A Quantitative Study on Paleo—River Environment During Late Jurassic on yaojie Region,Minhe Basin

Fluvial Sedimentation of alluvial facies prevailed during the Late Jrassic in the Minhe Basin.On the basis of the study of sedimentary facies of the Upper Jurassic series.this paper focuses on the river types suing the "Architecture Element" analysis method proposed by Miall,and calculated all the quantitative parameters to reflect the characteristics of the stream channel geometry and hydrodynamic conditions of paleo-rivers with the equations of ethrideg,schumm et al.Finally,we discussed the characteristics of environmental evolution of palsorivers on the quantitative basis.Our conclusion indicates that the evolution of paleo-rivers during the Late Jurassic,from early to late,shows such a tendency as alluvial fan river→ braid river→alluvial fan river→mid-sinuoisty river→ high-sinuosity river.

A study of the dependence of ferrocene diffusion on electrolyte concentration and size in a polymer medium using non-steady-state chronoamperometry

This article describes a quantitative study of the diffusion rate of ferrocene(Fc) dissolved in ploy(ethylene glycol)(PEG) medium containing MClO(4)(M = Li+, Na+, Bu(4)N(+), Hx(4)N(+)). The apparent diffusion coefficient D-app and the active concentration c(a) of Fc were simultaneously measured by using non-steady-state chronoamperometry. The D-app and c(a) of Fc have been estimated in PEG containing different concentrations and sizes of supporting electrolyte, and the dependence of D-app on ferrocene concentrations has been observed. The values of D-app decrease with increasing concentrations of Fc, increasing concentrations of LiClO4 or the ratio (O:Li) and also with 4 decreasing cation radius of the electrolyte. The temperature dependencies conform to a simple free volume model. The concentration and size of the counterion dependencies of the diffusion rate are similar to the behavior of their dependencies of ionic conductivity in polyelectrolyte.

Chemical bond analysis of nonlinearity of urea crystal

A novel and quantitative study on structure-property relationships has been carried out in urea crystal, based on the dielectric theory of complex crystals and the modified Levine bond charge model, mainly from the chemical bond viewpoint. For the first time, it was treated like this, and the bond parameters and linear and nonlinear characteristics of constituent chemical bonds were presented quantitatively. The theoretical result agrees satisfactorily with the experimental datum and can reasonably explain the nonlinear origin of urea crystal, that is, the C-N bond in the conjugated system of bonds O double left arrow C<--N-H. At the same time, the novel method should be a useful tool toward the future development of the search for new nonlinear optical (NLO) materials in the organic crystal field.

基于GIS的滑坡危险度区划定量研究

Abstract With the Development of the West Regions, the contradiction between economy and geological hazards was once again brought to our face in the Loess Plateau where was ,and is liable to geological hazards for the unique conditions of geology, hydrogeology, geography and meteorology. The goal to realize harmonious development between human and the earth was always there, and landslide hazard zoning provided us an effective way against geological hazards and damage. In the background of the construction of 750KV transformer substation in TianShui, we summarized some theories, methods and development of landslide hazard zoning and discussed the application of information value model in landslide hazard zoning. A called “judgement matrix” like in AHP was introduced to the information value model to solve the key point of landslide hazard zoning — choice of factors and weight of each factor. GIS was applied in the landslide hazard zoning, with its comprehensive function on data management, spatial analysis and mapping. A zonation map of landslide hazard was worked out on MAPGIS aimed to have something of reference and instruction on the construction of the transformer substation. Key words: landslide; hazard zoning; information value model; GIS; judgement matrix

填土边坡水文作用机理与破坏过程研究—以深圳羊宝地填土滑坡为例

A full understanding of failure mechanism, critical hydrological condition, and process of mobilization and deposition of a landslide is essential for optimal design of stabilization measure and forecasting of landslide hazard. This requires a quantitative study of hydrological response of a slope to rainfall through field monitoring, laboratory test and numerical modelling. At 13:40 on September 18, 2002, a fill slope failed following a period of prolonged rain in Shenzhen, resulting in 5 fatalities and 31 injuries. The failed mass with a volume about 2.5×104m3 traveled about 140m on level ground. Field monitoring, laboratory test, theoretical analysis and numerical modelling were carried out to undestand the hydrological response and failure mechanism of this fill slope. This thesis mainly focuses on the following aspects: (1) The hydrological responses and failure processes of slopes under rainfall infiltration were reviewed. Firstly, the factors influencing on the hydrological responses of slopes were analysed. Secondly, the change of stress state of slope soil and modelling methods of slope failure under rainfall infiltration were reviewed. (2) The characteristics of the Yangbaodi landslide and associated rainfall triggering the failure were presented. The failure was characterized by shallow flowslide, due to an increase of ground water table caused by rainfall infiltration. (3) A fully automated instrumentation was carried out to monitor rainfall, and saturated – unsaturated hydrological response of the fill slope, using a raingauge, piezometers, tensiometers and moisture probes. A conceptual hydrogeological model was presented based on field monitoring and borehole data. Analysis of monitoring data showed that the high pore water pressure in fill slope was caused by upward flow of semiconfined groundwater in the moderately decomposed granite. (4) Laboratory and in-situ testing was performed to study the physical and mechanical properties of fills. Isotropically consolidated undrained compression tests and anisotropically consolidated constant shear stress tests were carried out to understand the failure mechanism of the fill slope. It is indicated that loosely compacted soil is of strain-softening behaviour under undrained conditions, accompanied with a rapid increase in excess pore water pressure. In anisotropically consolidated constant shear stress tests, a very small axial strain was required to induce the failure and the excess pore water pressure increased quickly at failure. This indicated that static liquefaction caused by rise in groundwater table due to rainfall infiltration occurred. (5) The hydraulic conductivity of the highly and moderately decomposed granite was estimated using monitering data of pore water pressure. A saturated – unsaturated flow was modeled to study the hydrological response of the fill slope using rainfall records. It was observed that the lagged failure was due to the geological conditions and the discrepancy of hydraulic conductivity of slope soils. The hydraulic conductivity of moderately decomposed granite is relatively higher than the other materials, resulting in a semiconfied groundwater flow in the moderately decomposed granite, and subsequent upward flow into the upper fill layer. When the ground water table in the fill layer was increased to the critical state, the fill slope failed. (6) Numerical exercises were conducted to replay the failure process of the fill slope, based on field monitoring, laboratory and in-situ testing. It was found that the fill slope was mobilized by a rapid transfer of the concentrated shear stress. The movement of failure mass was characterized by viscosity fluid with a gradual increase in velocity. The failure process, including mobilization and subsequent movement and deposition, was studied using numerical methods.

改造型盆地油气成藏机理与油气预测－以银根－额济纳旗盆地为例

Reformed basin is a basin that underwent multiple immense reformation after the sedimentary stage, the major geologic elements of the petroleum system in the prototyped basin are destroyed to a certain extent, and their petroleum system has been reconstructed. This type of basin is frequently found in the course of exploration both home and abroad. In China, especially in the western and southern part of China, the basins in which oil explorations have been conducted are mostly reformed basins. The reformed basins from Paleozoic, Late Mesozoic to Cenozoic are widely distributed in West and South China. They are, and moreover, will be a challenge for oil and gas exploration. The conventional investigation and exploration techniques used in the slightly reconstructed basin just don't work well when facing the reformed basin. Therefore, the study on the reformed basin, especially the study on the pool-forming mechanism and reservoir prediction becomes a focus and one of difficulties for the geologists overseas and domestic. Yingen-Ejinaqi Basin is a typical case of the Late Mesozoic and Cenozoic reformed basins in China. It locates in West China and is a exploration frontier with difficulties and no break through is made for years. A comprehensive research on it will be of significance for oil and gas exploration in similar basins of China. The late research for reformed basin in China now is mainly concentrated on basin classification, formation mechanism, geologic features, and survey technique, distribution regularity of oil accumulation and its dominating factors, assessment of oil exploration prospect and target zones, etc. On the other hand, the study on the pool-forming mechanism and reservoir prediction seems insufficient in systematization, and the research is deficient in methodology and combination of qualitative and quantitative studies, as well as the application of the new theory and techniques. The current efforts are mainly directed to structures (faults), sedimentation, the relationship between reservoir evolution and oil accumulation, and some other relevant fields. However, the application of the new theory and techniques seems to be insufficient such as petroleum system, pool-forming dynamics, fluid pressure compartment, and basin simulation, etc. So is the dynamic and integrated research. As a result, incomplete knowledge and understandings derived from the research on pool-forming mechanism and reservoir prediction often do not accord with rea-lity of the basin. The study and exploration under the guidance of this knowledge will inevitably lead to errors and failure. This paper, based on the previous study of the other geologists on reformed basins, with emphasis on "wholeness or systematic, dynamic and integrated" research, presents a reverse thinking of beginning from conserved units in the basin and the combination of qualitative and quantitative study with new theory and technique by building a geological model. The paper also puts forward a new thought for studying the oil & gas accumulation and reservoir prediction , and establishes a new research system for reformed basin. It is verified by the known reservoir and oil accumulation area in the basin and has a practical value for use and reference. The new ideas and achievements in this research are as following: 1.This is the first time that the system for studying the reformed basin and its pool-forming mechanism and reservoir prediction is presented. A reverse thinking and combination of qualitative & quantitative are applied here with emphasis on "wholeness or systematic, dynamic and integrated" research, new theory, techniques & methods comprehensive use and geologic models building. 2. Identifying criterion and methods, classifying schemes, and denominating principles for the conserved units of reformed basins are presented in this paper. The geologic model of conserved units of Yingen-Ejinaqi Basin has been built. It is a practical method when combined with the traditional way for basin survey and the conserved units study. 3.The dynamic sources of basin deformation are believed to be stress, gravity and thermodynamics. The stress and gravity are key factors in basin deformation and pool forming, especially stress. Scientific proof is provided by classifying the functional type, style and range of the stress, gravity and thermodynamics. 4.The pool forming and reservoir distribution of Yingen-Ejinaqi Basin are controlled by multiple factors or geologic conditions or/and co-controlled by both of them. The qualitative and quantitative research on petroleum system and basin modeling will help us understand and determine the pool-forming period of the conserved unit (timing), the oil migrating direction (orientation), the oil accumulating region (location), the oil distributing border (bordering) and the size of oil accumulation (quantification). Thus the pool-forming and distribution zones can be predicted. 5.Three generating modes (reform-succession type, reform-destroyed type and reform-regenerating type or reform-newborn type) of pool forming for reformed basins are presented here, together with the inner relationships between basin deformation type, overlapping style and pool-forming modes. The pool-forming modes are determined by deformation type and overlapping style. Reservoir distribution will be predicted based on the modes and other concrete pool-forming conditions. 6.The evaluation methods of the conserved units and zones and the parameter selection are reliable in optimal selecting of target zones. The technical terms, new ideas and methods for the study of reformed basins, the pool-forming mechanism and reservoir prediction are presented in this paper. The concepts and terms, the identifying criterion, the denominating principles, the generating modes for pool forming, the methods of reservoir prediction, and the evaluation techniques for conserved units and zones can be used for reference in studies on the petroleum exploration of reformed basins in China and abroad. It serves as a typical example for further research of the reformed basins and the geologic regulations of oil accumulation. It has a practical value of use and reference. The future research in the field of pool-forming mechanism of the reformed basins may well be on the process simulation of pool-forming dynamics of the reformed basins. Experimental work has been conducted to simulate the processes by using quantitative and qualitative methods combined. The further study in this field calls for more efforts.

Quantitative structure-property relationship study on reductive dehalogenation of selected halogenated aliphatic hydrocarbons in sediment slurries

In this study, by the use of partial least squares (PLS) method and 26 quantum chemical descriptors computed by PM3 Hamiltonian, a quantitative structure-property relationship (QSPR) model was developed for reductive dehalogenation rate constants of 13 halogenated aliphatic compounds in sediment slurry under anaerobic conditions. The model can be used to explain the dehalogenation mechanism. Halogenated aliphatic compounds with great energy of the lowest unoccupied molecular orbital (E-lumo), total energy (TE), electronic energy (EE), the smallest bond order of the carbon-halogen bonds (BO) and the most positive net atomic charges on an atom of the molecule (q(+)) values tend to be reductively dehalogenated slow, whereas halogenated aliphatic compounds with high values of molecular weight (Mw), average molecular polarizability (a) and core-core repulsion energy (CCR) values tend to be reductively dehalogenated fastest. (C) 2001 Published by Elsevier Science Ltd.

Quantitative FTIR study of PHBV/bisphenol A blends

FTIR spectroscopy was used to verify the presence of intermolecular hydrogen bond (inter-H-bond) between poly-(3-hydroxybutyrate co-3-hydroxyvalerate) (PHBV) and bisphenol A (BPA). By monitoring the spectral changes during PHBV crystallization and blends dissociation, the absorptivity ratio of C=O bonds in crystalline and amorphous regions in PHBV and that of H-bonded and free C=O in PHBV/BPA blends were experimentally determined as 1.40 and 1.68, respectively. Using curve-fitting program, the C=O absorptions in spectra of blends were ascribed to three types of bonds: amorphous, crystalline and H-bonded C=O. The crystallinity of PHBV and the fraction of H-bonded C=O were calculated. These results indicated that the H-bond clearly suppressed the PHBV crystallization. Furthermore, the fraction of BPA molecules that simultaneously formed two hydrogen bonds (H-bonds) with C=O was estimated. It revealed that there existed a H-bond network in PHBV/BPA blends. This network was compared with the covalent network by estimating the number of atoms between every two adjacent crosslink points in chain. Up to the high density of H-bond discussed in this paper, there was always a certain part in PHBV that crystallized due to the dynamic character of hydrogen bonds; however, the hydrogen bonds significantly reduced the crystallization rate of PHBV.

Experimental Study On Liquid Free Surface In Buoyant-Thermocapillary Convection

We investigate the surface deformations of buoyant-thermocapillary convection in a rectangular cavity clue to gravity and temperature gradient between the two sidewalls. The cavity is 52mm x 42mm in horizontal cross section, the thickness of liquid layer h is changed from 2.5mm to 6.5mm. Surface deformations of h = 3.5mm and 6.0mm are discussed and compared. Temperature difference is increased gradually, and the flow in the liquid layer will change from stable convection to unstable convection. Two kinds of optical diagnostic system with image processor are developed for study of the kinetics of buoyant-thermocapillary convection, they give out the information of liquid free surface. The quantitative results are calculated by Fourier transform and correlation analysis, respectively. With the increasing temperature gradient, surface deformations calculated are more declining. It is interesting phenomenon that the inclining directions of the convections in thin and thick liquid layers are different. For a thin layer, the convection is mainly controlled by thermocapillary effect. However, for a thick layer, the convection is mainly controlled by buoyancy effect. The surface deformation theoretically analysed is consistent with our experimental results. The present experiment proves that surface deformation is related to temperature gradient and thickness of the liquid layer. In other words, surface deformation lies on capillary convection and buoyancy convection.

An Experimental Study on Flame Propagation in Cornstarch Dust Clouds

Following the quantitative determination of dust cloud parameters, this study investigates the flame propagation through cornstarch dust clouds in a vertical duct of 780 mm height and 160 x 160 mm square cross section, and gives particular attention to the effect of small scale turbulence and small turbulence intensity on flame characteristics. Dust suspensions in air were produced using an improved apparatus ensuring more uniform distribution and repeatable dust concentrations in the testing duct. The dispersion-induced turbulence was measured by means of a particle image velocimetry (PIV) system, and dust concentrations were estimated by direct weighing method. This quantitative assessment made it possible to correlate observed flame behaviors with the parameters of the dust cloud. Upward propagating dust flames, from both closed/open bottom end to open/closed top end of the duct, were visualized by direct light and shadow photography. From the observation of propagation regimes and the measurements of flame velocity, a critical value of the turbulence intensity can be specified below which laminar flame propagation would be established. This transition condition was determined to be 10 cm/s. Laminar flames propagated with oscillations from the closed bottom end to the open top end of the testing duct, while the turbulent flames accelerated continuously. Both laminar and turbulent flames propagated with steady velocity from the open bottom end to the closed top end of the duct. The measured propagation velocity of laminar flames appeared to be in the range of 0.45-0.56 m/s, and it was consistent with the measurements reported in the literature. In the present experimental study, the influence of dust concentration on flame propagation was also examined, and the flame propagation velocity was found weakly sensitive to the variations in dust concentration. Some information on the flame structure was revealed from the shadow records, showing the typical heterogeneous feature of the dust combustion process.

Experimental Study on Surface Deformation and Surface Wave of Fluid Convection with Free Surface

An optical diagnostic system consisting of Michelson interferometer with image processor has been developed for study of the kinetics of thermal capillary convection and buoyancy convection. This optical interferometer has been used to observe and measure surface deformation and surface wave of capillary convection and buoyancy convection in a rectangular cavity with different temperature’s sidewalls. Fourier transformation is used to image processing. The quantitative results of surface deformation and surface wave have been calculated from the interference fringe pattern. With the increasing of temperature gradient, the liquid surface slant gradually. It’s deformation has been calculated, which is related directly with temperature gradient. This is one of the characters introducing convection. Another interesting phenomenon is the inclining direction, which is different when the liquid layer is thin or thick. When the liquid layer is thin, convection is mainly controlled by thermocapillary effect. However, When the liquid layer is thick, convection is mainly controlled by buoyancy effect. Surface deformation in the present experiment are more and more declining in this process. The present experiment proved that surface deformation appears before the appearance of surface wave on fluid convection, it is related with temperature gradient, and the height of liquid layer, and lies on capillary convection and buoyancy convection. The present experiment also demonstrates that the amplitude of surface wave of thermocapillary-buoyancy convection is much smaller than surface deformation, the wave is covered by deformation.