Asphalt rubber mixtures with warm mix asphalt additives

En los últimos años, debido a la creciente preocupación por el calentamiento global y el cambio climático, uno de los retos más importantes a los que se enfrenta nuestra sociedad es el uso eficiente y económico de energía así como la necesidad correspondiente de reducir los gases de efecto invernadero (GEI). Las tecnologías de mezclas semicalientes se han convertido en un nuevo e importante tema de investigación en el campo de los materiales para pavimentos ya que ofrece una solución potencial para la reducción del consumo energético y las emisiones de GEI durante la producción y puesta en obra de las mezclas bituminosas. Por otro lado, los pavimentos que contienen polvo de caucho procedente de neumático fuera de uso, al hacer uso productos de desecho, ahorran energía y recursos naturales. Estos pavimentos ofrecen una resistencia mejorada a la formación de roderas, a la fatiga y a la fisuración térmica, reducen los costes de mantenimiento y el ruido del tráfico así como prolongan la vida útil del pavimento. Sin embargo, estas mezclas presentan un importante inconveniente: la temperatura de fabricación se debe aumentar en comparación con las mezclas asfálticas convencionales, ya que la incorporación de caucho aumenta la viscosidad del ligante y, por lo tanto, se producen mayores cantidades de emisiones de GEI. En la presente Tesis, la tecnología de mezclas semicalientes con aditivos orgánicos (Sasobit, Asphaltan A, Asphaltan B, Licomont) se incorporó a la de betunes de alta viscosidad modificados con caucho (15% y 20% de caucho) con la finalidad de dar una solución a los inconvenientes de mezclas con caucho gracias a la utilización de aditivos reductores de la viscosidad. Para este fin, se estudió si sería posible obtener una producción más sostenible de mezclas con betunes de alto contenido en caucho sin afectar significativamente su nivel de rendimiento mecánico. La metodología aplicada para evaluar y comparar las características de las mezclas consistió en la realización de una serie de ensayos de laboratorio para betunes y mezclas con caucho y con aditivos de mezclas semicalientes y de un análisis del ciclo de vida híbrido de la producción de mezclas semicalientes teniendo en cuenta la papel del aditivo en la cadena de suministro con el fin de cuantificar con precisión los beneficios de esta tecnología. Los resultados del estudio indicaron que la incorporación de los aditivos permite reducir la viscosidad de los ligantes y, en consecuencia, las temperaturas de producción y de compactación de las mezclas. Por otro lado, aunque la adición de caucho mejoró significativamente el comportamiento mecánico de los ligantes a baja temperatura reduciendo la susceptibilidad al fenómeno de fisuración térmica, la adición de las ceras aumentó ligeramente la rigidez. Los resultados del estudio reológico mostraron que la adición de porcentajes crecientes de caucho mejoraban la resistencia del pavimento con respecto a la resistencia a la deformación permanente a altas temperaturas y a la fisuración térmica a bajas temperaturas. Además, se observó que los aditivos mejoran la resistencia a roderas y la elasticidad del pavimento al aumentar el módulo complejo a altas temperaturas y al disminuir del ángulo de fase. Por otra parte, el estudio reológico confirmó que los aditivos estudiados aumentan ligeramente la rigidez a bajas temperaturas. Los ensayos de fluencia llevados a cabo con el reómetro demostraron una vez más la mejora en la elasticidad y en la resistencia a la deformación permanente dada por la adición de las ceras. El estudio de mezclas con caucho y aditivos de mezclas semicalientes llevado a cabo demostró que las temperaturas de producción/compactación se pueden disminuir, que las mezclas no experimentarían escurrimiento, que los aditivos no cambian significativamente la resistencia conservada y que cumplen la sensibilidad al agua exigida. Además, los aditivos aumentaron el módulo de rigidez en algunos casos y mejoraron significativamente la resistencia a la deformación permanente. Asimismo, a excepción de uno de los aditivos, las mezclas con ceras tenían la misma o mayor resistencia a la fatiga en comparación con la mezcla control. Los resultados del análisis de ciclo de vida híbrido mostraron que la tecnología de mezclas semicalientes es capaz de ahorrar significativamente energía y reducir las emisiones de GEI, hasta un 18% y 20% respectivamente, en comparación con las mezclas de control. Sin embargo, en algunos de los casos estudiados, debido a la presencia de la cera, la temperatura de fabricación debe reducirse en un promedio de 8 ºC antes de que los beneficios de la reducción de emisiones y el consumo de combustible puedan ser obtenidos. Los principales sectores contribuyentes a los impactos ambientales generados en la fabricación de mezclas semicalientes fueron el sector de los combustibles, el de la minería y el de la construcción. Due to growing concerns over global warming and climate change in recent years, one of the most important challenges facing our society is the efficient and economic use of energy, and with it, the corresponding need to reduce greenhouse gas (GHG) emissions. The Warm Mix Asphalt (WMA) technology has become an important new research topic in the field of pavement materials as it offers a potential solution for the reduction of energy consumption and GHG emissions during the production and placement of asphalt mixtures. On the other hand, pavements containing crumb-rubber modified (CRM) binders save energy and natural resources by making use of waste products. These pavements offer an improved resistance to rutting, fatigue and thermal cracking; reduce traffic noise and maintenance costs and prolong pavement life. These mixtures, however, present one major drawback: the manufacturing temperature is higher compared to conventional asphalt mixtures as the rubber lends greater viscosity to the binder and, therefore, larger amounts of GHG emissions are produced. In this dissertation the WMA technology with organic additives (Sasobit, Asphaltan A, Asphaltan B and Licomont) was applied to CRM binders (15% and 20% of rubber) in order to offer a solution to the drawbacks of asphalt rubber (AR) mixtures thanks to the use of fluidifying additives. For this purpose, this study sought to determine if a more sustainable production of AR mixtures could be obtained without significantly affecting their level of mechanical performance. The methodology applied in order to evaluate and compare the performance of the mixtures consisted of carrying out several laboratory tests for the CRM binders and AR mixtures with WMA additives (AR-WMA mixtures) and a hybrid input-output-based life cycle assessment (hLCA) of the production of WMA. The results of the study indicated that the incorporation of the organic additives were able to reduce the viscosity of the binders and, consequently, the production and compaction temperatures. On the other hand, although the addition of rubber significantly improved the mechanical behaviour of the binders at low temperatures reducing the susceptibility to thermal cracking phenomena, the addition of the waxes slightly increased the stiffness. Master curves showed that the addition of increasing percentages of rubber improved the resistance of the pavement regarding both resistance to permanent deformation at high temperatures and thermal cracking at low temperatures. In addition, the waxes improved the rutting resistance and the elasticity as they increased the complex modulus at high temperatures and decreased the phase angle. Moreover, master curves also attest that the WMA additives studied increase the stiffness at low temperatures. The creep tests carried out proved once again the improvement in the elasticity and in the resistance to permanent deformation given by the addition of the waxes. The AR-WMA mixtures studied have shown that the production/compaction temperatures can be decreased, that the mixtures would not experience binder drainage, that the additives did not significantly change the retained resistance and fulfilled the water sensitivity required. Furthermore, the additives increased the stiffness modulus in some cases and significantly improved the permanent deformation resistance. Except for one of the additives, the waxes had the same or higher fatigue resistance compared to the control mixture. The results of the hLCA demonstrated that the WMA technology is able to significantly save energy and reduce GHG emissions, up to 18% and 20%, respectively, compared to the control mixtures. However, in some of the case studies, due to the presence of wax, the manufacturing temperature at the asphalt plant must be reduced by an average of 8ºC before the benefits of reduced emissions and fuel usage can be obtained. The results regarding the overall impacts generated using a detailed production layer decomposition indicated that fuel, mining and construction sectors are the main contributors to the environmental impacts of manufacturing WMA mixtures.

Study of the effect of four warm mix asphalt additives on bitumen modified with 15% crumb rubber

Due to a growing concern over global warming, the bituminous mixture industry is making a constant effort to diminish its emissions by reducing manufacturing and installation temperatures without compromising the mechanical properties of the bituminous mixtures. The use of mixtures with tyre rubber has demonstrated that these mixtures can be economical and ecological and that they improve the behaviour of the pavements. However, bituminous mixtures with a high rubber content present one major drawback: they require higher mixing and installation temperatures due to the elevated viscosity caused by the high rubber content and thus they produce larger amounts of greenhouse gas emissions than conventional bituminous mixtures. This article presents a study of the effect of four viscosity-reducing additives (Sasobit®, Asphaltan A®, Asphaltan B® and Licomont BS 100®) on a bitumen modified with 15% rubber. The results of this study indicate that these additives successfully reduce viscosity, increase the softening temperature and reduce penetration. However, they do not have a clear effect on the test for elastic recovery and ductility at 25 °C.

Permanent deformation estimates of dynamic equipment foundations: Application to a gas turbine in granular soils

Permanent displacements of a gas turbine founded on a fine, poorly graded, and medium density sand are studied. The amplitudes and modes of vibration are computed using Barkan´s formulation, and the “High-Cycle Accumulation” (HCA) model is employed to account for accumulated deformations due to the high number of cycles. The methodology is simple: it can be easily incorporated into standard mathematical software, and HCA model parameters can be estimated based on granulometry and index properties. Special attention is devoted to ‘transient’ situations at equipment´s start-up, during which a range of frequencies – including frequencies that could be similar to the natural frequencies of the ground – is traversed. Results show that such transient situations could be more restrictive than stationary situations corresponding to normal operation. Therefore, checking the stationary situation only might not be enough, and studying the influence of transient situations on computed permanent displacements is needed to produce a proper foundation design

Impact parameters in relation to bruising and other fruit properties.

Impact response in fruits, primarily appl.es and pears (Pomaceae fruits), has been studied during the last five years. Using a laboratory impact testing device and also free-fall tests of instrumented apples, a significant body of results has been established, relative to the parameters which best characterize the impact response of these materials, and to their correlation with bruise damage, variety and ripeness level of the fruits. Bruise damage, measured as the size and/or volume of the affected fruit tissue is related primarily to applied energy (i.e. mainly drop height) for a given variety at a given ripeness stage. The relevant impact response parameters are maximum deformation (DM), permanent deformation (DP), maximum impulse (IM), maximum impact force (FM), maximum value of the force/time slope during impact (F/T) and impact time (T). The effect of ripeness differences was also studied in selected varieties of pears, being the most relevant parameters: maximum force (FM) and F/T slope.

Validación del método de predicción de direcciones principales de drenaje subterráneo en macizos anisótropos, en los terrenos volcánicos del macizo de Anaga, Tenerife

Actualmente y desde hace ya más de 25 años, el Método de “Predicción de las Direcciones Principales de Drenaje Subterráneo en Macizos Anisótropos”, ha sido utilizado con éxito en diferentes terrenos Kársticos como: calizas, yesos, cuarcitas, pizarras, granitos y criokarst (karst en el hielo glaciar). Sin embargo hasta ahora, nunca se había validado en terrenos volcánicos donde está focalizada esta tesis que lleva por título, Validación de dicho Método en los Terrenos Volcánicos del Macizo de Anaga en Tenerife. Este Método matemático consiste esencialmente en “Predecir y Cuantificar” las direcciones principales de drenaje turbulento subterráneo en macizos anisótropos. Para ello se basa en el estudio realizado en campo de los tectoglifos o deformaciones permanentes del macizo, impresas éstas en la roca, como consecuencia de los esfuerzos tectónicos a los que ha estado sometido dicho macizo. Se consigue de esta manera cubrir el vacío para macizos anisótropos que existe con el modelo matemático de flujo subterráneo laminar (macizos isótropos) definido por Darcy (1856). Para validar el Método se ha elegido el macizo de Anaga, pues es la zona de mayor anisotropía existente en la isla de Tenerife, conformada por una gran y extensa red de diques de diversas formas y tamaños que pertenecen a la familia de diques del eje estructural NE de la isla. En dicho macizo se realizó un exhaustivo trabajo de campo con la toma 331 datos (diques basálticos) y se aplicó el Método, consiguiendo definir las direcciones preferentes de drenaje subterráneo en el macizo de Anaga. Esta predicción obtenida se contrastó con la realidad del drenaje en la zona, conocida gracias a la existencia de cinco galerías ubicadas en la zona trabajo, de las cuales se tiene información sobre sus alumbramientos. En todos los casos se demuestra la bondad de la predicción obtenida con el Método. Queda demostrado que a mayor caos geológico o geotectónico, se ha conseguido mejor predicción del Método, obteniéndose resultados muy satisfactorios para aquellas galerías de agua en las que su rumbo de avance fue coincidente con la dirección perpendicular a la obtenida con la predicción dada por el Método, como dirección preferente de drenaje en la zona en la que se encuentra ubicada cada galería. No cabe duda que la validación de Método en los terrenos volcánicos de Tenerife, supondrá un cambio considerable en el mundo de la hidrogeología en este tipo de terrenos. Es la única herramienta matemática que se dispone para predecir un rumbo acertado en el avance de la perforación de las galerías de aguas, lo que conlleva al mismo tiempo un ahorro importantísimo en la ejecución de las obras. Por otro lado, el Método deja un importante legado a la sociedad canaria, pues con él se abren numerosas vías de trabajo e investigación que generarán un importante desarrollo en el mundo de la hidrogeología volcánica. ABSTRACT Currently and for over 25 years now, the Method of "Prediction of Subsurface Drainage Main Directions in Anisotropic Massifs" has been successfully used in various karstic terrains such as: limestone, gypsum, quartzite, slate, granite and criokarst (karst in the glacier ice). However, until now, it had never been validated in volcanic terrains where is focused this thesis entitled Validation of such Method in the Anaga Massif Volcanic Terrains, in Tenerife. This mathematical method is essentially "predict and quantify" the main directions of groundwater turbulent drainage in anisotropic massifs. This is based on field study of tectoglifes or permanent deformation of the massif, printed on the rocks as a result of previous tectonic stresses. Therefore it is possible to use in anisotropic rock mathematical model instead of the isotropic laminar flow mathematical models defined by Darcy (1856). The Anaga Massif have been chosen to validate the method, because it presents the greatest anisotropy in Tenerife Island, shaped by a large and extensive network of dikes of various shapes and sizes that belong to the family of NE structural axis dikes of the island. An exhaustive field work was carried out in such massif, with 331 collected data (basaltic dikes) and the method was applied, in order to define the preferred direction of the underground drainage in the Anaga massif. This obtained prediction was contrasted to the reality of the drainage in the area, known thanks to the existence of five galleries located in the work area, from which information about their springs was available. In all cases it was possible to demonstrate the fitness of the prediction obtained by the method. It had been demonstrated that a greater geological or geotectonic chaos enhances a better prediction of the method, that predicted very satisfactory results for those water galleries which directions were perpendicular to that predicted by the Method as a drainage preferential direction, for the zone where was located each gallery. No doubt that the validation of the use of the Method in the volcanic terrain of Tenerife, means a considerable change in the world of hydrogeology in this type of terrain. It is the only mathematical tool available to predict a successful drilling direction in advancing water galleries, what also leads to major savings in execution of the drilling works. Furthermore, the method leaves an important legacy to the Canary Islands society, because it opens many lines of work and research to generate a significant development in the world of volcanic hydrogeology.

Sistema portátil de medida de dispositivos sometidos a ensayos en campo

El proyecto fin de carrera “Sistema Portátil de Medida de Dispositivos Sometidos a Ensayos en Campo” es un proyecto acometido para el desarrollo y evaluación de un sistema de medición portátil y confiable, que permita la realización de mediciones de curvas I-V en campo, en condiciones reales de funcionamiento. Dado que la finalidad de este proyecto fin de carrera es la obtención de un sistema para la realización de mediciones en campo, en la implementación del proyecto se tendrán como requisitos principales de diseño el tamaño, la fuente de alimentación, el peso del sistema, además de la fiabilidad y una relativa precisión en la realización de mediciones. Durante la realización de este proyecto y dados los requerimientos anteriores de portabilidad y fiabilidad, se ha buscado ofrecer una solución de compromiso diseñando un equipamiento que sea realizable, que cumpla con los objetivos anteriores con un coste que no sea elevado y con la característica de que disponga de una facilidad de manejo que permita a cualquier usuario la utilización del mismo. El sistema final diseñado está basado en el dispositivo de adquisición de datos MyDAQ de National Instruments que permite la realización de múltiples tipos de mediciones. En base a este dispositivo de adquisición de datos, se ha diseñado un sistema de medición con una arquitectura que se implementa a través de un ordenador portátil, con un software de medición instalado que recopila e interpreta los datos, y que alimenta y controla al dispositivo a través del puerto USB. El sistema también implementa una carga variable que permite la medición de la curva I-V en iluminación de células o mini-paneles fotovoltaicos. Este diseño permite que para la realización de las mediciones de las curvas I-V en iluminación en campo sólo se requiera conectar el dispositivo de adquisición a un PC portátil con batería y a la carga variable. Aunque este diseño es específico para la medición de células solares se ha implementado de forma que pueda extrapolarse fácilmente a otro tipo de medición de tensión y corriente. Para la comprobación de la precisión del sistema portátil de medidas, durante el proyecto se ha procedido a la comparación de los resultados obtenidos del sistema diseñado con un equipo de caracterización en laboratorio. Dicho sistema de alta exactitud permite cuantificar la degradación real de la célula y establecer una comparación de mediciones con el sistema portátil de medida, ofreciendo resultados satisfactorios en todas las mediciones realizadas y permitiendo concluir la evaluación del sistema portátil como apto para las mediciones de dispositivos en campo. El proceso de evaluación del equipamiento diseñado consistiría en la medida de la curva I-V en laboratorio de un dispositivo fotovoltaico con instrumentación de alta precisión y condiciones controladas de luz y temperatura de un dispositivo, célula o mini-panel. Tras la medida inicial las células se instalarían en campo y se realizaría una caracterización periódica de los dispositivos mediante el sistema portátil de medida, que permitiría evidenciar si en la curva I-V bajo iluminación existe degradación, y en qué zona de la curva. Al finalizar el ensayo o en periodos intermedios se desmontarían los dispositivos para volver a medir la curva I-V con exactitud en laboratorio. Por tanto el sistema portátil de medida, debe permitir evaluar la evolución de la curva I-V en condiciones ambientales similares a obtenidas en medidas anteriores, y a partir de la misma determinar el modo de degradación del dispositivo, no siendo necesaria una elevada precisión de medida para ofrecer resultados exactos de degradación, que sólo podrán medirse en el laboratorio. ABSTRACT. The final degree project "Portable Measurement System For Devices Under Field Tests" is a project undertaken for the development and evaluation of portable and reliable measurement equipment, which allows the realization of I-V curve measurements in field conditions actual operation. Since the purpose of this final project is to obtain a system for conducting field measurements in the implementation of the project will have as main design requirements for size, power supply, system weight, plus reliability and precision relative to the taking of measurements. During the development of this project and given the above requirements portability and reliability, has sought to offer a compromise designing equipment that is achievable, that meets the above objectives with a cost that is not high and the feature that available management facility that allows any user to use it. The final system is designed based on the acquisition device MyDAQ NI data that allows the execution of multiple types of measurements. Based on this data acquisition device, we have designed a measurement system with an architecture that is implemented via a laptop, with measurement software installed that collects and interprets data, and feeds and controls the device through the USB port. The system also implements a variable load which allows measurement of the I-V curve lighting photovoltaic cells. This design allows performing measurements of I-V curves in lighting field is only required to connect the device to purchase a laptop with a battery and variable load. Although this design is specific for the measurement of solar cells has been implemented so that it can easily be extrapolated to other types of measuring voltage and current. To test the accuracy of the portable measurement system during the project has been carried out to compare the results of the designed system, a team of laboratory characterization. This system of high accuracy to quantify the actual degradation of the cell and a comparison of measurements with portable measurement system, providing satisfactory results in all measurements and allowing complete portable system assessment as suitable for measurements of devices field. The evaluation process designed equipment would be far laboratory I-V curve of a photovoltaic device with high precision instrumentation controlled light and temperature of a device, panel or mini-cell conditions. After initial measurement cells settle in a periodic field and device characterization will be achieved through the portable measurement system, which would show whether the I-V curve under illumination degradation exists, and in which area of the curve. At the end of the trial or in interim periods devices to remeasure the I-V curve accurately in laboratory dismount. Therefore the portable measurement system should allow evaluating the evolution of the I-V curve similar to previous measurements obtained in ambient conditions, and from it determine the mode of degradation of the device, not a high measurement accuracy to be necessary to provide degradation accurate results, which can only be measured in the laboratory.

Optical characterisation of semi-transparent PV modules for building integration

A complete characterisation of PV modules for building integration is needed in order to know their influence on the building’s global energy balance. Specifically, certain characteristic parameters should be obtained for each different PV module suitable for building integrated photovoltaics (BIPV), some by direct or indirect measurements at the laboratory, and others by monitoring the element performance mounted in real operating conditions. In the case of transparent building envelopes it is particularly important to perform an optical and thermal characterization of the PV modules that would be integrated in them. This paper addresses the optical characterization of some commercial thin-film PV modules having different degrees of transparency, suitable for building integration in façades. The approach is based on the measurement of the spectral UV/Vis/NIR reflectance and transmittance of the different considered samples, both at normal incidence and as a function of the angle of incidence. With the obtained results, the total and zoned UV, visible and NIR transmission and reflection values are calculated, enabling the correct characterization of the PV modules integrated in façades and the subsequent evaluation of their impact over the electrical, thermal and lighting performance in a building.

Influencia de la temperatura en la deflexión de firmes flexibles

En esta investigación se ha estudiado el efecto de la variación de la temperatura en la deflexión de firmes flexibles. En primer lugar se han recopilado los criterios existentes de ajuste de la deflexión por efecto de la temperatura. Posteriormente, se ha llevado a cabo un estudio empírico mediante la auscultación de las deflexiones en cinco tramos de carretera con firme flexible y con diferentes espesores de mezclas bituminosas (entre 10 y 30 cm). Las medidas se han efectuado en dos campañas (verano e invierno), tratando de abarcar un amplio rango de temperaturas. En cada campaña, se han llevado a cabo distintas auscultaciones a diferentes temperaturas. Las medidas de cada campaña se han realizado el mismo día. Se han obtenido los coeficientes empíricos de ajuste por temperatura para cada tramo analizado. Además, se ha realizado un estudio teórico mediante la elaboración de diferentes modelos (multicapa elástico lineal, multicapa visco-elástico lineal y elementos finitos) que reproducen la respuesta estructural de los firmes flexibles auscultados. La caracterización mecánica de las mezclas bituminosas se ha realizado mediante ensayos de módulo complejo en laboratorio, a diferentes temperaturas y frecuencias, sobre testigos extraídos en las carreteras estudiadas. Se han calculado los coeficientes teóricos de ajuste por temperatura para cada modelo elaborado y tramo analizado. Finalmente, se ha realizado un estudio comparativo entre los distintos coeficientes de ajuste (existentes, empíricos y teóricos), que ha puesto de manifiesto que, en todos los casos analizados, los coeficientes obtenidos en el modelo de elementos finitos son los que más se aproximan a los coeficientes empíricos (valor de referencia para los tramos analizados). El modelo desarrollado de elementos finitos permite reproducir el comportamiento visco-elástico de las mezclas bituminosas y el carácter dinámico de las cargas aplicadas. Se han utilizado elementos tipo tetraedro isoparamétrico lineal (C3D8R) para el firme y la parte superior del cimiento, mientras que para la parte inferior se han empleado elementos infinitos (CIN3D8). In this research the effect produced by the temperature change on flexible pavements deflection is analysed. First, the existing criteria of deflection adjustment by temperature were collected. Additionally, an empirical analysis was carried out, consisting on deflection tests in five flexible-pavement road sections with different asphalt mix thickness (from 10 to 30 cm). The measures were taken in two seasons (summer and winter) in an effort to register a wide range of temperatures. Different surveys were carried out at different temperatures in each season. The tests of each season were done at the same day. The empirical temperature adjustment factors for every analysed section were obtained. A theoretical study was carried out by developing different models (linear elastic multilayer, linear visco-elastic multilayer and finite elements) that reproduce the structural response of the tested flexible pavements. The mechanical characterization of the asphalt mixes was achieved through laboratory complex-modulus tests at different temperatures and frequencies, using pavement cores from the surveyed roads. The theoretical temperature adjustment factors for each model developed and each section analysed were calculated. Finally, a comparative study among the different adjustment factors (existing, empirical and theoretical) was carried out. It has shown that, in all analysed cases, the factors obtained with the finite elements model are the closest to the empirical factors (reference value for the analysed sections). The finite elements model developed makes it possible to reproduce the visco-elastic behavior of the asphalt mixes and the dynamic nature of the applied loads. Linear isoparametric tetrahedral elements (C3D8R) have been used for the pavement and the subgrade, while infinite elements (CIN3D8) have been used for the foundations.

Determination of the average ionization and thermodynamic regimes of xenon plasmas with an application to the characterization of blast waves launched in xenon clusters

Radiative shock waves play a pivotal role in the transport energy into the stellar medium. This fact has led to many efforts to scale the astrophysical phenomena to accessible laboratory conditions and their study has been highlighted as an area requiring further experimental investigations. Low density material with high atomic mass is suitable to achieve radiative regime, and, therefore, low density xenon gas is commonly used for the medium in which the radiative shock propagates. In this work the averageionization and the thermodynamicregimes of xenonplasmas are determined as functions of the matter density and temperature in a wide range of plasma conditions. The results obtained will be applied to characterize blastwaveslaunched in xenonclusters

Characterization Of Friction Stir Welded Joints Of Aa 2024-T351 - Native Vs. Treated By Laser Shock Processing

The paper presents a consistent set of results showing the ability of Laser Shock Processing (LSP) in modifying the overall properties of the Friction Stir Welded (FSW) joints made of AA 2024-T351. Based on laser beam intensities above 109 W/cm2 with pulse energies of several Joules and pulses durations of nanoseconds, LSP is able of inducing a compression residual stress field, improving the wear and fatigue resistance by slowing crack propagation and stress corrosion cracking, but also improving the overall behaviour of the structure. After the FSW and LSP procedures are briefly presented, the results of micro-hardness measurements and of transverse tensile tests, together with the corrosion resistance of the native joints vs. LSP treated are discussed. The ability of LSP to generate compressive residual stresses and to improve the behaviour of the FSW joints is underscored.

Characterization cement pastes degraded in lanoratory solutions and physiochemical parameters employed for modeling the process

Previously degradation studies carried out, over a number of different mortars by the research team, have shown that observed degradation does not exclusively depend on the solution equilibrium pH, nor the aggressive anions relative solubility. In our tests no reason was found that could allow us to explain, why same solubility anions with a lower pH are less aggressive than others. The aim of this paper is to study cement pastes behavior in aggressive environments. As observed in previous research, this cement pastes behaviors are not easily explained only taking into account only usual parameters, pH, solubility etc. Consequently the paper is about studying if solution physicochemical characteristics are more important in certain environments than specific pH values. The paper tries to obtain a degradation model, which starting from solution physicochemical parameters allows us to interpret the different behaviors shown by different composition cements. To that end, the rates of degradation of the solid phases were computed for each considered environment. Three cement have been studied: CEM I 42.5R/SR, CEM II/A-V 42.5R and CEM IV/B-(P-V) 32.5 N. The pastes have been exposed to five environments: sodium acetate/acetic acid 0.35 M, sodium sulfate solution 0.17 M, a solution representing natural water, saturated calcium hydroxide solution and laboratory environment. The attack mechanism was meant to be unidirectional, in order to achieve so; all sides of cylinders were sealed except from the attacked surface. The cylinders were taking out of the exposition environments after 2, 4, 7, 14, 30, 58 and 90 days. Both aggressive solution variations in solid phases and in different depths have been characterized. To each age and depth the calcium, magnesium and iron contents have been analyzed. Hydrated phases evolution studied, using thermal analysis, and crystalline compound changes, using X ray diffraction have been also analyzed. Sodium sulphate and water solutions stabilize an outer pH near to 8 in short time, however the stability of the most pH dependent phases is not the same. Although having similar pH and existing the possibility of forming a plaster layer near to the calcium leaching surface, this stability is greater than other sulphate solutions. Stability variations of solids formed by inverse diffusion, determine the rate of degradation.

Research lines in Hyperthermia at the Bioinstrumentation Laboratory of the Centre for Biomedical Technology

The Bioinstrumentation Laboratory belongs to the Centre for Biomedical Technology (CTB) of the Technical University of Madrid and its main objective is to provide the scientific community with devices and techniques for the characterization of micro and nanostructures and consequently finding their best biomedical applications. Hyperthermia (greek word for “overheating”) is defined as the phenomenon that occurs when a body is exposed to an energy generating source that can produce a rise in temperature (42-45ºC) for a given time [1]. Specifically, the aim of the hyperthermia methods used in The Bioinstrumentation Laboratory is the development of thermal therapies, some of these using different kinds of nanoparticles, to kill cancer cells and reduce the damage on healthy tissues. The optical hyperthermia is based on noble metal nanoparticles and laser irradiation. This kind of nanoparticles has an immense potential associated to the development of therapies for cancer on account of their Surface Plasmon Resonance (SPR) enhanced light scattering and absorption. In a short period of time, the absorbed light is converted into localized heat, so we can take advantage of these characteristics to heat up tumor cells in order to obtain the cellular death [2]. In this case, the laboratory has an optical hyperthermia device based on a continuous wave laser used to kill glioblastoma cell lines (1321N1) in the presence of gold nanorods (Figure 1a). The wavelength of the laser light is 808 nm because the penetration of the light in the tissue is deeper in the Near Infrared Region. The first optical hyperthermia results show that the laser irradiation produces cellular death in the experimental samples of glioblastoma cell lines using gold nanorods but is not able to decrease the cellular viability of cancer cells in samples without the suitable nanorods (Figure 1b) [3]. The generation of magnetic hyperthermia is performed through changes of the magnetic induction in magnetic nanoparticles (MNPs) that are embedded in viscous medium. The Figure 2 shows a schematic design of the AC induction hyperthermia device in magnetic fluids. The equipment has been manufactured at The Bioinstrumentation Laboratory. The first block implies two steps: the signal selection with frequency manipulation option from 9 KHz to 2MHz, and a linear output up to 1500W. The second block is where magnetic field is generated ( 5mm, 10 turns). Finally, the third block is a software control where the user can establish initial parameters, and also shows the temperature response of MNPs due to the magnetic field applied [4-8]. The Bioinstrumentation Laboratory in collaboration with the Mexican company MRI-DT have recently implemented a new research line on Nuclear Magnetic Resonance Hyperthermia, which is sustained on the patent US 7,423,429B2 owned by this company. This investigation is based on the use of clinical MRI equipment not only for diagnosis but for therapy [9]. This idea consists of two main facts: Magnetic Resonance Imaging can cause focal heating [10], and the differentiation in resonant frequency between healthy and cancer cells [11]. To produce only heating in cancer cells when the whole body is irradiated, it is necessary to determine the specific resonant frequency of the target, using the information contained in the spectra of the area of interest. Then, special RF pulse sequence is applied to produce fast excitation and relaxation mechanism that generates temperature increase of the tumor, causing cellular death or metabolism malfunction that stops cellular division

A fatigue damage model for seismic response of RC structures

Numerous damage models have been developed in order to analyze seismic behavior. Among the different possibilities existing in the literature, it is very clear that models developed along the lines of continuum damage mechanics are more consistent with the definition of damage as a phenomenon with mechanical consequences because they include explicitly the coupling between damage and mechanical behavior. On the other hand, for seismic processes, phenomena such as low cycle fatigue may have a pronounced effect on the overall behavior of the frames and, therefore, its consideration turns out to be very important. However, most of existing models evaluate the damage only as a function of the maximum amplitude of cyclic deformation without considering the number of cycles. In this paper, a generalization of the simplified model proposed by Cipollina et al. [Cipollina A, López-Hinojosa A, Flórez-López J. Comput Struct 1995;54:1113–26] is made in order to include the low cycle fatigue. Such a model employs in its formulation irreversible thermodynamics and internal state variable theory.

Exploring polysilicon deposition conditions through a laboratory CVD prototype

Cost and energy consumption related to obtaining polysilicon impact significantly on the total photovoltaic module cost and its energy payback time. Process simplifications can be performed, leading to cost reductions. Nowadays, among several approaches currently pursued to produce the so called Solar Grade Silicon, the chemical route, named Siemens process, is the dominant one. At the Instituto de Energía Solar research on this topic is focused on the chemical route, in particular on the polysilicon deposition step by chemical vapor deposition (CVD) from Trichlorosilane through a laboratory prototype. Valuable information about the phenomena involved in the polysilicon deposition process and the operating conditions is obtained from our experiments. A particular feature of our system is the inclusion of a mass spectrometer. The present work comprises spectra characterization of the polysilicon deposition chemical reaction, temperature and inlet gas mixture composition influence on the deposition rate and analysis of polysilicon deposition conditions for the ?pop-corn' phenomenon to appear, based on experimental experience (Actas de la Special Issue: E-MRS 2012 Spring Meeting ? Symposium A

Modelization of low cycle fatigue damage in frames

Damage models based on the Continuum Damage Mechanics (CDM) include explicitly the coupling between damage and mechanical behavior and, therefore, are consistent with the definition of damage as a phenomenon with mechanical consequences. However, this kind of models is characterized by their complexity. Using the concept of lumped models, possible simplifications of the coupled models have been proposed in the literature to adapt them to the study of beams and frames. On the other hand, in most of these coupled models damage is associated only with the damage energy release rate which is shown to be the elastic strain energy. According to this, damage is a function of the maximum amplitude of cyclic deformation but does not depend on the number of cycles. Therefore, low cycle effects are not taking into account. From the simplified model proposed by Flórez-López, it is the purpose of this paper to present a formulation that allows to take into account the degradation produced not only by the peak values but also by the cumulative effects such as the low cycle fatigue. For it, the classical damage dissipative potential based on the concept of damage energy release rate is modified using a fatigue function in order to include cumulative effects. The fatigue function is determined through parameters such as the cumulative rotation and the total rotation and the number of cycles to failure. Those parameters can be measured or identified physically through the haracteristics of the RC. So the main advantage of the proposed model is the possibility of simulating the low cycle fatigue behavior without introducing parameters with no suitable physical meaning. The good performance of the proposed model is shown through a comparison between numerical and test results under cycling loading.