THE PHYSICAL AND CHEMICAL-PROPERTIES OF SYNTHETIC AND NATURAL JADEITE FOR JEWELRY

Jadeite was synthesized from its glass of stoichiometric composition NaAlSi2O6, and a colouring agent Cr2O3 (0.3-0.6 wt%) was added to achieve the emerald colour. The conditions employed were a pressure range of 3.0-5.0 GPa and a temperature range of 1150

Immunosensor Interface Based on Physical and Chemical Immunogylobulin G Adsorption onto Mixed Self-Assembled Monolayers

An immunosensor interface based on mixed hydrophobic self-assembled monolayers (SAMs) of methyl and carboxylic acid terminated thiols with covalently attached human Immunoglobulin G (hIgG), is investigated. The densely packed and organised SAMs were characterised by contact angle measurements and cyclic voltammetry. The effect of the non-ionic surfactant, Tween 20, in preventing nonspecific adsorption is addressed by ellipsometry during physical and covalent hIgG immobilization on pure and mixed SAMs, respectively. It is clearly demonstrated that nonspecific adsorption due to hydrophobic interactions of hIgG on methyl ended groups is totally inhibited, whereas electrostatic/hydrogen bonding interactions with the exposed carboxylic groups prevail in the presence of surfactant. Results of ellipsometry and Atomic Force Microscopy, reveal that the surface concentration of covalently immobilized hIgG is determined by the ratio of COOH/CH3-terminated thiols in SAM forming solution. Moreover, the ellipsometric data demonstrates that the ratio of bound anti-hIgG/hIgG depends on the density of hIgG on the surface and that the highest ratio is close to three. We also report the selectivity and high sensitivity achieved by chronoamperometry in the detection of adsorbed hIgG and the reaction with its antibody.

Physical and thermal properties of P2O5-Al2O3-BaO-La2O3 glasses

The physical and thermal properties Of P2O5-Al2O3-BaO-La2O3 glasses were investigated. The effects of glass compositions on the transition temperature, thermal expansion coefficient, density, hardness and refractive index of glasses were studied. The highest hardness of the glasses is 4143.891 MPa and the lowest thermal expansion coefficient of the glasses is 71.770 x 10(-7)/° C. A phosphate glass with high mechanical strength and good thermal characteristic is obtained.

Effect of F- ions on physical and spectroscopic properties of Yb3+-doped TeO2-based glasses

The effects of F- ions on physical and spectroscopic properties of the Yb3+ in tellurite glass system are investigated. The results show that the glass system takes on good thermal stability with the content of ZnF2 lower than 15 mol%, both the emission cross-section and the fluorescence lifetime of Yb3+ ions increase evidently which indicate that such oxyfluoride tellurite glass system is a promising laser host matrix for high power generation. FT-IR spectra were used to analyze the effect of F- ions on the structure of tellurite glasses and OH- groups in this glass system. Analysis demonstrates that addition of fluoride decreases the symmetry of the structure of tellurite glasses which increases the emission cross-section and removes the OH- groups, and which improves the measured fluorescence lifetime of Yb3+ ions. (c) 2004 Elsevier B.V. All rights reserved.

Synthesis and chemical properties of [Z]-1-[2-(triaryl stannyl)vinyl]cyclooctanol

The compounds of [Z]-1-[2-(triphenyl stannyl) vinyl] cyclooctanol (1) and [Z]-1-[2-(tri-p-tolyl stannyl) vinyl] cyclooctanol (2) were synthesized by the reactions of triphenyltin hydride and tri-p-tolyltin hydride with 1-ethynyl cyclooctanol. The crystal structure of compound 1 was determined. The reactions of compound 1 and 2 with IC1, Br-2, I-2 formed nine organotin halides. The organotin oxide or hydroxide were prepared by the reactions of [Z]-1-[2-(phenyl dibromo stannyl) vinyl] cyclooctanol (6) and [Z]-1-[2-(diphenyl monobromo stannyl) vinyl] cyclooctanol (5) with KOH. Three complexes were obtained by the reactions of [Z]-1-[2-(phenyl diiodide stannyl) vinyl] cyclooctanol (8) with three ligands (2,2'-bipyridyl,5-nitro-1,10-phenanthroline,8-Hydroxyquinoline). The sixteen new compounds synthesized in this paper were characterized by means of elemental analysis, IR, H-1 NMR. The reaction mechanism of triphenyltin hydride and tri-p-tolyltin hydride with 1-ethynyl cyclooctanol were also proposed.

典型草原土壤性状变化对灌丛化的响应

以草原和稀树草原中木本植物多度的增加为特征的草地灌丛化，是全球范围普遍发生的现象，但灌丛化的生态学效应目前仍存在争议。对灌丛化草地生态系统特征与过程的研究，将有助于我们进一步了解草地生态系统的退化和恢复机理，为退化草原恢复与管理实践提供理论依据。 本研究以位于内蒙古锡林河流域, 一个经23年围封恢复、具有明显灌丛化特征的草原生态系统为研究对象，通过分析小叶锦鸡儿灌丛及其相邻草本群落下的土壤容重、机械组成、土壤有机碳(SOC)、全氮(TN)和无机氮(IN)的差异，确定小叶锦鸡儿灌丛对草原土壤物理化学性状的影响。主要结果如下： （1）小叶锦鸡儿灌丛化增加了表层土壤（0-5 cm）粗粒级颗粒的比例，降低了浅层土壤（0-20 cm）的容重，较大灌丛下10-20 cm土层仍存在这种现象。这至少部分归因于灌丛对凋落物的截获积聚，以及小叶锦鸡儿的根系分泌物在质和量上较之草本植物的不同，促进了土壤团聚体的发育。 （2）小叶锦鸡儿灌丛斑块引起了典型草原生态系统土壤有机碳、全氮和无机氮的空间分布的变化。在浅层土壤中（0-20cm），由灌丛斑块内部向外部SOC、TN和IN均趋于降低。随小叶锦鸡儿灌丛大小（存在时间）的增加，0-20 cm和60-100cm土层SOC和TN均有增加趋势。 （3）除表层（0-5cm）外，小叶锦鸡儿大灌丛与邻近草地土壤C/N比值无显著差异。 总之，小叶锦鸡儿灌丛不仅改变了草原土壤的物理性状，而且提高了灌丛下土壤有机碳和氮的含量，改变了草原生态系统C、N的空间分布格局，表明草原灌丛化明显改变了草原生态系统的碳氮循环。基于草原约占陆地面积的40%以及全球草地灌丛化普遍存在的事实，这种伴随草原灌丛化发生的土壤有机碳和氮的变化可能会对全球碳氮循环和气候有显著影响。

三峡水库蓄水对消落带土壤理化性状的影响

三峡水利枢纽工程的调度运行导致水库水位的涨落，从而在三峡水库周边水陆交错带形成周期性淹没与出露于水面的一段特殊区域，被称为三峡水库消落带。三峡水库消落带生态系统的健康是库岸稳定和水库安全运行的重要保障。土壤养分是三峡库区消落带土壤生态系统的重要组成部分。三峡水库蓄水以来，土壤理化性状发生改变，水土流失日益加剧。土壤是植物的基础，因此，对三峡水库消落带土壤性状的研究对消落带植被恢复有一定的指导意义，也为研究水库消落带水土流失提供依据，为研究水库消落带土壤污染与水体污染提供基础。 本文首先通过对重庆忠县石宝寨水库消落带不同水位、不同时期的表层土壤分析，研究了消落带不同水位土壤容重、酸碱度、有机质、全氮、全磷、全钾、硝态氮、氨态氮、速效磷、速效钾的含量变化。实验结果表明：（1）消落带土壤淹水前各测定指标在不同海拔高程之间的差异均不显著（P>0.05）；（2）三峡水库淹水后消落带土壤由微碱性变为碱性，养分平均含量普遍下降，土壤养分缺乏，淹水易造成养分流失；（3）不同淹水强度下，土壤pH 值、有机质、全氮、全磷、氨态氮、速效钾平均含量差异显著（P＜0.001），经过淹水土壤有机质、全氮、速效钾含量进一步降低；（4）不同淹水时期，土壤全钾、硝态氮、氨态氮平均含量差异显著（P＜0.001），速效氮含量随季节变化较大，与土壤水分有密切关系；（5）干湿交替更容易造成氮、磷解吸释放入水体，从而增加富营养化的风险。 其次，通过对石宝寨消落带5 个时间段6个水位的表层土壤分析，研究了消落带不同时期、不同淹水强度土壤酸碱度及Cu、Zn、Pb、Cr 的含量变化。结果表明（1）淹水土壤pH 显著高于未淹水土壤，长期淹水土壤重金属含量显著高于短期淹水土壤与未淹水土壤，146m 土壤重金属含量最高；（2）经过淹水土壤，pH 先升高后下降，铜含量、锌含量都下降，铬含量先上升后下降，铅含量随着土壤暴露先稍微上升，后又下降，但在08 年9 月达到最大值；（3）各土壤重金属之间均存在显著相关关系，表明三峡消落带土壤存在重金属复合污染隐患；（ 4 ） 以三峡水库土壤背景值为评价标准， 消落带土壤污染程度具有Cu>Pb>Zn>Cr 的特征，其中，铜污染相对最为严重，消落带土壤随着淹水强度的加大与淹水时间的延长，污染程度加重，消落带综合污染指数达到1.24，属于轻度污染级。

间伐对仁用杏园土壤理化性质及生长结果的影响

为了探讨密闭仁用杏园衰败的原因,采用常规的方法研究了间伐对仁用杏园土壤养分、水分及树体生长等方面的影响。结果表明:间伐减小了土壤容重,略微增加了土壤孔隙度;间伐显著提高了0-40 cm土层土壤有机质、0-20 cm土层土壤全氮,略微提高了0-20 cm土层土壤全磷;间伐显著提高了0-80 cm土层土壤速效氮、0-40 cm土层土壤速效磷和0-60 cm土层土壤速效钾,且间伐强度越大土壤养分越高;间伐显著提高了0-500cm土层土壤水分,在干旱的春季、夏季优为显著,且间伐强度越大,土壤水分越高;间伐显著促进了仁用杏生长,提高了坐果率和杏仁产量。白于山山区仁用杏间伐后密度应为167~222株/hm2。

黄土丘陵区不同植被恢复模式对土壤酶活性的影响

为了解侵蚀环境下植被恢复对土壤酶活性的影响,以典型侵蚀环境黄土丘陵区纸坊沟流域生态恢复30a植被长期定位试验点为研究对象,选取坡耕地为参照,分析了植被恢复过程中土壤脲酶、磷酸酶、蔗糖酶、淀粉酶、纤维素酶、过氧化氢酶、多酚氧化酶及理化性质的演变特征。结果表明,黄土丘陵区的坡耕地由于不合理的人为干扰,土壤理化性质和酶活性较弱,通过植被恢复可以有效的改善土壤肥力,不同恢复模式对土壤酶活性和肥力的改善作用不同,恢复30a,脲酶活性增加33%～213%,磷酸酶活性增加275%～394%,蔗糖酶活性增加70%～210%,纤维素酶活性增加24%～48%,过氧化氢酶增加32%～96%,多酚氧化酶降低23%～29%,淀粉酶变化规律不同。不同植被恢复模式其生物特性不同,对土壤酶活性影响也不同。相关性分析说明磷酸酶、蔗糖酶、纤维素酶和多酚氧化酶与其它因子相关性相对较强,可以作为评价土壤质量的生物学指标。

黄延高速公路边坡植被与土壤特性调查研究

采用现场调查、观测、试验等多种试验方法,对黄延高速公路绿化植物、边坡土壤理化性质以及植物群落组成进行了研究。通过分析,总结了中央分隔带、平台和边坡绿化植物种类以及边坡有效配置模式,分析了土壤养分贫瘠的原因和提高措施。在此基础上提出土壤肥力与植物恢复是相辅相成的,土壤肥力随人工植被建立时间的延长而逐渐恢复;随着时间序列的延长,其物种数目和比例也发生较大变化,有利于护坡植物群落最终实现结构稳定。

黄土高原沟坡地土地生产力评价的指标体系与评价方法

通过对渭北黄土高原地区沟坡地土壤理化性质的分析和对当地社会经济状况的调查研究,应用层次分析法对沟坡地上地自然生产力和现实生产力进行了分析和评价。在分析过程中,把当地主要造林树种根系垂直分布特征及其根系抗旱性特性纳入了分析评价体系。结果表明,嘴头村和西坡村不同树种沟坡地上刺槐(Robinia pseudoacacia)的自然生产力属于中等稍微偏上水平,而山杏(Prunus armeniacia var.ansu)、油松(Pinus tabulaeformis)和侧柏(Platycladus orientalis)的自然生产力水平则较低。两地沟坡地上的现实生产力计算结果则证明刺槐和山杏两个树种表现出了较高的水平,具有较好的发展前途;而油松和侧柏的现实生产力水平则较低,其发展推广受到了限制。群众对沟坡开发治理的态度和对开发方案的认可对沟坡开发的成功起到了重要作用。