Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes
Data(s) |
08/09/2003
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Resumo |
Crosslinked polymeric salen-Co(III) complexes derived from a novel dialdehyde and a trialdehyde were synthesized and employed in the hydrolytic kinetic resolution (HKR) of terminal epoxides. Up to 99%, ee were obtained with only 0.16-0.02 mol%,, of catalyst (based on catalytic unit). (C) 2003 Elsevier Ltd. All rights reserved. |
Identificador | |
Idioma(s) |
英语 |
Fonte |
宋玉明;陈惠林;胡信全;白长敏;郑卓.Highly enantioselective resolution of terminal epoxides with cross-linked polymeric salen-Co(III) complexes,TETRAHEDRON LETTERS,2003,44():7081-7085 |
Tipo |
期刊论文 |