Interface tailoring for adhesion enhancement of diamond-like carbon thin films


Autoria(s): Salvadori, Maria Cecilia Barbosa da Silveira; Teixeira, Fernanda de Sá; Araujo, Wagner Wlysses Rodrigues de; Sgubin, Leonardo Gimenes; Brown, I. G.
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

20/08/2013

20/08/2013

01/05/2012

Resumo

We have explored the suitability and characteristics of interface tailoring as a tool for enhancing the adhesion of hydrogen-free diamond-like carbon (DLC) thin films to silicon substrates. DLC films were deposited on silicon with and without application of an initial high energy carbon ion bombardment phase that formed a broad Si-C interface of gradually changing Si:C composition. The interface depth profile was calculated using the TRIDYN simulation program, revealing a gradient of carbon concentration including a region with the stoichiometry of silicon carbide. DLC films on silicon, with and without interface tailoring, were characterized using Raman spectroscopy, scanning electron microscopy, atomic force microscopy and scratch tests. The Raman spectroscopy results indicated sp3-type carbon bonding content of up to 80%. Formation of a broadened Si:C interface as formed here significantly enhances the adhesion of DLC films to the underlying silicon substrate. (C) 2012 Elsevier B.V. All rights reserved.

NUS

NUS

[R284000087112]

Identificador

DIAMOND AND RELATED MATERIALS, LAUSANNE, v. 25, n. 5, supl. 1, Part 1, pp. 8-12, MAY, 2012

0925-9635

http://www.producao.usp.br/handle/BDPI/32625

10.1016/j.diamond.2012.02.005

http://dx.doi.org/10.1016/j.diamond.2012.02.005

Idioma(s)

eng

Publicador

ELSEVIER SCIENCE SA

LAUSANNE

Relação

DIAMOND AND RELATED MATERIALS

Direitos

restrictedAccess

Copyright ELSEVIER SCIENCE SA

Palavras-Chave #DIAMOND-LIKE CARBON #INTERFACE TAILORING #ENHANCED ADHESION #ION BOMBARDMENT #DYNAMIC COMPOSITION CHANGES #IMMERSION ION-IMPLANTATION #AMORPHOUS-CARBON #ARC DEPOSITION #SIMULATION #SCRATCH #VACUUM #STRESS #GROWTH #TRIDYN #MATERIALS SCIENCE, MULTIDISCIPLINARY
Tipo

article

original article

publishedVersion