Annealing effects on strain and stress sensitivity of polymer optical fibre based sensors

The annealing effects on strain and stress sensitivity of polymer optical fibre Bragg grating sensors after their photo-inscription are investigated. PMMA optical fibre based Bragg grating sensors are first photo-inscribed and then they were placed into hot water for annealing. Strain, stress and force sensitivity measurements are taken before and after annealing. Parameters such as annealing time and annealing temperature are investigated. The change of the fibre diameter due to water absorption and the annealing process is also considered. The results show that annealing the polymer optical fibre tends to increase the strain, stress and force sensitivity of the photo-inscribed sensor.

Growth and characterisation of certain organic crystals

The thesis presents the results of the investigations on the crystallisation ‘behaviour, detect structure end electrical properties of certain organic crystals---phthslic snhydride end potsssiun scid phthalate Hollow crystals of phthalic snhydride were grown from vapour. the norpholog of these hollow crystals were studied in detail and s. mechanism for their growth has been proposed. A closed crystal—vapour system was used to study the basal plane growth of the whiskers and the sequential growth, observed, confirmed the mechanism suggested for hollow crystals. The dendritic crystals of phthslic enhydride were grown, both iron the melt and solution. The observed morphologies of these dendrites ere described. Bpherulites of phthalic anhydride have been grown by the artificial initiation of nucleation, from melt and solution. The variation of the substructure oi’ these spherulites with the growth tenperature wee investigated. The spherulitic filll having ribbon substructure were etched to reveal dislocations. A mechanism for the formation of the observed etch pattern has been suggested. the slip occurring in these ribbons were studied and the results are presented

VAM applied to dimensional reduction of non-linear hyperelastic plates

This work aims at dimensional reduction of non-linear isotropic hyperelastic plates in an asymptotically accurate manner. The problem is both geometrically and materially non-linear. The geometric non-linearity is handled by allowing for finite deformations and generalized warping while the material non-linearity is incorporated through hyperelastic material model. The development, based on the Variational Asymptotic Method (VAM) with moderate strains and very small thickness to shortest wavelength of the deformation along the plate reference surface as small parameters, begins with three-dimensional (3-D) non-linear elasticity and mathematically splits the analysis into a one-dimensional (1-D) through-the-thickness analysis and a two-dimensional (2-D) plate analysis. Major contributions of this paper are derivation of closed-form analytical expressions for warping functions and stiffness coefficients and a set of recovery relations to express approximately the 3-D displacement, strain and stress fields. Consistent with the 2-D non-linear constitutive laws, 2-D plate theory and corresponding finite element program have been developed. Validation of present theory is carried out with a standard test case and the results match well. Distributions of 3-D results are provided for another test case. (c) 2012 Elsevier Ltd. All rights reserved.

Caracterización dinámica del glaciar Hurd combinando observaciones de campo y simulaciones numéricas

El objetivo fundamental de esta tesis es la caracterización de la morfología y del estado de deformaciones y tensiones del Glaciar Hurd (Isla Livingston, Archipiélago de las Shetland del Sur, Antártida), mediante una combinación de observaciones de campo, registros de georradar y simulaciones numéricas. La morfología y el estado de deformaciones y tensiones actuales son la expresión de la evolución dinámica del glaciar desde tiempos pretéritos hasta recientes, y su análisis nos dará las pautas con las cuales ser capaces de predecir, con el apoyo de las simulaciones numéricas, su evolución futura. El primer aspecto que se aborda es el estudio de las estructuras que pueden observarse en la superficie del glaciar. Describimos las distintas técnicas utilizadas (medidas de campo, fotointerpretación de ortofotografías, análisis geoquímico de cenizas volcánicas, etc.) y presentamos el análisis e interpretación de los resultados morfo-estructurales, así como la correlación, mediante análisis geoquímicos (fluorescencia de rayos X), entre las cenizas volcánicas que extruyen en la superficie del Glaciar Hurd y las del volcán Decepción, origen de las cenizas. Esto nos permite realizar una datación de las mismas como Tefra 1, correspondiente a la erupción de 1970, Tefra 2, correspondiente a las erupciones pre-1829, y el conjunto Tefra 3, asociado a las erupciones más antiguas. En segundo lugar nos ocupamos de las estructuras presentes en el interior del glaciar, cuya herramienta de detección fundamental es el georradar. Identificadas estas estructuras internas, las vinculamos con las observadas en la superficie del glaciar. También hemos estudiado la estructura hidrotérmica del glaciar, obteniendo una serie de evidencias adicionales de su carácter politérmico. Entre éstas se contaban, hasta ahora, las basadas en el valor del parámetro de rigidez de la relación constitutiva del hielo determinada por ajuste de modelos dinámicos y observaciones realizados por Otero (2008) y las basadas en las velocidades de las ondas de radar en el hielo determinadas con el método de punto medio común por Navarro y otros (2009). Las evidencias adicionales que aportamos en esta tesis son: 1) la presencia de estructuras típicas de régimen compresivo en la zona terminal del glaciar y de cizalla en los márgenes del mismo, y 2) la presencia de un estrato superficial de hielo frío (por encima de otro templado) en la zona de ablación de los tres lóbulos del Glaciar Hurd –Sally Rocks, Argentina y Las Palmas–, que alcanzan espesores de 70, 50 y 40 m, respectivamente. Este estrato de hielo frío está probablemente congelado al lecho subglaciar en la zona terminal (Molina y otros, 2007; esta tesis). Por último, nos ocupamos de la simulación numérica de la dinámica glaciar. Presentamos el modelo físico-matemático utilizado, discutimos sus condiciones de contorno y cómo éstas se miden en los trabajos de campo, y describimos el procedimiento de resolución numérica del sistema de ecuaciones parciales del modelo. Presentamos los resultados para los campos de velocidades, deformaciones y tensiones, comparando estos resultados con las estructuras observadas. También incluimos el análisis de las elipses de deformación acumulativa, que proporcionan información sobre las estructuras a las que puede dar lugar la evolución del estado de deformaciones y tensiones a las que se ve sometido el hielo según avanza, lentamente, desde la cabecera hasta la zona terminal del glaciar, con tiempos de tránsito de hasta 1.250 años, recogiendo así la historia de deformaciones en el glaciar. Concluyendo, ponemos de manifiesto en esta tesis que las medidas de campo de las estructuras y niveles de cenizas, las medidas de georradar y las simulaciones numéricas de la dinámica glaciar, realizadas de forma combinada, permiten caracterizar el régimen actual de velocidades, deformaciones y tensiones del glaciar, entender su evolución en el pasado y predecir su evolución futura. ABSTRACT The main objective of this thesis is to characterize the morphology and the state of strains and stresses of Hurd Glacier (Livingston Island, South Shetland Islands archipelago, Antarctica) through a combination of field observations, ground-penetrating radar measurements and numerical simulations. The morphology and the current state of strain and stresses are the expression of the dynamic evolution of the glacier from the past to recent times, and their analysis gives us the guidelines to be able to predict, with the support of numerical simulations, its future evolution. The first subject addressed is the study of structures that can be observed on the glacier surface. We describe the different techniques used (field measurements, photointerpretation of orthophotos, geochemical analysis of volcanic ashes, etc.) and we present the analysis and interpretation of the morpho-structural results, as well as the correlation with geochemical analysis (XRF) between the volcanic ashes extruded to the surface of Hurd Glacier and those of Deception Island volcano, from which the ashes originate. This allows us dating the ashes as Tephra 1, corresponding to the 1970 eruption, Tephra 2, corresponding to the pre-1829 eruptions, and the Tephra 3 group, associated with older eruptions. Secondly we focus on the study of the structures present within the glacier, which are detected with the help of ground-penetrating radar. Once identified, we link these internal structures with those observed on the glacier surface. We also study the hydrothermal structure of the glacier, getting a series of additional evidences of its polythermal structure. Among the evidences available so far, we can mention those based on the value of the stiffness parameter of the constitutive relation of ice, determined by fitting dynamic models to observations, as done by Otero (2008), and those based on the velocity of propagation of the radar waves through the glacier ice, measured using the common midpoint method, as done by Navarro et al. (2009). The additional evidences that we provide in this thesis are: 1) the presence of structures typical of compressive regime in the terminal zone of the glacier, together with shear at its margins, and 2) the presence of a surface layer of cold ice (overlying a layer of temperate ice) in the ablation zone of the three lobes of Hurd Glacier –Sally Rocks, Argentina and Las Palmas–, reaching thicknesses of 70, 50 and 40 m, respectively. This cold layer is probably frozen to the subglacial bed in the terminal zone (Molina and others 2007; this thesis). Finally, we deal with the numerical simulation of glacier dynamics. We present the physical-mathematical model, discuss its boundary conditions and how they are measured in the field work, and describe the method of numerical solution of the model’s partial differential equations. We present the results for the velocity, strain and stress fields, comparing these results with the observed structures. We also include an analysis of the ellipses of cumulative deformation, which provide information about the structures that can result from the evolution of the strain and stress regime of the glacier ice as it moves slowly from the head to the snout of the glacier, with transit times of up to 1,250 years, so picking the history of deformation of the glacier. Summarizing, we show in this thesis that field measurements of structures and ash layers, ground-penetrating radar measurements and numerical simulations of glacier dynamics, performed in combination, allow us to characterize the current regime of velocities, strains and stresses of the glacier, to understand its past evolution and to predict its future evolution.

Strain relaxation and stress-driven interdiffusion in InAsInGaAsInP nanowires

The authors have investigated strain relaxation in InAsInGaAsInP nanowires (NW's). Transmission electron microscopy images show an additional stress field attributed to compositional modulation in the ternary layer, which disrupts NW formation and drives Ga interdiffusion into InAs, according to grazing incidence x-Ray diffraction under anomalous scattering conditions. The strain profile along the NW, however, is not significantly affected when interdiffusion is considered. Results show that the InAs NW energetic stability is preserved with the introduction of ternary buffer layer in the structure. © 2007 American Institute of Physics.

New stress and velocity fields for highly frictional granular materials

The idealised theory for the quasi-static flow of granular materials which satisfy the Coulomb-Mohr hypothesis is considered. This theory arises in the limit that the angle of internal friction approaches $\pi/2$, and accordingly these materials may be referred to as being `highly frictional'. In this limit, the stress field for both two-dimensional and axially symmetric flows may be formulated in terms of a single nonlinear second order partial differential equation for the stress angle. To obtain an accompanying velocity field, a flow rule must be employed. Assuming the non-dilatant double-shearing flow rule, a further partial differential equation may be derived in each case, this time for the streamfunction. Using Lie symmetry methods, a complete set of group-invariant solutions is derived for both systems, and through this process new exact solutions are constructed. Only a limited number of exact solutions for gravity driven granular flows are known, so these results are potentially important in many practical applications. The problem of mass flow through a two-dimensional wedge hopper is examined as an illustration.

Families of asymptotic tensile crack tip stress fields in elastic-perfectly plastic single crystals

In this work, two families of asymptotic near-tip stress fields are constructed in an elastic-ideally plastic FCC single crystal under mode I plane strain conditions. A crack is taken to lie on the (010) plane and its front is aligned along the [(1) over bar 01] direction. Finite element analysis is first used to systematically examine the stress distributions corresponding to different constraint levels. The general framework developed by Rice (Mech Mater 6:317-335, 1987) and Drugan (J Mech Phys Solids 49:2155-2176, 2001) is then adopted to generate low triaxiality solutions by introducing an elastic sector near the crack tip. The two families of stress fields are parameterized by the normalized opening stress (tau(A)(22)/tau(o)) prevailing in the plastic sector in front of the tip and by the coordinates of a point where elastic unloading commences in stress space. It is found that the angular stress variations obtained from the analytical solutions show good agreement with finite element analysis.

Examination of Stress-Fields In Elastic Plastic Indentation

A block of high-purity copper was indented by a 120-degrees diamond-tipped cone. Strain gauges were placed on the surface to measure the radial strains at different surface locations, during loading as well as unloading. The competence of three stress fields proposed for elastic-plastic indentation is assessed by comparing the predicted surface radial strains with those experimentally observed.

Cement stabilised rammed earth. Part B: compressive strength and stress-strain characteristics

Strength and behaviour of cement stabilised rammed earth (CSRE) is a scantily explored area. The present study is focused on the strength and elastic properties of CSRE. Characteristics of CSRE are influenced by soil composition, density of rammed earth, cement and moisture content. The study is focused on examining (a) role of clay content of the soil on strength of CSRE and arriving at optimum clay fraction of the soil mix, (b) influence of moisture content, cement content and density on strength and (c) stress-strain relationships and elastic properties for CSRE. Major conclusions are (a) there is considerable difference between dry and wet compressive strength of CSRE and the wet to dry strength ratio depends upon the clay fraction of soil mix and cement content, (b) optimum clay fraction yielding maximum compressive strength for CSRE is about 16%, (c) strength of CSRE is highly sensitive to density and for a 20% increase in density the strength increases by 300-500% and (d) in dry state the ultimate strain at failure for CSRE is as high as 1.5%, which is unusual for brittle materials.

Electrical and magneto-resistance of Co/CNT/epoxy thin film for strain and magnetic field sensing

Cobalt and iron nanoparticles are doped in carbon nanotube (CNT)/polymer matrix composites and studied for strain and magnetic field sensing properties. Characterization of these samples is done for various volume fractions of each constituent (Co and Fe nanoparticles and CNTs) and also for cases when only either of the metallic components is present. The relation between the magnetic field and polarization-induced strain are exploited. The electronic bandgap change in the CNTs is obtained by a simplified tight-binding formulation in terms of strain and magnetic field. A nonlinear constitutive model of glassy polymer is employed to account for (1) electric bias field dependent softening/hardening (2) CNT orientations as a statistical ensemble and (3) CNT volume fraction. An effective medium theory is then employed where the CNTs and nanoparticles are treated as inclusions. The intensity of the applied magnetic field is read indirectly as the change in resistance of the sample. Very small magnetic fields can be detected using this technique since the resistance is highly sensitive to strain. Its sensitivity due to the CNT volume fraction is also discussed. The advantage of this sensor lies in the fact that it can be molded into desirable shape and can be used in fabrication of embedded sensors where the material can detect external magnetic fields on its own. Besides, the stress-controlled hysteresis of the sample can be used in designing memory devices. These composites have potential for use in magnetic encoders, which are made of a magnetic field sensor and a barcode.