Novel carbon materials for thermal energy harvesting

To decrease the consumption of fossil fuels, research has been done on utilizing low grade heat, sourced from industrial waste streams. One promising thermoenergy conversion system is a thermogalvanic cell; it consists of two identical electrodes held at different temperatures that are placed in contact with a redox-based electrolyte [1, 2]. The temperature dependence of the direction of redox reactions allows power to be extracted from the cell [3, 4]. This study aims to increase the power conversion efficiency and reduce the cost of thermogalvanic cells by optimizing the electrolyte and utilizing a carbon based electromaterial, reduced graphene oxide, as electrodes. Thermal conductivity measurements of the K3Fe(CN)6/K4Fe(CN)6 solutions used, indicate that the thermal conductivity decreases from 0.591 to 0.547 W/m K as the concentration is increased from 0.1 to 0.4 M. The lower thermal conductivity allowed a larger temperature gradient to be maintained in the cell. Increasing the electrolyte concentration also resulted in higher power densities, brought about by a decrease in the ohmic overpotential of the cell, which allowed higher values of short circuit current to be generated. The concentration of 0.4 MK3Fe(CN)6/K4Fe(CN)6 is optimal for thermal harvesting applications using R-GO electrodes due to the synergistic effect of the reduction in thermal flux across the cell and the enhancement of power output, on the overall power conversion efficiency. The maximum mass power density obtained using R-GO electrodes was 25.51 W/kg (three orders of magnitude higher than platinum) at a temperature difference of 60 _C and a K3Fe(CN)6/K4Fe(CN)6 concentration of 0.4 M.

Carbon Nanotube – Reduced Graphene Oxide Composites for Thermal Energy Harvesting Applications

By controlling the SWNT-rGO electrode composition and thickness to attain the appropriate porosity and tortuosity, the electroactive surface area is maximized while rapid diffusion of the electrolyte through the electrode is maintained. This leads to an increase in exchange current density between the electrode and electrolyte which results in enhanced thermocell performance.

Nano-carbon electrodes for thermal energy harvesting

Thermogalvanic cells are capable of converting waste heat (generated as a by-product of almost all human activity) to electricity. These devices may alleviate the problems associated with the use of fossil fuels to meet the world's current demand for energy. This review discusses the developments in thermogalvanic systems attained through the use of nano-carbons as the electrode materials. Advances in cell design and electrode configuration that improve performance of these thermo converters and make them applicable in a variety of environments are also summarized. It is the aim of this review to act as a channel for further developments in thermogalvanic cell design and electrode engineering.

Enhanced thermal energy harvesting performance of a cobalt redox couple in ionic liquid-solvent mixtures

Thermoelectrochemical cells are increasingly promising devices for harvesting waste heat, offering an alternative to the traditional semiconductor-based design. Advancement of these devices relies on new redox couple/electrolyte systems and an understanding of the interplay between the different factors that dictate device performance. The Seebeck coefficient (Se) of the redox couple in the electrolyte gives the potential difference achievable for a given temperature gradient across the device. Prior work has shown that a cobalt bipyridyl redox couple in ionic liquids (ILs) displays high Seebeck coefficients, but the thermoelectrochemical cell performance was limited by mass transport. Here we present the Se and thermoelectrochemical power generation performance of the cobalt couple in novel mixed IL/molecular solvent electrolyte systems. The highest power density of 880 mW m-2, at a ΔT of 70 °C, was achieved with a 31 (v/v) MPN-[C2mim][B(CN)4] electrolyte combination. The significant power enhancement compared to the single solvent or IL systems results from a combination of superior ionic conductivity and higher diffusion coefficients, shown by electrochemical analysis of the different electrolytes. This is the highest power output achieved to-date for a thermoelectrochemical cell utilising a high boiling point redox electrolyte.

Temperature dependence of the electrode potential of a cobalt-based redox couple in ionic liquid electrolytes for thermal energy harvesting

Increasing the application of technologies for harvesting waste heat could make a significant contribution to sustainable energy production. Thermoelectrochemical cells are one such emerging technology, where the thermal response of a redox couple in an electrolyte is used to generate a potential difference across a cell when a temperature gradient exists. The unique physical properties of ionic liquids make them ideal for application as electrolytes in these devices. One of the keys to utilizing these media in efficient thermoelectrochemical cells is achieving high Seebeck coefficients, Se: the thermodynamic quantity that determines the magnitude of the voltage achieved per unit temperature difference. Here, we report the Se and cell performance of a cobalt-based redox couple in a range of different ionic liquids, to investigate the influence of the nature of the IL on the thermodynamics and cell performance of the redox system. The results reported include the highest Se to-date for an IL-based electrolyte. The effect of diluting the different ILs with propylene carbonate is also reported, which results in a significant increase in the output powers and current densities of the device.

Harvesting waste thermal energy using a carbon-nanotube-based thermo-electrochemical cell

Low efficiencies and costly electrode materials have limited harvesting of thermal energy as electrical energy using thermo-electrochemical cells (or “thermocells”). We demonstrate thermocells, in practical configurations (from coin cells to cells that can be wrapped around exhaust pipes), that harvest low-grade thermal energy using relatively inexpensive carbon multiwalled nanotube (MWNT) electrodes. These electrodes provide high electrochemically accessible surface areas and fast redox-mediated electron transfer, which significantly enhances thermocell current generation capacity and overall efficiency. Thermocell efficiency is further improved by directly synthesizing MWNTs as vertical forests that reduce electrical and thermal resistance at electrode/substrate junctions. The efficiency of thermocells with MWNT electrodes is shown to be as high as 1.4% of Carnot efficiency, which is 3-fold higher than for previously demonstrated thermocells. With the cost of MWNTs decreasing, MWNT-based thermocells may become commercially viable for harvesting low-grade thermal energy.

Thermoelectric performance of a single-layer graphene sheet for energy harvesting

We investigate the thermoelectric (TE) figure-of-merit of a single-layer graphene (SLG) sheet by a physics-based analytical technique. We first develop analytical models of electrical and thermal resistances and the Seebeck coefficient of SLG by considering electron interactions with the in-plane and flexural phonons. Using those models, we show that both the figure-of-merit and the TE efficiency can be substantially increased with the addition of isotope doping as it significantly reduces the phonon-dominated thermal conductivity. In addition, we report that the TE open circuit output voltage and output power depends weakly on the SLG sheet dimensions and sheet concentration in the strongly diffusive regime. Proposed models agree well with the available experimental data and demonstrate the immense potential of graphene for waste-heat recovery application.

Theoretical insights on the electro-thermal transport properties of monolayer MoS2 with line defects

Two dimensional (2D) materials demonstrate several novel electrical, mechanical, and thermal properties which are quite distinctive to those of their bulk form. Among many others, one important potential application of the 2D material is its use in the field of energy harvesting. Owing to that, here we present a detailed study on electrical as well as thermal transport of monolayer MoS2, in quasi ballistic regime. Besides the perfect monolayer in its pristine form, we also consider various line defects which have been experimentally observed in mechanically exfoliated MoS2 samples. For calculating various parameters related to the electrical transmission, we employ the non-equilibrium Green's function-density functional theory combination. However, to obtain the phonon transmission, we take help of the parametrized Stillinger-Weber potential which can accurately delineate the inter-atomic interactions for the monolayer MoS2. Due to the presence of line defects, we observed significant reductions in both the charge carrier and the phonon transmissions through a monolayer MoS2 flake. Moreover, we also report a comparative analysis showing the temperature dependency of the thermoelectric figure of merit values, as obtained for the perfect as well as the other defective 2D samples. (C) 2016 AIP Publishing LLC.

CH2 energy harvesting systems : economic use and efficiency

This paper looks at the City of Melbourne's new office development CH₂ as a case study of world class energy performance. In particular, the integrated design of conventionally independent systems has led to the potential to deliver significant savings to the Council and to deliver better environmental conditions to building occupants that in turn may contribute to satisfaction, well-being and Productivity. It is concluded that this project has the potential
to be an iconic example of effective implementation of ESD (environmental sustainable design) principles and therefore act as a demonstration project to others. Energy efficiency of more than 50% of current benchmarks for Melbourne is effected. Energy harvesting is defined as arising from squander, waste and nature, which is a new concept introduced in this paper to better describe the design decision process.

Thermal evaluation of a greenhouse in a remote high altitude area of Nepal

Remote communities in the high altitude areas of Nepal suffer both chronic and acute malnutrition. This is due to a shortage of arable land and a harsh climate. For seven months of the year, the harvesting of fresh vegetables is almost impossible. Greenhouse technology, if appropriate for the location and its community, can extend the growing season considerably. Experience in the Ladakh region of India indicates that year-round cropping is possible in greenhouses in cold mountainous areas. A simple 50-m2 greenhouse has been constructed in Simikot, the main town of Humla, northwest Nepal. This paper describes the evaluation of the thermal performance of that greenhouse. Both measurement and simulation were used in the evaluation. Measurements during the winter of 2006-7 indicate that the existing design is capable of producing adequate growing conditions for some vegetable crops, but that improvements are required if crops like tomatoes are to be grown successfully. Options to improve the thermal performance of the greenhouse have been investigated by simulation. Improvements to the building envelope such as wall insulation, double-glazing and using a thermal screen were simulated with a validated TRNSYS model. The impact of the addition of nighttime heat from internal passive solar water collectors was also predicted. The simulations indicate that the passive solar water collectors would raise the average greenhouse air temperature by 2.5°C and the overnight air temperature would increase by 4.0°C. When used in combination, overnight temperatures are predicted to by almost 7°C higher.

Phenological cycles, thermal time and growth curves of mango fruit cultivars in subtropical conditions

There are many mango cultivars available in different regions. It is about time we analysed their productive behavior in these areas, as well as their phenological performance. This study aimed to evaluate: phenological cycles, thermal time and growth curves of mango fruit cultivars in subtropical conditions. For this study we used the following cultivars: Espada Vermelha, Keitt and Palmer. All the experiments were done at UNESP experimental farm in Sao Manuel (SP), during the agricultural cycle from 2012 to 2013. It was selected 15 branches in each plant, which provided 150 per cultivar. It was determined the number of days of phenological cycles of flowering to fruit ripening, as well as the total number of days to flowering and harvesting. The thermal time was evaluated to each phenological cycle and expressed in accumulation of degree-days. The measurement of the longitudinal diameters (LD) and transverse diameters (TD) of the fruitwere performed in a 12 day’s intervals, from the tenth day after the flowers anthesis, to evaluate the growth curve. Based on the data, it was found that Keitt cultivar requires more days for the fruit to reach physiological maturity and greater accumulation of degree-days to complete its production cycle. The growth curves of the three varieties of fruits have a simple sigmoidal model in function of the days after anthesis.

Estimation of the risks of thermal stress due to the microclimate for manual fruit and vegetable harvesters in central Italy

Agricultural workers are exposed to various risks, including chemical agents, noise, and many other factors. One of the most characteristic and least known risk factors is constituted by the microclimatic conditions in the different phases of work (in field, in greenhouse, etc). A typical condition is thermal stress due to high temperatures during harvesting operations in open fields or in greenhouses. In Italy, harvesting is carried out for many hours during the day, mainly in the summer, with temperatures often higher than 30 degrees C. According to ISO 7243, these conditions can be considered dangerous for workers' health. The aim of this study is to assess the risks of exposure to microclimatic conditions (heat) for fruit and vegetable harvesters in central Italy by applying methods established by international standards. In order to estimate the risk for workers, the air temperature, radiative temperature, and air speed were measured using instruments in conformity with ISO 7726. Thermodynamic parameters and two more subjective parameters, clothing and the metabolic heat production rate related to the worker's physical activity, were used to calculate the predicted heat strain (PHS) for the exposed workers in conformity with ISO 7933. Environmental and subjective parameters were also measured for greenhouse workers, according to ISO 7243, in order to calculate the wet-bulb globe temperature (WBGT). The results show a slight risk for workers during manual harvesting in the field. On the other hand, the data collected in the greenhouses show that the risk for workers must not be underestimated. The results of the study show that, for manual harvesting work in climates similar to central Italy, it is essential to provide plenty of drinking water and acclimatization for the workers in order to reduce health risks. Moreover, the study emphasizes that the possible health risks for greenhouse workers increase from the month of April through July.