Understanding the branching ratios of chi(c1) -> phi phi,omega omega,omega phi observed at BES-III

In this work, we discuss the contribution of the mesonic loops to the decay rates of chi(c1) -> phi phi, omega omega, which are suppressed by the helicity selection rules and chi(c1) -> phi omega, which is a double- Okubo- ZweigIizuka forbidden process. We find that the mesonic loop effects naturally explain the clear signals of chi(c1) -> phi phi, omega omega decay modes observed by the BES Collaboration. Moreover, we investigate the effects of the omega - phi mixing, which may result in the order of magnitude of the branching ratio BR(chi(c1) -> omega phi) being 10(-7). Thus, we are waiting for the accurate measurements of the BR(chi(c1) -> omega omega), BR(chi(c1) -> phi phi) and BR(chi(c1) -> omega phi) which may be very helpful for testing the long- distant contribution and the omega - phi mixing in chi(c1) -> phi phi, omega omega, omega phi decays.

Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes

Crosslinked polymeric salen-Co(III) complexes derived from a novel dialdehyde and a trialdehyde were synthesized and employed in the hydrolytic kinetic resolution (HKR) of terminal epoxides. Up to 99%, ee were obtained with only 0.16-0.02 mol%,, of catalyst (based on catalytic unit). (C) 2003 Elsevier Ltd. All rights reserved.

Novel Potentiometric Membrane Sensor for the Determination of Trace Amounts of Chromium(III) Ions

A plasticized Cr3+ ion sensor by incorporating 2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene (TTCT) ionophore exhibits a good potentiometric response for Cr3+ over a wide concentration range (1.0×10-6-1.0×10-1 M) with a slope of 19.5 mV per decade. The sensor response is stable for at least three months. Good selectivity for Cr3+ in comparison with alkali, alkaline earth, transition and heavy metal ions, and minimal interference are caused by Li+, Na+, K+, Co2+, Hg2+, Ca2+, Pb2+ and Zn2+ ions, which are known to interfere with other chromium membrane sensors. The TTCT-based electrode shows a fast response time (15 s), and can be used in aqueous solutions of pH 3 - 5.5. The proposed sensor was used for the potentiometric titration of Cr3+ with EDTA and for a direct potentiometric determination of Cr3+ content in environmental samples.