Constraints on the carbon cycle and climate during the early evolution of animals

One of the greatest challenges in science lies in disentangling causality in complex, coupled systems. This is illustrated no better than in the dynamic interplay between the Earth and life. The early evolution and diversification of animals occurred within a backdrop of global change, yet reconstructing the potential role of the environment in this evolutionary transition is challenging. In the 200 million years from the end-Cryogenian to the Ordovician, enigmatic Ediacaran fauna explored body plans, animals diversified and began to biomineralize, forever changing the ocean's chemical cycles, and the biological community in shallow marine ecosystems transitioned from a microbial one to an animal one.

In the following dissertation, a multi-faceted approach combining macro- and micro-scale analyses is presented that draws on the sedimentology, geochemistry and paleontology of the rocks that span this transition to better constrain the potential environmental changes during this interval.

In Chapter 1, the potential of clumped isotope thermometry in deep time is explored by assessing the importance of burial and diagenesis on the thermometer. Eocene- to Precambrian-aged carbonates from the Sultanate of Oman were analyzed from current burial depths of 350-5850 meters. Two end-member styles of diagenesis independent of burial depth were observed.

Chapters 2, 3 and 4 explore the fallibility of the Ediacaran carbon isotope record and aspects of the sedimentology and geochemistry of the rocks preserving the largest negative carbon isotope excursion on record---the Shuram Excursion. Chapter 2 documents the importance of temperature, fluid composition and mineralogy on the delta 18-O min record and interrogates the bulk trace metal signal. Chapter 3 explores the spatial variability in delta 13-C recorded in the transgressive Johnnie Oolite and finds a north-to-south trend recording the onset of the excursion. Chapter 4 investigates the nature of seafloor precipitation during this excursion and more broadly. We document the potential importance of microbial respiratory reactions on the carbonate chemistry of the sediment-water interface through time.

Chapter 5 investigates the latest Precambrian sedimentary record in carbonates from the Sultanate of Oman, including how delta 13-C and delta 34-S CAS vary across depositional and depth gradients. A new model for the correlation of the Buah and Ara formations across Oman is presented. Isotopic results indicate delta 13-C varies with relative eustatic change and delta 34-S CAS may vary in absolute magnitude across Oman.

Chapter 6 investigates the secular rise in delta 18-Omin in the early Paleozoic by using clumped isotope geochemistry on calcitic and phosphatic fossils from the Cambrian and Ordovician. Results do not indicate extreme delta 18-O seawater depletion and instead suggest warmer equatorial temperatures across the early Paleozoic.

Aseismic deformation in subduction megathrusts : central Andes and north-east Japan

We aim to characterize fault slip behavior during all stages of the seismic cycle in subduction megathrust environments with the eventual goal of understanding temporal and spatial variations of fault zone rheology, and to infer possible causal relationships between inter-, co- and post-seismic slip, as well as implications for earthquake and tsunami hazard. In particular we focus on analyzing aseismic deformation occurring during inter-seismic and post-seismic periods of the seismic cycle. We approach the problem using both Bayesian and optimization techniques. The Bayesian approach allows us to completely characterize the model parameter space by searching a posteriori estimates of the range of allowable models, to easily implement any kind of physically plausible a priori information and to perform the inversion without regularization other than that imposed by the parameterization of the model. However, the Bayesian approach computational expensive and not currently viable for quick response scenarios. Therefore, we also pursue improvements in the optimization inference scheme. We present a novel, robust and yet simple regularization technique that allows us to infer robust and somewhat more detailed models of slip on faults. We apply such methodologies, using simple quasi-static elastic models, to perform studies of inter- seismic deformation in the Central Andes subduction zone, and post-seismic deformation induced by the occurrence of the 2011 Mw 9.0 Tohoku-Oki earthquake in Japan. For the Central Andes, we present estimates of apparent coupling probability of the subduction interface and analyze its relationship to past earthquakes in the region. For Japan, we infer high spatial variability in material properties of the megathrust offshore Tohoku. We discuss the potential for a large earthquake just south of the Tohoku-Oki earthquake where our inferences suggest dominantly aseismic behavior.