Formation mechanism of defects in annealed InP


Autoria(s): Han YJ; Liu XL; Jiao JH; Lin LY
Data(s)

1998

Resumo

Dynamical formation mechanism of defects in the annealed nominally undoped semi-insulating InP obtained by high pressure, high temperature annealing of high purity materials is proposed. Local vibrational modes in tenths of InP samples reveal clearly existence of complexes related to hydrogen. Complexes of vacancy at indium site with one to four hydrogen atoms and isolated hydrogen or hydrogen dimers, complexes of hydrogen with various impurities are investigated by FTIR. Hydrogen can acts as an actuator for generation of antistructure defects. Fully hydrogenated indium vacancy dissociates leaving large lattice relaxation behind, deep donors, mainly larger complexes involving phosphorus at indium site and isolated hydrogen defects are created in nominally undoped InP after annealing. Also created are acceptor levels such as vacancy at indium site. Carrier charge compensation mechanism in nominally undoped InP upon annealing at high temperature is given. Microscopic models of hydrogen related defects are given. Structural, electronic and vibrational properties of LVMs related to hydrogen as well as their temperature effect are discussed.

Dynamical formation mechanism of defects in the annealed nominally undoped semi-insulating InP obtained by high pressure, high temperature annealing of high purity materials is proposed. Local vibrational modes in tenths of InP samples reveal clearly existence of complexes related to hydrogen. Complexes of vacancy at indium site with one to four hydrogen atoms and isolated hydrogen or hydrogen dimers, complexes of hydrogen with various impurities are investigated by FTIR. Hydrogen can acts as an actuator for generation of antistructure defects. Fully hydrogenated indium vacancy dissociates leaving large lattice relaxation behind, deep donors, mainly larger complexes involving phosphorus at indium site and isolated hydrogen defects are created in nominally undoped InP after annealing. Also created are acceptor levels such as vacancy at indium site. Carrier charge compensation mechanism in nominally undoped InP upon annealing at high temperature is given. Microscopic models of hydrogen related defects are given. Structural, electronic and vibrational properties of LVMs related to hydrogen as well as their temperature effect are discussed.

于2010-10-29批量导入

Made available in DSpace on 2010-10-29T06:37:20Z (GMT). No. of bitstreams: 1 3040.pdf: 392263 bytes, checksum: dd4d290baa0de6fc549dd1b325a200ec (MD5) Previous issue date: 1998

SPIE, Taiwan Chapter.; Photon Ind Dev Assoc.; Natl Sci Council, Taiwan.

Chinese Acad Sci, Inst Semicond, Beijing 100083, Peoples R China

SPIE, Taiwan Chapter.; Photon Ind Dev Assoc.; Natl Sci Council, Taiwan.

Identificador

http://ir.semi.ac.cn/handle/172111/13875

http://www.irgrid.ac.cn/handle/1471x/105119

Idioma(s)

英语

Publicador

SPIE-INT SOC OPTICAL ENGINEERING

1000 20TH ST, PO BOX 10, BELLINGHAM, WA 98227-0010 USA

Fonte

Han YJ; Liu XL; Jiao JH; Lin LY .Formation mechanism of defects in annealed InP .见:SPIE-INT SOC OPTICAL ENGINEERING .OPTOELECTRONIC MATERIALS AND DEVICES, 3419,1000 20TH ST, PO BOX 10, BELLINGHAM, WA 98227-0010 USA ,1998,346-353

Palavras-Chave #光电子学 #defects formation #hydrogen related defects #semi-insulating #InP
Tipo

会议论文