Binuclear cyclopalladated compounds with antitubercular activity: synthesis and characterization of [{Pd(C-2,N-dmba)(X)}(2)(mu-bpp)] (X = Cl, Br, NCO, N-3; bpp=1,3-bis(4-pyridyl)propane)
Contribuinte(s) |
Universidade Estadual Paulista (UNESP) |
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Data(s) |
20/05/2014
20/05/2014
01/01/2012
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Resumo |
Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Reactions between [Pd(C-2,N-dmba)(mu-X)](2) (Hdmba = N,N-dimethylbenzylamine; X = Cl, Br, NCO, N-3) and 1,3-bis(4-pyridyl)propane (bpp) in 1 : 1 molar ratio at room temperature resulted in the binuclear compounds [{Pd(C-2,N-dmba)(X)}(2)(mu-bpp)] (X = Cl (1), Br (2), NCO (3), N-3 (4)), which were characterized by elemental analyses, infrared (IR), H-1- and C-13{H-1}-NMR spectroscopies, and thermogravimetric analysis. The IR and NMR data of 1-4 were consistent with the presence of bridging bpp. The thermal stability order of the complexes was 4 > 3 > 2 > 1. Compounds 1-4 and bpp were tested against Mycobacterium tuberculosis and their MIC values were determined. |
Formato |
1434-1442 |
Identificador |
http://dx.doi.org/10.1080/00958972.2012.673718 Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 65, n. 8, p. 1434-1442, 2012. 0095-8972 http://hdl.handle.net/11449/26024 10.1080/00958972.2012.673718 WOS:000304322800012 |
Idioma(s) |
eng |
Publicador |
Taylor & Francis Ltd |
Relação |
Journal of Coordination Chemistry |
Direitos |
closedAccess |
Palavras-Chave | #Cyclopalladated #bpp #Spectroscopy #Tuberculosis #Antimycobacterial agents |
Tipo |
info:eu-repo/semantics/article |