Hydrochalcogenation of activated olefines. Synthesis of functionalized dialkylchalcogenides
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2008
|
| Resumo |
Alkanethiols, selenols and tellurols are generated in situ by reaction of elemental sulfur, selenium and tellurium with commercial alkyllithiums, followed by reaction with deoxygenated water. The alkanechalcogenols react in situ with activated ole. ns in a Michael- type addition reaction. (c) 2008 Elsevier B. V. All rights reserved. |
| Identificador |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.693, n.17, p.2929-2936, 2008 0022-328X http://producao.usp.br/handle/BDPI/31276 10.1016/j.jorganchem.2008.06.014 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE SA |
| Relação |
Journal of Organometallic Chemistry |
| Direitos |
restrictedAccess Copyright ELSEVIER SCIENCE SA |
| Palavras-Chave | #alkanethiols #alkaneselenols #alkanetellurols #dialkylsulfides #dialkylselenides #dialkyltellurides #ELECTRON-DEFICIENT ALKENES #PHASE-TRANSFER CONDITIONS #MICHAEL ADDITION #IONIC LIQUID #TELLURIDES #THIOLS #ORGANOMETALLICS #ANIONS #ROUTE #ORGANOTELLURIDES #Chemistry, Inorganic & Nuclear #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
