Thermal study of cyclopalladated complexes of the type [Pd-2(dmba)(2)X-2(bpe)] - (X=NO3-, Cl-, N-3(-), NCO-, NCS-; bpe=trans-1,2-bis(4-pyridyl)ethylene)
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/11/2005
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Resumo |
The synthesis, characterization and thermal analysis of the novel cyclometallated compounds [Pd-2(dmba)(2)Cl-2(mu-bpe)] (1), [Pd-2(dmba)(2)(N-3)(2)(mu-bpe)] (2), [Pd-2(dmba)(2)(NCO)(2)(mu-bpe)] (3), [Pd-2(dmba)(2)(SCN)(2)(mu-bpe)] (4), [Pd-2(dmba)(2)(NO3)(2)(mu-bpe)] (5) (bpe=trans-1,2-bis(4-pyridyl)ethylene; dmba=N,N-dimethylbenzylamine) are described. The thermal stability of [Pd-2(dmba)(2)X-2(mu-bpe)] complexes varies in the sequence 1 > 4 > 3 > 2 > 5. The final residues of the thermal decompositions were characterized as metallic palladium by X-ray powder diffraction. |
Formato |
361-364 |
Identificador |
http://dx.doi.org/10.1007/s10973-005-0903-3 Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 82, n. 2, p. 361-364, 2005. 1388-6150 http://hdl.handle.net/11449/32842 10.1007/s10973-005-0903-3 WOS:000233043700012 |
Idioma(s) |
eng |
Publicador |
Springer |
Relação |
Journal of Thermal Analysis and Calorimetry |
Direitos |
closedAccess |
Palavras-Chave | #cyclopalladated complexes #DTA #pseudohalides #TG |
Tipo |
info:eu-repo/semantics/article |