E_0值对潜水蒸发计算精度影响分析

目前常用潜水蒸发经验公式中,都包含了埋深为零时的潜水蒸发强度,并认为可用水面蒸发强度代替。但对不同土质,由于土壤含水孔隙大小及与大气直接交换的空间不同,必然造成不同土壤质地埋深为零时的蒸发量差异。选用阿维里扬诺夫公式、清华公式和叶氏公式,利用新疆渭干河灌区地下水均衡试验场实测潜水蒸发数据、就E0分别为水面蒸发强度和埋深为零时潜水蒸发强度两种情况进行计算与对比分析。结果表明:除细砂和砾石外,若用水面蒸发强度代替埋深为零时的潜水蒸发强度,计算结果会产生一定误差,应选用埋深为零时的潜水蒸发强度进行计算。提出了清华公式中参数η新的求解方法,建立了η与地下水埋深的指数函数关系。研究结果对潜水蒸发经验公式求解不同土质潜水蒸发量时E0的选用及清华公式中参数η的计算提供参考。

中国陆地生态信息空间化技术研究(Ⅲ):温度、降水等气候要素

利用国家气象局722个气象台站1971～2000年的气象资料,采用三维二次趋势面分析与空间插值相结合等方法,在ArcGIS平台上对气温、降水、空气湿度等气候要素进行空间化,生成国家尺度的1km×1km栅格各种要素气候图180多幅。经检验,平均绝对误差,平均气温和平均最高、最低气温为0.5℃左右,极端最高气温为1℃左右,极端最低气温为1.5℃左右,平均风速为0.4m·min-1;而平均相对误差,≥0℃、5℃、10℃、15℃的积温和平均相对湿度多在5%以下,降水量和饱和差在10%左右;其空间化的精度基本上达到

Efficient and divergent synthesis of cyclophosphamide analogues from 2-arylamino-3-acetyl-5, 6-dihydro-4H-pyrans

A facile and efficient one-pot synthesis of substituted cyclophosphamidic chlorides and their analogues has been developed from readily available enaminones, 2-arylamino-3-acetyl-5,6-dihydro4H-pyrans.

(Z)-2-(2-chloro-3,3,3-trifluoroprop-1enyl)-6-methoxyphenyl acetate

The crystal structure of the title compound, C12H10ClF3O3, was determined in order to establish the configuration of the C double bond. The compound was found to be the Z isomer. The crystal structure is dominated by Cl center dot center dot center dot O halogen bonds [Cl center dot center dot center dot O = 3.111 (3) angstrom], as well as C-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen-bonding interactions, that connect neighboring molecules into a three-dimensional supramolecular network.

Bis(2,2 '-bipyridine)(5,6-epoxy-5,6-dihydro-[1,10] phenanthroline)ruthenium: Synthesis and electrochemical and electrochemiluminescence characterization

In this work, an electrochemiluminescence (ECL) reagent bis(2,2'-bipyridine)(5,6-epoxy-5,6-dihydro-[1,10]phenanthroline)ruthenium complex (Ru-1) was synthesized, and its electrochemical and ECL properties were characterized. The synthesis of Ru-1 was confirmed by IR spectra, element analysis, and H-1 NMR spectra. For further study, its UV-vis absorption and fluorescence emission spectra were investigated. Ru-1 also exhibited quasi-reversible Ru-II/Ru-III redox waves in acetonitrile solution. The aqueous ECL behaviors of Ru-1 were also studied in the absence and in the presence of tripropylamine.

The first soluble conjugated poly(2,6-anthrylene): synthesis and properties

The first soluble conjugated poly(2,6-anthrylene) with 9,10-diphenyl-anthracene as the repeating unit is reported; photophysical studies reveal that this polymer represents a novel well-conjugated system.

Bulk ultrafine binderless (W0.4Al0.6)C prepared by high pressure sintering

Pure (W0.4Al0.6)C powder of about 1 mu m in diameter was sintered by the high pressure sintering (HPS) process without the addition of any binder phase. The microstructure, Vickers micro hardness and density versus the sintering time and temperature are well described. The most suitable sintering condition under pressure of 4.5 GPa is 1873 K for 8 min. Under this sintering condition, the hardness can reach 2295 kg mm(-2) and the relative density can reach 98.6%.

SiO2 nanoparticles as scatterers for random organic laser action in red fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran doped polystyrene films

Random multimode lasers are achieved in 4-(dicyanomethylene)-2-tert-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped polystyrene thin films by introducing silicon dioxide (SiO2) nanoparticles as scatterers. The devices emit a resonance multimode peak at a center wavelength of 640 nm with a mode linewidth less than 0.87 nm. The threshold excitation intensity is as low as 0.25 mJ pulse(-1) cm(-2). It can be seen that the microscopic random resonance cavities can be formed by multiple scattering of SiO2 nanoparticles.