炭载微过氧化物酶-11电极对O_2和H_2O_2还原的电催化性能

通过平衡吸附法将微过氧化物酶 -1 1 (MP-1 1 )沉积到活性炭上制成 MP-1 1 /C催化剂 ,利用循环伏安法、线性扫描法和旋转圆盘电极技术研究了该催化剂对 O2 和 H2 O2 的电催化还原 .结果表明 ,MP-1 1 /C对 O2和 H2 O2 的电化学还原均具有较好的催化活性 ,并且氧的还原机理与溶液 p H值有关 ,为生物燃料电池的研制提供了一种较好的酶固定方法和一种比较有希望的氧还原催化剂

微过氧化酶-11在聚赖氨酸修饰银电极上的电化学及电催化

发现利用吸附在粗糙Ag电极上的聚赖氨酸(Ply),以静电作用方式固定微过氧化酶-11(MP-11)来制备MP-11/Ply/Ag修饰电极,不但方法简单,而且制得的修饰电极对O2的还原有高的电催化活性和好的稳定性.另外还发现MP-11分子中血红素的第六配体被配位能力较强的配体,如咪唑取代时,其本身的氧化还原电位负移,对O2还原的电催化活性降低.

Resonance Raman and surface-enhanced Raman spectroscopic study of microperoxidase-11

The electron transfer and structure of microperoxidase-11(MP-11) in solution and at electrode/solution interface were studied by electrochemical, resonance Raman and surface-enhanced Raman spectroscopic techniques. Results show that the central iron in heme group was six-coordinated in solution, whereas it was converted to five-coordinated state as MP-11 was adsorbed on the surface of a roughened silver electrode, due to the reorientation of MP-11 molecules. The electrochemical properties of MP-11 were directly affected by the coordination state of heme iron.

Influence of annealing on structure of Nylon 11

Differential scanning calorimeter (DSC), wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS), and density techniques have been used to investigate the structural parameters of the solid state of Nylon 11 annealed at different temperatures. The equilibrium heat of fusion Delta H-m(0) and equilibrium melting temperature T-m(0) were estimated to be 189.05 J g(-1) and 202.85 degrees C respectively by using the Hoffman-Weeks approach. The degree of crystallinity (W-c,W-x) ranged approximately 24-42% was calculated by WAXD and compared with those by calorimetry (W-c,W-h) and density (W-c,W-d) measurements. The radius of gyration R-g, crystalline thickness L-c, noncrystalline thickness L-a, long period L, semiaxes of the particles (a, b), electron-density difference between the crystalline and noncrystalline regions eta(c) - eta(a), and the invariant Q increased with increasing annealing temperature. The analysis of the SAXS data was based upon the particle characteristic function and the one-dimensional electron-density correlation function. An interphase region existed between the crystalline and noncrystalline region with a clear dimension of about 2 nm for semicrystalline Nylon 11. Instead of the traditional two-phase model, a three-phase model has been proposed to explain these results by means of SAXS.

Electrocatalytic reduction of O-2 and H2O2 at the glass carbon electrode modified with microperoxidase-11

Electrocatalytic reduction of O-2 and H2O2 at the glass carbon electrode modified with microperoxidase-11 immobilized with Nafion film has been studied by means of cyclic voltammetry and rotating disk electrode techniques. The modified electrode shows high catalytic activity toward the reduction of both O-2 and H2O2. The rate constants of Oz and H2O2 reduction at the modified electrode have been measured and compared. It is found that O-2 undergoes a four-electron reduction at the modified electrode and the catalytic activity for the reduction of O-2 is dependent on the pH of the solutions.

Crystal transformation of Nylon 11 using in situ WAXD

alpha Form Nylon 11 films were found to exist a non-linear transformation at 70 degrees C during the heating process using in situ WAXD. The alpha Form disappeared but delta Form appeared when the temperature was higher 70 degrees C.

微过氧化物酶-11修饰电极对O_2和H_2O_2的电催化还原

运用电化学循环伏安法和旋转圆盘电极技术研究了O2 和H2O2 在Nafion膜固定的微过氧化物酶 11修饰的玻碳 (MP 11 +Nafion/GC)电极上的电化学还原.结果表明,修饰电极对O2 和H2O2 的还原均具有电催化作用.测定和比较了O2 和H2O2 在MP 11 +Nafion/GC电极上电催化还原反应的一些动力学参数.发现O2 在修饰电极上经历了四电子还原 ,且还原过程与溶液的 pH值有关.

Electrochemistry and spectroscopy study on the interaction of microperoxidase-11 with lipid membrane

The interaction of microperoxidase-11 (MP11) with cationic lipid vesicles of didodecyldimethylammonium bromide (DDAB) induces an alpha -helical conformation from random coil conformations in solution and this change then makes heme macrocycle more distorted. DDAB-induced MP11 conformations were investigated by cyclic votammetry (CV), circular dichroism (CD) and UV-vis spectrometry. All results indicate that the binding of MP11 in solution to DDAB vesicles and the ordered structure formation are driven by mostly electrostatic interaction between negatively charged residues in the undecapeptide and positively charged lipid headgroups on the membrane surface. Upon binding to DDAB, its half-peak potential was also changed. The mechanism of the interaction between MP11 and DDAB was also discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

Morphology of conductive blend fibers of polyaniline and polyamide-11

Polyaniline (PANI), a member of the intrinsically conducting polymer (ICPs) family, was blended with polyamide-11 (polyco-aminoundecanoyle) in concentrated sulfuric acid. The above solution was used to spin conductive PANI/polyamide-11 fibers by wet-spinning technology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were employed to study the two-phase morphology of the conductive PANI/polyamide-11 fibers. The micrographs of the cross-section, the axial section and the surface of the monofilament demonstrated that the two blend components were incompatible. The morphology of PANI in the fibers was of fibrillar form, which was valuable for producing conducting channels. The electrical conductivity of the fibers was from 10(-6) to 10(-1) S/cm with the different PANI fraction and the percolation threshold was about 5 wt.%. By comparing the two blend systems of PANI/Polyamide-11 fibers and carbon black filled poly(ethylene terephthalate) (PET) fibers, it was shown that the morphology of the conductive component had an influence on electrical conductivity, The former had higher conductivity and lower percolation threshold than the latter. (C) 2001 Elsevier Science B.V. All rights reserved.

Crystal transitions of Nylon 11 under drawing and annealing

The crystal transitions of Nylon 11 annealed and drawn at different temperatures (T-d) with different drawing ratios (n) were investigated by wide-angle X-ray diffraction (WAXD). The alpha -form of Nylon Il could be transformed from the delta'-form by annealing at high temperature, The results showed that the crystal transitions of Nylon 11 strongly depended on the thermal history and the conditions of drawing. The delta'-form Nylon Il could he gradually transformed into the alpha -form when it was drawn at high temperature and the alpha -form was only partly transformed into the delta'-form when it was drawn at low temperature. This should be due to the effect of the competition between thermal inducement and drawing inducement. The thermal inducement was favorable to producing the alpha -form, while the drawing inducement was favorable to producing the delta'-form. (C) 2001 Elsevier Science Ltd. All rights reserved.

LaMAl_(11)O_(19)(M=Mg,Fe)的化学键性质和穆斯堡尔谱研究

利用复杂晶体化学键的平均能带模型研究了LaMAl11O19(M =Mg ,Fe)晶体的化学键性质。结果表明 ,La O键只有 3%的共价性 ,4f1格位却具有很强的共价特征。晶体中各格位共价次序为 :La O

尼龙11结构与性能的研究进展

结合作者的研究工作 ,综述了尼龙 11的物理化学性质、晶体结构、晶型转变及压电性的研究进展

Photoreduction behaviors of microperoxidase-11 adsorbed on the roughened silver electrodes

It was found that microperoxidase-ll (MP-II) can undergo photoreduction at the bale roughened silver electrode. No photoreduction happens at the roughened silver electrode modified with mercaptoundecanoic carboxylic acid/poly-lysine. The photoreduction mechanism is discussed.

Crystal Structure of [PrAl(CF3COO)(2)(CF3CHOO)(C2H5)(2)(C4H8O)(2)](2)

[PrAl (CF3COO)(2) (CF3CHOO) (C2H5)(2) (C4H8O)(2)](2) M-r = 1420. 56, monoclinic, P2(1)/n, a = 10. 651 (6) , b = 24. 276(9), c = 11. 110(5) Angstrom, beta = 107. 650 (4)degrees , V = 2737. 4(1) Angstrom (3) , Z = 2, D-c = 3. 45 g/cm(3) , F(000) = 2816 , T = 233K, MoK alpha radiation (lambda= 0. 71069 Angstrom), mu(MoK alpha) = 38. 017 cm(-1) , R = 0. 048 for 2847 observed reflections (I greater than or equal to 3 sigma(I)). It is isostructural with [LnAl (CF3COO)(2) (CF3CHOO) -R-2 (C4H8O)(2)](2) (Ln = Ho, R = Et; Ln = Ndt Y, R = Bu-1). Pr3+ is coordinated by eight oxygen atoms from five bridging ligands and two THF forming a distorted bicap-prism.