Pre-column derivatization of amines with 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl chloroformate followed by LC-fluorescence and LC-APCI-MS

A pre-column derivatization method for the sensitive determination of amines using the labeling reagent 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl chloroformate (BCIC-Cl) followed by high-performance liquid chromatography with fluorescence detection has been developed. Identification of derivatives is carried out by high performance liquid chromatography/atmospheric pressure chemical ionization (LC-APCl-MS-MS). The chromophore of 2-(9-carbazole)-ethyl chloroformate (CEOC) reagent is replaced by 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl functional group, which results in a sensitive fluorescence derivatizing reagent BCIC-Cl. BCIC-Cl can easily and quickly label amines. Derivatives are stable enough to be efficiently analyzed by high-performance liquid chromatography and show an intense protonated molecular ion corresponding m/z [MH](+) under APCl in positive-ion mode. The collision-induced dissociation of protonated molecular ion formed a product at m/z 260 corresponding to the cleavage of CH2-OCO bond. Studies on derivatization demonstrate excellent derivative yields over the pH 9.0-10.0. Maximal yields close to 100% are observed with a 3 to 4-fold molar reagent excess. In addition, the detection responses for BCIC derivatives are compared with those obtained using CEOC and FMOC as derivatization reagents. The ratios of l(BCIC)/l(CEOC) and l(BCIC)/l(FMOC) are, respectively, 1.23-3.14 and 1.25-3.08 for fluorescent (FL) responses (here, l is relative fluorescence intensity). Separation of the derivatized amines had been optimized on reversed-phase Eclipse XDB-C-8 column. Detection limits are calculated from 1.0 pmol injection, at a signal-to-noise ratio of 3, are 10.6-37.8 fmol. The mean interday accuracy ranges from 94 to 105% for fluorescence detection with the largest mean %CV < 7.5. The mean interday precision for all standards is < 6.0% of the expected concentration. Excellent linear responses are observed with coefficients of > 0.9997.

黄海海域前新生代残留盆地综合地质地球物理研究

China’s annual oil import volume has been increasing in recent years, but the oil price in the international market fluctuates and poses a severe threat to China’s economic development and national security. Therefore, it is of great importance to study the gas and oil exploration of Pre-Cenozoic Residual Basins in Yellow Sea. Yellow Sea has widespread and thick Mesozoic and Paleozoic strata that contain multilayer source rock. Hence, Yellow Sea Mesozoic and Paleozoic strata have good conditions of forming Pre-Cenozoic hydrocarbon reservoirs. Pre-Cenozoic Residual Basins are usually buried deep and then transformed many times in its long evolutional history. These characteristics make it difficult to apply a single method in exploring Pre-Cenozoic Residual Basins. On the other hand, it is highly effective to solve key problems of gas and oil exploration of Pre-Cenozoic Residual Basins in Yellow Sea by using integrated geological and geophysical methods which make full use of the advantages of various exploring techniques. Based on the principle of “the region controls the local; the deep restricts the shallow,” this study focuses on Pre-Cenozoic Residual Basins in Yellow Sea to describe the structure frame of its distribution, with gravity, magnetic, seismic, drill-hole and geological data and previous research findings. In addition, the distribution characteristics of Pre-Cenozoic Residual Basins in Yellow Sea are also analyzed. This paper explores the characteristics of error between gravity forward with constant density and gravity forward with variable density through the study on 2-D and 3-D gravity forward in frequency domain. The result shows that there is a linear relationship between error and depth of 2-D geological model but there is a nonlinear relationship between error and depth of 3-D geological model. The error can be removed according to its linear characteristics or statistical nature of nonlinear characteristics. There is also error between gravity inversion with constant density and gravity inversion with variable density due to variable density and edge-effect. Since there are not noticeable rules between the error and the two causes as variable density and edge-effect, this study adopts gravity inversion with variable density and methods to eliminate the edge-effect in basement inversion to improve inversion accuracy. Based on the study on the rock physical properties and strata distribution of Yellow Sea and adjacent regions, this study finds that there is a big density contrast between Cretaceous-Jurassic strata and their substratum. The magnetic basement of south Yellow Sea is regarded as top of Archeozoic-Proterozoic early strata, and there are double magnetic basements in north Yellow Sea. Gravity and magnetic data are used to inverse the gravity basement and magnetic basement of Yellow Sea, with seismic and drill-hole data as constrains. According to data of gravity and magnetic basement distribution, the depth of Cenozoic strata and previous research findings, this paper calculates the thickness of the Mesozoic and Pre-Mesozoic Residual Basins, draws the distribution outline of Pre-Cenozoic Residual Basins in Yellow Sea, and analyzes its macro-distribution characteristics. Gravity inversion is applied on a typical geological profile in Yellow Sea to analyze the characteristics of its fractures and magnetic basements. The characteristics of Pre-Cenozoic Residual Basins distribution outline in Yellow Sea and the fractures and magnetic basements of its typical profile shown by profile inversion provides new geophysical evidence for these structure views such as “the South Yellow Sea and the North Yellow Sea belong to different structural units” and “Sino-Korea and Yangtze blocks combine along Yellow Sea East Fractured Zone in Yellow Sea”.

鄂尔多斯盆地西缘中生代构造与地层分析及盆地演化研究

Through the detailed analyses of Mesozoic tectono-stratigraphy and basin formation dynamic mechanism and the styles of different units in the western margin of Ordos Basin(Abbreviated to "the western margin"), while some issues of the pre-Mesozoic in the western margin and central part of Ordos Basin also be discussed, the main views and conclusion as follows: 1. There are three types of depositional systems which are related with syndepositional tectonic actions and different tectonic prototype basins, including: alluvial fan systems, river system (braided river system and sinuosity river system), lacustrine-river delta system and fan delta system. They have complex constitutions of genetic facies. For the tectonic sequence VI, the fan sediments finning upper in the north-western margin and coarse upper in the south-western margin respectively. 2. In order to light the relationship between basin basement subsidence rate and sediment supply and the superposed styles, five categories of depositional systems tracts in different prototype basins were defined: aggrading and transgressive systems tracts during early subsidence stage, regressive and aggrading systems tracts during rapid subsidence, upper transgessive systems tracts during later subsidence stage. Different filling characteristics and related tectonic actions in different stages in Mesozoic period were discussed. 3. In order to determined the tectonic events of the provenance zones and provenance strata corresponding to basins sediments, according the clastics dispersal style and chemical analyses results of sediments in different areas, the provenance characteristics have been described. The collision stage between the "Mongolia block" and the north-China block may be the late permian; The sediments of Mesozoic strata in the north-western margin is mainly from the Alex blocks and north-Qilian Paleozoic orogeny, while the south-western margin from Qinling orogeny. The volcanic debris in the Yan'an Formation may be from the arc of the north margin of north-China block, although more study needed for the origin of the debris. The provenance of the Cretaceous may be from the early orogeny and the metamorphic basement of Longshan group. 4. The subsidence curve and subsidence rate and sedimentary rate in different units have been analyzed. For different prototype basin, the form of the subsidence curves are different. The subsidence of the basins are related with the orogeny of the basins.The beginning age of the foreland basin may be the middle Triassic. The change of basement subsidence show the migration of the foredeep and forebulge into the basin. The present appearance of the Ordos basin may be formed at the late stage of Cretaceous, not formed at the late Jurassic. 5. The structure mode of the west margin is very complex. Structure transfer in different fold-thrust units has been divided into three types: transfer faults, transition structures and intersected form. The theoretic explanations also have been given for the origin and the forming mechanism. The unique structure form of Hengshanpu is vergent west different from the east vergence of most thrust faults, the mechanism of which has been explained. 6. In Triassic period, the He1anshan basin is extensional basin while the Hengshanbu is "forland", and the possible mechanism of the seemingly incompatible structures has been explained. First time, the thesis integrate the Jurassic—early Cretaceous basins of west margin with the Hexi corridor basins and explain the unitive forming mechanism. The model thinks the lateral extrusion is the main mechanism of the Hexi corridor and west margin basins, meanwhile, the deep elements and basement characters of the basins. Also, for the first time, we determine the age of the basalt in Helanshan area as the Cretaceous period, the age matching with the forming of the Cretaceous basins and as the main factor of the coal metamorphism in the Helanshan area. 7. The Neoprotterozoic aulacogen is not the continuation of the Mesozoic aulacogen, while it is another new rift stage. In the Paleozoic, the Liupanshan—southern Helanshan area is part of the back-arc basins of north Qilian ocean. 8. The Helanshan "alacogen" is connected with the north margin of north China block, not end at the north of Zhouzishan area like "appendices". Also, I think the upper Devonian basin as the beginning stage of the extensional early Carboniferous basins, not as a part of the foreland basins of Silurian period, not the collision rift. 9. The controlling factor of the difference of the deformation styles of the north-west margin and the south-west margin is the difference of the basements and adjacent tectonic units of the two parts.

Detection of Myxobolus rotundus (Myxozoa : Myxosporea) in skin mucus of crucian carp Carassius auratus auratus using a monoclonal antibody

Diagnosis of myxosporean Myxobolus rotundus infection was conducted by examining skin mucus from the infected crucian carp Carassius auratus auratus with a monoclonal antibody, MAb 2D12, raised previously against the parasite. A positive reaction was observed in skin mucus collected from infected fish, and spores and pre-spore stages of the parasite were identified by the MAb 2D12. It was also demonstrated that M. rotundus infection can be successfully detected by a simple method, enzyme-linked immunosorbent assay (ELISA), and that skin mucus collected from infected fish skin had a significantly higher optical density (OD) value than that from uninfected fish.

Amphi-Eomes/Tbr1: An amphioxus cognate of vertebrate Eomesodermin and T-Brain1 genes whose expression reveals evolutionarily distinct domain in amphioxus development

A cDNA for a novel T-box containing gene was isolated from the amphioxus Branchiostoma belcheri. A molecular phylogenetic tree constructed from the deduced amino acid sequence of the isolated cDNA indicates that this gene belongs to the T-Brain subfamily. In situ hybridization reveals that the expression is first detected in the invaginating archenteron at the early gastrula stage and this expression is down-regulated at the neurula stage. In early larvae, the expression appears again and transcripts are detected exclusively in the pre-oral pit (wheel organ-Hatschek's pit of the adult). In contrast to the vertebrate counterparts, no transcripts are detected in the brain vesicle or nerve cord throughout the development. These results are interpreted to mean that a role of T-Brain products in vertebrate forebrain development was acquired after the amphioxus was split from the lineage leading to the vertebrates. On the other hand, comparison of the tissue-specific expression domain of T-Brain genes and other genes between amphioxus and vertebrates revealed that the pre-oral pit of amphioxus has several molecular features which are comparable to those of the vertebrate olfactory and hypophyseal placode. (C) 2002 Wiley-Liss, Inc.

Petroleum geological framework and hydrocarbon potential in the Yellow Sea

Sedimentary basins in the Yellow Sea can be grouped tectonically into the North Yellow Sea Basin (NYSB), the northern basin of the South Yellow Sea (SYSNB) and the southern basin of the South Yellow Sea (SYSSB). The NYSB is connected to Anju Basin to the east. The SYSSB extends to Subei Basin to the west. The acoustic basement of basins in the North Yellow Sea and South Yellow Sea is disparate, having different stratigraphic evolution and oil accumulation features, even though they have been under the same stress regime since the Late Triassic. The acoustic basement of the NYSB features China-Korea Platform crystalline rocks, whereas those in the SYSNB and SYSSB are of the Paleozoic Yangtze Platform sedimentary layers or metamorphic rocks. Since the Late Mesozoic terrestrial strata in the eastern of the NYSB (West Korea Bay Basin) were discovered having industrial hydrocarbon accumulation, the oil potential in the Mesozoic strata in the west depression of the basin could be promising, although the petroleum exploration in the South Yellow Sea has made no break-through yet. New deep reflection data and several drilling wells have indicated the source rock of the Mesozoic in the basins of South Yellow Sea, and the Paleozoic platform marine facies in the SYSSB and Central Rise could be the other hosts of oil or natural gas. The Mesozoic hydrocarbon could be found in the Mesozoic of the foredeep basin in the SYSNB that bears potential hydrocarbon in thick Cretaceous strata, and so does the SYSSB where the same petroleum system exists to that of oil-bearing Subei Basin.

四川盆地构造控藏规律研究

Firstly, established sequence stratigraphy of Sinian System-Middle Triassic Series framework in Sichuan basin,be divided into 21 second-level sequence stratigraphy and 105 third-level sequence stratigraphy.From many aspects,discussed sequence stratigraphy characteristic. On the foundation of structure unconformity and fission track analysis, on the ground of An county-Shuinin county regional seismic section, using the positive evolution equilibrium principle technology, comprehensivly be mapped structure evolution of Sichuan basin. It can be divided into seven stages, that is :Pre-Sinian basement stage, cratonic depression basin(Z1-S)stage, cratonic rifted basin(D-T2)stage, passive continental margin(T3x1-3)stage, foreland basin(T3x4-6)stage, depression basin (Jurassic Period-Miocene Epoch) stage, formed basin (Holocene Epoch) stage. Analysis on structure evolution history,burial history,source rocks thermal evolution history, Maoba changxing formation gas pool forming process can be classified into four stages: ancient lithological oil pool stages in Indosinian-early Yanshanian period（T-J1-2）, ancient structure- lithological gas pool stages in middle Yanshanian period（J3-K1）, structure- lithological gas pool setting stages in last Yanshanian period（K2）, structure- lithological gas pool adjusting and transformation stages in Himalayan period（R-Q）. Maoba feixianguan formation gas pool forming process can be classified into two stages: second structure gas pool stages in last Yanshanian period（K2）,second structure gas pool physical adjusting and transformation stages in Himalayan period（R-Q）,and summarize reservoir formation model. On the base of newest exploration achievement and petroleum geologic comprehensive research , demonstrate how structure controls hydrocarbon accumulation. Structure controlling source rocks behaves structure controlling main source rocks’sedimentary facies, medium-large pools mainly located at center or margin of hydrocarbon generation. Structure controlling palaeo-karst reservoirs ,reef and beach facies reservoirs, fault and fracture reservoirs. Structure controlling palaeo-uplift, and palaeo-uplift controlling hydrocarbon migration, active reservoirs’forming, palaeo-structure traps forming. Structure controls distribution of mudstone and gypsolith, controls preservation. Structure controls hydrocarbon conducting, structure traps forming and hydrocarbon accumulation. Whether or no, Structure controls total process of basin forming-source rocks’generation- hydrocarbon accumulation. It is direct effect results of structure movements that large traps’ conditions, conducting migration conditions, high quality preservation. source rocks’condition and reservoirs’ condition are the indirect effect results. In the last analysis, “source rock controlling theory”, “high quality reservoir mainly controlling theory”, “palaeo-uplift controlling theory” and “current structure deciding theory” are structure controlling hydrocarbon accumulation. There are high variability and complex mechanisms in Sichuan basin , but the regional hydrocarbon accumulation conditions are very well, such as abundant source rocks, matching process of hydrocarbon accumulation and many exploration areas. By means of integrated analysis, put forward hydrocarbon exploration direction and large-middle targets of China Petroleum and Chemical Corporation .Thus, more and more hydrocarbon proved reserve and output in Sichuan basin will be contributed to China energy industry in a long future time.

牡丹江碰撞带的组成及演化

Jiamusi Massif is an important tectonic unit in Northeast China. It’s significant for understanding the evolution of Paleo-Asian Ocean and reconstruction of the tectonic framework of Northeast China. Mudanjiang area is located in the southern margin of Jiamusi Massif and is the key to understand the evolution of Jiamusi Massif. However, the detailed geological research for Mudanjiang area has long been deficient in many important problems, such as the tectonic components of the Mudanjiang collision zone (MCZ), the age of collisional complexes and the scenario of tectonic evolution. Based on the lithology, geochemistry and the SHRIMP zircon U-Pb geochronology in Mudanjiang area, our new data and results come to some constraints for the tectonic reconstruction of MCZ as follows: 1） It is identified that the former suggestion, which the so-called “Heilongjiang Group” in Mudanjiang area is the vestige of oceanic crust, is correct. The oceanic relics represent the Neo-Proterozoic-Early Paleozoic oceanic basins based on the SHRIMP zircon U-Pb geochronology. 2） One sheet of gabbroic complex with oceanic island-type geochemical signature was discovered by this work in Mudanjiang area. 3） It is verified that the Proterozoic concordant U-Pb ages of the migmatites developed along the southern margin of Jiamusi massif, which represent the events of magmatic intrusion, as the direct evidence for the existence of the Proterozoic crystalline basements of the Jiamusi Massif. Based on geochronology, we suggest that the migmatization and coeval S-type granite magmatism of the southern margin of Jiamusi Massif took place about 490Ma. 4） The island arc complex has been found in the Heilongjiang Group, and the oceanic relics was found distributing on both sides, as provided important constraint for the tectonic reconstruction of the MCZ. 5） ~440Ma metamorphic event and coeval post-collisional granite magmatism have been firmly identified in the MCZ and its southern neighboring area. Together with previous data obtained by other researchers, our conclusions on the reconstruction of the tectonic architecture and evolution of the MCZ as follows: 1） The orogenic assemblages developed in the Mudanjiang collisional zone are featured by a sequence of ancient active continental margins and ensuing orogenic processing. The Mashan Group is the reworking basement of Jiamusi Massif, whereas the Heilongjiang Group represents arc and oceanic complexes characterized by imbricate deep-seated sliced and slivering sheets due to multi-phases of thrusting and nappe stacking. 2） The northern sub-belt of MCZ is probably the arc-continent collisional boundary related to the closure of main oceanic basin. The collisional age can be constrained by the events of syn-orogenic migmatization of migmatite, coeval S-type granite magmatism and the related granulite-facies metamorphism. Therefore, we suggested the collisional age of northern sub-belt is probably Cambrian-Early Ordovician. The extensive granulite-facies metamorphism of the Mashan Group in Jiamusi Massif, as affirmed by former works, was probably related with the collisional event. 3） The southern sub-belt of the MCZ was possibly related with the closure of back-arc basin. We presumed that the collisional age of southern sub-belt is about Ordovician-Early Silurian according to the ~440Ma extensive metamorphism and the occurrence of coeval post-collisional granite magmatism. 4） The extant structural architecture of the MCZ is related to the multi-phases of intra-continental superimposition, which is characterized by the Mesozoic nappe structure.

辽河盆地西部凹陷深部流体的地球化学特征与成藏效应

The main research area of this thesis is the Western Depression in the Liaohe Basin. Based on the drilling core observation and mud logging data, the features of the mantle–derived fluids and their effects on oil/gas generation in the Western Depression of the Liaohe Basin,was studied with comprehensive methods of volcanic petrology, sediment petrology, fluid geochemistry, sedimentlogy, and structural geology, and use of polarized light microscope, fluorescence microscope, electron microscope, fluid and melt inclusion test, and isotopic test of nature gas etc. The observation of drill cores in study area and other studies reveal that the main passageway of the volcanic eruption in the Cenozoic was the Xibaqian-Gaosheng fault, and the volcanic rocks of each stage were distributed around it. Mantle-derived fluid which affected on oil/gas generation formed later than the volcanic spew and those fluids entered into the depression through the Taian-Dawa fault and the Central fault. The volatile fraction analysis of the melt inclusion reveals the presence of two kinds of mantle fluids; they are hydrogen-rich fluid and carbon dioxide-rich fluid. These the two kinds of fluids were mainly distributed in olivine and pyroxene respectively. The hydrothermal veins development have multiple stages, from high temperature quartz vein to low temperature calcite vein and analcime vein, in which the fluid inclusion extremity component are methane and carbon dioxide, which indicate that when mantle-derived fluids ascended and entered into the basin, most of these fluids interacted with the organic matter in the basin even though some of these entered into atmosphere. The present isotopic test of the nature gas reveals the high 3He/4He value between the region of the Taian-Dawa fault and the Central fault, which also imply the feature of origin in mantle. This phenomenon indicates that the Mesozoic basement faults and the main Cenozoic faults had connected crust and the mantle during the basin evolution, so the mantle derived fluids could enter the basin along those faults. The main source rocks of the ES3 and ES4 members of the Shahejie Formation began to expel hydrocarbon at the end period of the ES1 member of the Shahejie Formation, and reached its peak during the period of the Dongying Formation deposition. During these periods, the mantle derived-fluids entered the basin constantly along the main faults, and supplied lots of hydrogen for hydrocarbon generation. Though the volcanic rocks and the mantle-derived fluids in the Eastern Depression were more developed than in the Western Depression, the source rocks and the deep fluids were not interacted better than the Western Depression because of the affection of structural evolution. In the Eocene, the Eastern Depression did not deposit the ES4 member of the Shahejie Formation, furthermore, the mantle-fluid formed in the Fangshengpao stage escaped to the atmosphere, which confined the later stage hydrocarbon generation capability.

酒泉盆地酒东坳陷下白垩统储层特征及有利勘探方向研究

Jiuquan basin, located in the middle of the Hexizoulang, is one of the major important Mesozoic、cenozoic oil-gas bearing basin in the west of China. Jiuquan basin is composed of Jiuxi depression、Huahai-jinta depression and Jiudong depression. Basement of Jiudong depression is Silurian shallow metamorphic rock. Ying-er sag , focus of this study, is the biggest sag in Jiudong depression and the targeting study object is cretacic strata. Structure evolution and geological background were carefully studied in this research. A series of methods were applied to this research: values of oxygen and carbon isotope and trace elements analysis were used to recover salinity of the palae-lake water of the sag. The evolution and distribution of sedimentary faces were carefully studied. Also, various analysis and tests were made to study the diagenesis of the reservoir sandstones、porosity evolution and porosity distribution. All the studies indicate that sedimentary faces are main macroscopic factor controlling the reservoir quality; Compaction is the main factor destroying reservoir property. Carbonate cements greatly preserved the porosity in eodiagenesis because it had prevented significant early mechanical compaction and its dissolution in the late diagenesis generated secondary pores. Carbonate cements in the late diagenesis occluded primary porosity and played a negative role in the porosity preservation. Source of the carbonate cements were also preliminarily discussed. Feldspar grains and lithic fragments were dissolved by acid fluid and formed a great amount of secondary pores and developed the reservoir quality. Also, sedimentary-diagenesis zones were identified. On basis of these studies, Reservoir forming factors were studied. Keywords: Jiudong depression, sedimentary faces，reservoirs diagenesis reservoir evaluation，secondary pores

山东平度大庄子金矿床地质地球化学特征及成因——兼论层间滑动角砾岩型金矿成矿模式

The author selected the geological and geochemical characteristics and the genesis of the Dazhuangzi gold deposit in the Pingdu City as the central content of the study. The author summarized geological features of the other gold deposits formed within the same geological setting along the margin of the Jiaolai pull-apart basin and compared these gold deposits with the Dazhuangzi gold deposit. On the basis of the first-hand data obtained from field investigation and from mining production reports, ore-controlling structures, geological characteristics and mineralization regularities of the Dazhuangzi gold deposit are studied in detail. According to the analyzing results of petrochemistry, trace element, rare earth element and fluid inclusion etc., the geochemical characteristics, the genesis and the ore-forming material source of the Dazhuangzi gold deposit and that of the other similar gold deposits along the margin of the Jiaolai Basin are proposed. The study results suggest that the Dazhuangzi gold deposit belongs to the typical interstratified glide breccia type gold deposit, which is controlled by the interstratified glide fault structure located along the margin of the Mesozoic pull-apart Jiaolai basin. The interstratified glide fault structure is in the outer part of unconformity belt between the overlying strata and the basement of the pull-apart basin, being along the marble strata of the Jingshan group. The formation of the ore-controlling structure is related closely with the evolution of the Jiaolai Basin in the Mesozoic. The ore-controlling structure underwent the structural stress changes from compressive to tensional and then to compressive stress with strike slipping features sequentially, which were coincided with the regional tectonic stress evolution. The interstratified glide breccia type gold mineralization mainly occurs in the siliceous-marble breccias and cataclastic rocks within the interstratified glide fault structure. The gold minerogenetic epoch is later than 120Ma when the ore-controlling structure was tensioning and strike-slipping. The occurrences of the ore controlling structure and the gold ore bodies are the same as that of the unconformity belt. The geological and geochemical studies show that the source of the ore-forming material is alike with that of the volcanic rocks of the Qingshan formation, which is widespread in the Jiaolai Basin. Both of them came from the deep crust or even the upper mantle. Based on the geological characteristics and the minerogenetic regularities of the Dazhuangzi gold deposit, a genetic model of the deposit is constructed. In addition, the author used the remote sensing image and exploration results of geochemical and geophysical methods to point out several prospecting areas for further exploration. Through comprehensive study on the interstratified glide fault structure and on the interstratified glide breccia type gold deposits along the Jiaolai pull-apart basin, three types of interstratified glide structures and related gold mineralization are set up according to evolution and distribution of main fault as well as related secondary faults in time and space. They are named as Penjiakuang type, Dazhuangzi type and Fayunkuang type. The author summarized up the minerogenetic characteristics and regularities controlled by these three different types of interstratified glide structures respectively, and set up a general minerogenetic model of the interstratified glide breccia type gold deposit.

东海陆架盆地西南部烟囱构造与油气运聚关系研究

In recent years, chimney structure has been proved one of important indicators and a useful guide to major petroleum fields exploration through their exploration history both at home and abroad. Chimney structure, which has been called "gas chimney" or "seismic chimney", is the special fluid-filled fracture swarm, which results from the boiling of active thermal fluid caused by abruptly decreasing of high pressure and high temperature in sedimentary layers of upper lithosphere. Chimney structure is well developed in continental shelf basin of East China Sea, which indicates the great perspectives of petroleum resources there. However, the chimney structure also complicated the petroleum accumulation. So the study of chimney structure on its formation, its effect on occurrence and distribution of petroleum fields is very important not only on theoretical, but also on its applied research. It is for the first time to make a clear definition of chimney structure in this paper, and the existence and practical meaning of chimney structure are illustrated. Firstly, on the viewpoint of exploration, this will amplify exploration area or field, not only in marine, but also on continent. Secondly, this is very important to step-by-step exploration and development of petroleum fields with overpressure. Thirdly, this will provide reference for the study on complex petroleum system with multi-sources, commingled sources and accumulation, multi-stage accumulations, and multi-suits petroleum system in the overlay basin. Fourthly, when the thermal fluid enters the oceanic shallow layer, it can help form gas hydrate under favorable low-temperature and high-pressure conditions. Meanwhile, the thermal fluid with its particular component and thermal content will affect the physical, chemical and ecological environments, which will help solving the problem of global resources and environment. Beginning from the regional tectonic evolution characteristics, this paper discussed the tectonic evolution history of the Taibei depression, then made an dynamical analysis of the tectonic-sedimentary evolution during the Mesozoic and Cenozoic for the East China Sea basin. A numerical model of the tectonic-thermal evolution of the basin via the Basin-Mod technique was carried out and the subsidence-buried history and thermal history of the Taibei depression were inverse calculated: it had undergone a early rapid rift and sag, then three times of uplift and erosion, and finally depressed and been buried. The Taibei depression contains a huge thick clastic sedimentary rock of marine facies, transitional facies and continental facies on the complex basement of ante-Jurassic. It is a part of the back-arc rifting basins occurred during the Mesozoic and Cenozoic. The author analyzed the diagenesis and thermal fluid evolution of this area via the observation of cathodoluminescence, scanning electron microscope and thin section, taking advantage of the evidences of magma activities, paleo-geothermics and structural movement, the author concluded that there were at least three tectonic-thermal events and three epochs of thermal-fluid activities; and the three epochs of thermal-fluid activities were directly relative to the first two tectonic-thermal events and were controlled by the generation and expulsion of hydrocarbon in the source rock simultaneously. Based on these, this paper established the corresponding model between the tectonic-thermal events and the thermal-fluid evolution of the Taibei Depression, which becomes the base for the study on the chimney structures. According to the analyses of the gas-isotope, LAM spectrum component of fluid inclusion, geneses of CO_2 components and geneses of hydrocarbon gases, the author preliminarily verified four sources of the thermal fluid in the Taibei Depression: ① dehydration of mud shale compaction, ② expulsion of hydrocarbon in the source rock; ③ CO_2 gas hydro-thermal decomposition of carbonatite; ④magma-derived thermal fluid including the mantle magma water and volatile components (such as H_2O, CO_2, H_2S, SO_2, N_2 and He etc.). On the basis of the vitrinite reflectance (Ro), homogenization temperature of fluid inclusion, interval transit time of major well-logging, mud density of the wells, measured pressure data and the results of previous studies, this paper analyzed the characteristics of the geothermal fields and geo-pressure fields for the various parts in this area, and discussed the transversal distribution of fluid pressure. The Taibei depression on the whole underwent a temperature-loss process from hot basin to cold basin; and locally high thermal anomalies occurred on the regional background of moderate thermal structure. The seal was primarily formed during the middle and late Paleocene. The overpressured system was formed during the middle and late Eocene. The formation of overpressured system in Lishui Sag underwent such an evolutionary process as "form-weaken-strengthen-weaken". Namely, it was formed during the middle and late Eocene, then was weakened in the Oligocene, even partly broken, then strengthened after the Miocene, and finally weakened. The existence of the thermal fluid rich in volatile gas is a physical foundation for the boiling of the fluid, and sharply pressure depletion was the major cause for the boiling of the fluid, which suggests that there exists the condition for thermal fluid to boil. According to the results of the photoelastic simulation and similarity physical experiments, the geological condition and the formation mechanism of chimnestructures are summarized: well compartment is the prerequisite for chimney formation; the boiling of active thermal fluid is the original physical condition for chimney formation; The local place with low stress by tension fault is easy for chimney formation; The way that thermal fluid migrates is one of the important factors which control the types of chimney structures. Based on where the thermal fluid come from and geometrical characteristics of the chimney structures, this paper classified the genetic types of chimney structures, and concluded that there existed three types and six subtypes chimney structures: organic chimney structures generated by the hydrocarbon-bearing thermal fluid in middle-shallow layers, inorganic and commingling-genetic chimney structures generated by thermal fluid in middle-deep layers. According to the seismic profiles interpretations, well logging response analysis and mineralogical and petrological characteristics in the study area, the author summarized the comprehensive identification marks for chimney structures. Especially the horizon velocity analysis method that is established in this paper and takes advantage of interval velocity anomaly is a semi-quantitative and reliable method of chimney structure s identification. It was pointed out in this paper that the occurrence of the chimney structures in the Taibei depression made the mechanism of accumulation complicated. The author provided proof of episodic accumulation of hydrocarbon in this area: The organic component in the boiling inclusion is the trail of petroleum migration, showing the causality between the boiling of thermal fluid and the chimney structures, meanwhile showing the paroxysmal accumulation is an important petroleum accumulation model. Based on the evolutionary characteristics of various types of chimney structures, this paper discussed their relationships with the migration-accumulation of petroleum respectively. At the same time, the author summarized the accumulating-dynamical models associated with chimney structures. The author analyzed such accumulation mechanisms as the facies state, direction, power of petroleum migration, the conditions of trap, the accumulation, leakage and reservation of petroleum, and the distribution rule of petroleum. The author also provides explanation for such practical problems the existence of a lot of mantle-derived CO_2, and its heterogeneous distribution on plane. By study on and recognition for chimney structure, the existence and distribution of much mantle-derived CO_2 found in this area are explained. Caused by tectonic thermal activities, the deep magma with much CO_2-bearing thermal fluid migrate upward along deep fault and chimney structures, which makes two wells within relatively short distance different gas composition, such as in well LF-1 and well LS36-1-1. Meanwhile, the author predicted the distribution of petroleum accumulation belt in middle-shallow layer for this area, pointed out the three favorable exploration areas in future, and provided the scientific and deciding references for future study on the commingling-genetic accumulation of petroleum in middle-deep layer and the new energy-gas hydrate.

下扬子北缘前陆盆地形成演化与油气赋存条件

The foreland basin on the northern margin of the lower reach of the Yangtze river (the lower Yangtze foreland basin) is tectonically situated in the basin-mountain transitional area along the southeastern flank of the Dabie mountains. The early formation and development of the basin is closely related to the open-up of the Mian-Lue paleo-oceanic basin on the southern margin of the Central Orogenic System represented by Qinling-Dabei orogenic belt, while the tectonic evolution of the middle-late stage of the basin is mainly related to development of the Mian-Lue tectonic zone that occurred on the basis of the previous Mian-Lue paleo-suture. The foreland basin of the northern rim of the lower reach of the Yangtze river was formed during the middle-Triassic collision between the Yangtze and North China plates and experienced an evolution of occuirence-development-extinction characterized by marine facies to continental facies and continental margin to intracontinent in terms of tectonic setting.The foreland basin (T2-J2) was developed on the basis of the passive continental marginal basin on the south side of the Mian-Lue paleo-ocean and superimposed by late Jurassic-Tertiary fault basin. The tectonic setting underwent a multiple transformation of rifting-collisional clososing-tensional faulting and depression, which resulted in changes of the property for the basin and the final formation of the superposed compose basin in a fashion of 3-story-building. According to the tectonic position and evolution stages of plate collision happening on the southeastern margin of the Dabie mountains, and tectono-tratigraphic features shown by the foreland basin in its main formational period, the evolution of the foreland basin can be divided into four stages: 1) pre-orogenic passive margin (P2-Ti). As the Mian-Lue ocean commenced subduction in the late-Permian, the approaching of the Yangtze and North China plates to each other led to long-periodical and large-scale marine regression in early Triassic which was 22 Ma earlier than the global one and generated I-type mixed strata of the clastic rocks and carbonate, and I-type carbonate platform. These represent the passive stratigraphy formed before formation of the foreland basin. 2) Foreland basin on continental margin during main orogenic episode (T2.3). The stage includes the sub-stage of marine foreland basin (T2X remain basin), which formed I-type stratigrphy of carbonate tidal flat-lagoon, the sub-stage of marine-continental transition-molasse showing II-type stratigraphy of marine-continental facies lake - continental facies lake. 3) Intracontinental foreland basin during intracontinental orogeny (Ji-2)- It is characterized by continental facies coal-bearing molasses. 4) Tensional fault and depression during post-orogeny (J3-E). It formed tectono-stratigraphy post formation of the foreland basin, marking the end of the foreland evolution. Fold-thrust deformation of the lower Yangtze foreland basin mainly happened in late middle-Jurassic, forming ramp structures along the Yangtze river that display thrusting, with deformation strength weakening toward the river from both the Dabie mountains and the Jiangnan rise. This exhibits as three zones in a pattern of thick-skinned structure involved the basement of the orogenic belt to decollement thin-skinned structure of fold-thrust from north to south: thrust zone of foreland basin on northern rim of the lower reach of the Yangtze river, foreland basin zone and Jiannan compose uplift zone. Due to the superposed tensional deformation on the earlier compressional deformation, the structural geometric stratification has occurred vertically: the upper part exhibits late tensional deformation, the middle portion is characterized by ramp fault -fold deformation on the base of the Silurian decollement and weak deformation in the lower portion consisting of Silurian and Neo-Proterozoic separated by the two decollements. These portions constitutes a three-layered structural assemblage in a 3-D geometric model.From the succession of the lower reach of the Yangtze river and combined with characteristics of hydrocarbon-bearing rocks and oil-gas system, it can be seen that the succession of the continental facies foreland basin overlies the marine facies stratigraphy on the passive continental margin, which formed upper continental facies and lower marine facies hydrocarbon-bearing rock system and oil-gas forming system possessing the basic conditions for oil-gas occurrence. Among the conditions, the key for oil-gas accumulation is development and preservation of the marine hydrocarbon-bearing rocks underlying the foreland basin. The synthetic study that in the lower Yangtze foreland basin (including the Wangjiang-Qianshan basin), the generation-reservoir-cover association with the Permian marine facies hydrocarbon-bearing rocks as the critical portion can be a prospective oil-gas accumulation.Therefore, it should aim at the upper Paleozoic marine hydrocarbon-bearing rock system and oil-gas forming system in oil-gas evaluation and exploration. Also, fining excellent reservoir phase and well-preserved oil-gas accumulation units is extremely important for a breakthrough in oil-gas exploration.