Dinuclear half-sandwich complexes containing bridging 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands. Molecular structures of Cp2Fe2(CO)(3)[mu-Se2C2(B10H10)], Cp2Ru2[mu-S2C2(B10H10)](2), and CP*Ru-2(2)(mu-Se)[mu-Se2C2(B10H10)].
| Data(s) |
2002
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|---|---|
| Resumo |
Three prototypes of dinuclear complexes were obtained from the reactions of dilithium 1,2-dicarbacloso-dodecaborane-1,2-dichalcogenolates, (B10H10)C-2-(ELi)(2) (E = S, Se), with CpFe(CO)(2)Cl (1), CpRu(PPh3)(2)Cl (2), or [Cp*RuCl2](2) (3), respectively, and their structures have been determined by X-ray crystallography. |
| Identificador | |
| Idioma(s) |
英语 |
| Fonte |
Lu SX;Jin GX;Eibl S;Herberhold M;Xin Y.Dinuclear half-sandwich complexes containing bridging 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolato ligands. Molecular structures of Cp2Fe2(CO)(3)[mu-Se2C2(B10H10)], Cp2Ru2[mu-S2C2(B10H10)](2), and CP*Ru-2(2)(mu-Se)[mu-Se2C2(B10H10)].,ORGANOMETALLICS,2002,21(12):2533-2535 |
| Palavras-Chave | #CP-ASTERISK-IR #B-H ACTIVATION #METHYL ACETYLENE CARBOXYLATES #HALFSANDWICH COMPLEXES #ADDITION-REACTIONS #CRYSTAL-STRUCTURES #RH #1 #2-DITHIOLATE-O-CARBORANE #CYCLOMETALATION #(P-CYMENE)RU |
| Tipo |
期刊论文 |
