制备了Er^3+/Yb^3+共掺的氧化镧钇透明陶瓷并对其光谱性能进行了研究.样品具有较大的吸收和发射截面.La2O3的添加使样品的荧光寿命(τs)与玻璃接近,当Yb^3+和Er^3+的掺杂量分别为5at%和0.5at%时,测得τs=9.65ms.这种荧光寿命长、发射截面大和线宽窄的特性有利于微型、可集成化和大功率激光输出的实现.

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研究了La2O3对Yb:Y2O3透明陶瓷光谱性能的影响,添加适量La2O3以后,Yb:Y2O3透明陶瓷的吸收峰和发射峰的位置不变,但由于La^3+的离子半径大于Y^3+的离子半径,在Y2O3中引入La^3+离子后,导致Y2O3晶格常数变大,晶场强度变弱,同时降低了Y2O3晶体的有序度,致使发射峰强度有所下降,发射截面变小.过量的№La2O3(x=0.16)造成yb^3+激活离子发射强度明显下降;其荧光寿命在添加La2O3后总体增大45%-60%.

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The up-conversion luminescence of Yb3+-doped yttriurn lanthanum oxide transparent ceramic was investigated. It was ascribed to cooperative luminescence originated from the coupled states of the Yb3+ ion pairs. The proper doping of La2O3 can remove the cooperative luminescence of Yb3+ ion. But excessive La2O3 (at least 10 at.%) the cooperative up-conversion of Yb3+:Y2O3 is obtained again, and the intensity of up-conversion luminescence strengthens with the increase of La2O3 content. (c) 2007 Elsevier B.V. All rights reserved.

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Luminescence characteristics of Yb3+, La3+ codoped yttrium oxide nanopowders were investigated. The grain size and the crystallinity of (Yb0.05Y0.90La0.05)(2)O-3 nanopowders increase with the increase of calcination temperature. The average grain size of the nanopowders calcined at 1100 degrees C is 66 nm and its cooperative up-conversion luminescence centered at 498 nm was detected due to nanometer size effect and perfect crystallinity. However, the cooperative up-conversion luminescence of (Yb0.05Y0.90La0.05)(2)O-3 transparent ceramics was not detected. (c) 2008 Elsevier B.V. All rights reserved.

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To understand mechanisms underlying laser-induced damage of BK7 and fused silica, we calculate the temperature field of the substrates with CO2 laser irradiating at a given laser power and beam radius. We find that the two glasses show different thermal behaviors. A model is developed for estimating the time t to heat the surface of the substrates up to a particular temperature T with cw CO2 laser irradiation. We calculate theoretically the duration t that the samples are irradiated, from the beginning to visual catastrophic damage, with the assumption of damage threshold determined by the critical temperature. The duration t that the samples are irradiated, from the beginning to visual catastrophic damage, is investigated experimentally as well. Here we take the melting point or softening point as the critical temperature, given the thermomechanical coupling properties, which is enough to cause damage for BK7. Damage features are characterized by the sound of visual cracks. Finally, we calculate stresses induced by laser heating. The analysis of stress indicates that the damage of BK7 is due to the stresses induced by laser heating. (c) 2005 Society of Photo-Optical Instrumentation Engineers.

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To understand mechanisms underlying laser-induced damage of BK7 and fused silica, we calculate the temperature field of the substrates with CO2 laser irradiating at a given laser power and beam radius. We find that the two glasses show different thermal behaviors. A model is developed for estimating the time t to heat the surface of the substrates up to a particular temperature T with cw CO2 laser irradiation. We calculate theoretically the duration t that the samples are irradiated, from the beginning to visual catastrophic damage, with the assumption of damage threshold determined by the critical temperature. The duration t that the samples are irradiated, from the beginning to visual catastrophic damage, is investigated experimentally as well. Here we take the melting point or softening point as the critical temperature, given the thermomechanical coupling properties, which is enough to cause damage for BK7. Damage features are characterized by the sound of visual cracks. Finally, we calculate stresses induced by laser heating. The analysis of stress indicates that the damage of BK7 is due to the stresses induced by laser heating. (c) 2005 Society of Photo-Optical Instrumentation Engineers.

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Optical properties and microstructure of Ag film on glass substrate with Cr intermediate layer were studied by using spectrophotometer and XRD. The spectra results showed that introducing Cr intermediate layer reduced the surface roughness and promoted the reflectivity of Ag film. The XRD analysis showed that the crystalline grains increased and the stress decreased. The adhesion was also improved by using the tape test method. (c) 2006 Published by Elsevier B.V.

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A total integrated scattering (TIS) measurement was performed to investigate the surface and volume scattering of K9 glass substrates with low reflectance. Ag layers with thicknesses of 60 nm were deposited on the front and back surfaces of the K9 glass substrates by the magnetron sputtering technique. Surface scattering of the K9 glass substrate was obtained by the TIS measurement of the Ag layers on the assumption that the Ag layers and the K9 substrate had the same surface profile. Volume scattering of the substrates was deduced by subtracting the front and back surface scattering from the total scattering of the substrates. (c) 2005 Optical Society of America.

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A method for the design of an all-dielectric nonpolarizing prism beam splitter utilizing the principle of frustrated total internal reflection is reported. The nonpolarizing condition for a prism beam splitter is discussed, and some single layer design examples are elaborated. The concept can be applied to a wide range of wavelengths and arbitrary transmittance values, and with the help of a computer design program examples of 400-700 nm, T-p = T-p = 0.5 +/- 0.01, with incident angles of 45 degrees and 62 degrees are given. In addition, the sensitivity and application of the design are also discussed. (c) 2006 Optical Society of America.

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A new model for analyzing the laser-induced damage process is provided. In many damage pits, the melted residue can been found. This is evidence of the phase change of materials. Therefore the phase change of materials is incorporated into the mechanical damage mechanism of films. Three sequential stages are discussed: no phase change, liquid phase change, and gas phase change. To study the damage mechanism and process, two kinds of stress have been considered: thermal stress and deformation stress. The former is caused by the temperature gradient and the latter is caused by high-pressure drive deformation. The theory described can determine the size of the damage pit. (c) 2006 Optical Society of America.

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Effects of alumina and chromium interlayers on the microstructure and optical properties of thin Ag films are investigated by using spectrophotometry, x-ray diffraction and AFM. The characteristics of Ag films in Ag/glass, Ag/Al2O3/glass and Ag/Cr/glass stacks are analysed. The results indicate that the insertion of an Al2O3 or Cr layer decreases the grains and influences the reflectance of Ag films. The reflectance of the Ag film can be increased by controlling the thickness of alumina interlayer. The stability of Ag films is improved and the adhesion of Ag films on glass substrates is enhanced by alumina as an interlayer.