1000 resultados para Sistemas Binários
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A preservação e o armazenamento de células e tecidos têm sido utilizados largamente em pesquisa científica e aplicações clínicas. No entanto, há uma aparente contradição entre o conceito de preservaão e as conclusões baseadas em resultados experimentais que materiais biológicos criopreservados podem ser danificados pelo próprio processo de preservação. A compreensão do processo de solidificação de soluções salinas é fundamental para a proposição de novos protocolos de criopreservação. No presente estudo, o congelamento de uma solução de cloreto de sódio a 1% em massa é simulado. As equações de conservação de massa, momentum, energia, e espécies químicas foram discretizadas e resolvidas numericamente utilizando-se o método dos volumes de controle para um domínio bidimensional que contém a parede da bolsa plástica e a solução salina. A perda de água da célula foi calculada a partir da história de temperatura e concentração durante o processo de solidificação e verificou-se que, dependendo da posição inicial da célula na bolsa, a célula tem probabilidades diferentes de sobreviver durante o processo.
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In this work is presented a new method for the determination of the orbital period (Porb) of eclipsing binary systems based on the wavelet technique. This method is applied on 18 eclipsing binary systems detected by the CoRoT (Convection Rotation and planetary transits) satellite. The periods obtained by wavelet were compared with those obtained by the conventional methods: box Fitting (EEBLS) for detached and semi-detached eclipsing binaries; and polynomial methods (ANOVA) for contact binary systems. Comparing the phase diagrams obtained by the different techniques the wavelet method determine better Porb compared with EEBLS. In the case of contact binary systems the wavelet method shows most of the times better results than the ANOVA method but when the number of data per orbital cicle is small ANOVA gives more accurate results. Thus, the wavelet technique seems to be a great tool for the analysis of data with the quality and precision given by CoRoT and the incoming photometric missions.
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On this study we have revisited the predicted tidal circularization theory in close binary systems with a evolved component. Close binaries suffer tidal interactions that tend to synchronize periods and circularize the orbits (Zahn 1977, 1989, 1992). According to Zahn s theory we compute the integral that give us the variation of the eccentricity in a binary under the influence of tidal force and we compare the integral results with new observations for 260 binary systems with orbital solutions. Our results confirm the success of the Zahn s theory with a new data and new stellar evolutionary models, on the other hand, our results points to the need for a better description of the role of convection on this theory
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One of the best established properties of the single late type evolved stars is that their rotational velocity and lithium content decrease with effective temperature and age. Nevertheless, the root cause of this property, as well as the link between rotation and lithium abundance and, in particular, the effects of binarity on rotation and lithium content in binary systems with evolved component, are not yet completely established. How does the gravitational tides, in binary systems, affects rotational evolution and lithium dilution? Trying to answer these questions, we have carried out an observational survey, in the lithium region centered at the lithium I line A6707.81A, for a large sample of about 100 binary systems with evolved component along the spectral range F, G and K, with the CES spectrometer mounted at the CAT 1.44 m Telescope of the ESO, La Silla, Chile. By combining the abundances of lithium issued from these observations with rotational velocity and orbital parameters, we have found a number of important results. First of all, we confirm that in this class of binary systems rotation is effectively affected by tidal effects. Binary systems with orbital period lower than about 100 days and circular or nearly circular orbits, present rotational velocity enhanced in relation to the single giant stars and to the binary systems with an orbital period larger than 100 days. This is clearly the result of the synchonization between the rotational and orbital motions due to tidal effects. In addition, we have found that lithium abundances in binary systems with giant components present the same gradual decreasing with effective temperature, observed in the single giants of same luminosity class and spectral types. We have found no lithium-rich binary systems, in contrast with single giants. A remarkable result from the present study is the one showing that synchronized binary systems with giant component retains more of their original lithium than the unsynchronized systems. In fact, we have found a possible "inhibited zone", in which synchronized binary systems with giant component having lithium abundance lower than a threshold level should be unusual. Finally, the present study also shows that the binary systems with giant component presenting the highest lithium contents are those with the highest rotation rates
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Sistemas binários e ternários envolvendo cobre (II) e benzalpiruvatos. Equilíbrios em solução aqöosa
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The discovery of giant stars in the spectral regions G and K, showing moderate to rapid rotation and single behavior, namely with constant radial velocity, represents one important topic of study in Stellar Astrophysics. Indeed, such anomalous rotation clearly violates the theoretical predictions on the evolution of stellar rotation, since in evolved evolutionary stages is expected that the single stars essentially have low rotation due to the evolutionary expansion. This property is well-established from the observational point of view, with different studies showing that for single giant stars of spectral types G and K values of the rotation are typically smaller than 5kms−1 . This Thesis seeks an effective contribution to solving the paradigm described above, aiming to search for single stars of spectral types G and K with anomalous rotation, tipically rotation of moderate to rapid, in other luminosity classes. In this context, we analyzed a large stellar sample consisting of 2010 apparently single stars of luminosity classes IV, III, II and Ib with spectral types G and K, with rotational velocity v sin i and radial velocity measurements obtained from observations made by CORAVEL spectrometers. As a first result of impact we discovered the presence of anomalous rotators also among subgiants, bright giants and supergiants stars, namelly stars of luminosity classes IV, II and Ib, in contrast to previous studies, that reported anomalous rotators only in the luminosity class III classic giants. Such a finding of great significance because it allows us to analyze the presence of anomalous rotation at different intervals of mass, since the luminosity classes considered here cover a mass range between 0.80 and 20MJ, approximately. In the present survey we discovered 1 subgiant, 9 giants, 2 bright giants and 5 Ib supergiants, in spectral regions G and K, with values of v sin i ≥ 10kms−1 and single behavior. This amount of 17 stars corresponds to a frequency of 0.8% of G and K single evolved stars with anomalous rotation in the mentioned classes of luminosities, listed at the Bright Star Catalog, which is complete to visual magnitude 6.3. Given these new findings, based on a stellar sample complete in visual magnitude, as that of the Bright Star Catalog, we conducted a comparative statistical analysis using the Kolmogorov- Smirnov test, from where we conclude that the distributions of rotational velocity, v sin i, for single evolved stars with anomalous rotation in luminosity classes III and II, are similar to the distributions of v sin i for spectroscopic binary systems with evolved components with the same spectral type and luminosity class. This vii result indicates that the process of coalescence between stars of a binary system might be a possible mechanism to explain the observed abnormal rotation in the referred abnormal rotators, at least among the giants and bright giants, where the rotation in excess would be associated with the transfer of angular momentum for the star resulting from the merger. Another important result of this Thesis concerns the behavior of the infrared emission in most of the stars with anomalous rotation here studied, where 14 stars of the sample tend to have an excess in IR compared with single stars with low rotation, within of their luminosity class. This property represents an additional link in the search for the physical mechanisms responsible for the abnormal observed rotation, since recent theoretical studies show that the accretion of objects of sub-stellar mass, such as brown dwarfs and giant planets, by the hosting star, can significantly raise its rotation, producing also a circumstellar dust disk. This last result seems to point in that direction, since it is not expected that dust disks occurring during the stage of star formation can survive until the stages of subgiants, giants and supergiants Ib. In summary, in this Thesis, besides the discovery of single G and K evolved stars of luminosity classes IV, II and Ib with anomalously high rotation compared to what is predicted by stellar evolution theory, we also present the frequency of these abnormal rotators in a stellar sample complete to visual magnitude 6.3. We also present solid evidence that coalescence processes in stellar binary systems and processes of accretion of brown dwarfs star or giant planets, by the hosting stars, can act as mechanisms responsible for the puzzling phenomenon of anomalous rotation in single evolved stars.
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Binary systems are key environments to study the fundamental properties of stars. In this work, we analyze 99 binary systems identified by the CoRoT space mission. From the study of the phase diagrams of these systems, our sample is divided into three groups: those whose systems are characterized by the variability relative to the binary eclipses; those presenting strong modulations probably due to the presence of stellar spots on the surface of star; and those whose systems have variability associated with the expansion and contraction of the surface layers. For eclipsing binary stars, phase diagrams are used to estimate the classification in regard to their morphology, based on the study of equipotential surfaces. In this context, to determine the rotation period, and to identify the presence of active regions, and to investigate if the star exhibits or not differential rotation and study stellar pulsation, we apply the wavelet procedure. The wavelet transform has been used as a powerful tool in the treatment of a large number of problems in astrophysics. Through the wavelet transform, one can perform an analysis in time-frequency light curves rich in details that contribute significantly to the study of phenomena associated with the rotation, the magnetic activity and stellar pulsations. In this work, we apply Morlet wavelet (6th order), which offers high time and frequency resolution and obtain local (energy distribution of the signal) and global (time integration of local map) wavelet power spectra. Using the wavelet analysis, we identify thirteen systems with periodicities related to the rotational modulation, besides the beating pattern signature in the local wavelet map of five pulsating stars over the entire time span.
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Binary systems are key environments to study the fundamental properties of stars. In this work, we analyze 99 binary systems identified by the CoRoT space mission. From the study of the phase diagrams of these systems, our sample is divided into three groups: those whose systems are characterized by the variability relative to the binary eclipses; those presenting strong modulations probably due to the presence of stellar spots on the surface of star; and those whose systems have variability associated with the expansion and contraction of the surface layers. For eclipsing binary stars, phase diagrams are used to estimate the classification in regard to their morphology, based on the study of equipotential surfaces. In this context, to determine the rotation period, and to identify the presence of active regions, and to investigate if the star exhibits or not differential rotation and study stellar pulsation, we apply the wavelet procedure. The wavelet transform has been used as a powerful tool in the treatment of a large number of problems in astrophysics. Through the wavelet transform, one can perform an analysis in time-frequency light curves rich in details that contribute significantly to the study of phenomena associated with the rotation, the magnetic activity and stellar pulsations. In this work, we apply Morlet wavelet (6th order), which offers high time and frequency resolution and obtain local (energy distribution of the signal) and global (time integration of local map) wavelet power spectra. Using the wavelet analysis, we identify thirteen systems with periodicities related to the rotational modulation, besides the beating pattern signature in the local wavelet map of five pulsating stars over the entire time span.
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Pressão interna, volume livre, refração molar e propriedades termodinâmicas de excesso de misturas líquidas binárias de dimetil sulfóxido + tiofeno e dimetil sulfóxido + piridina a 298.15K foram calculadas a partir de medidas experimentais de densidades, tensão superficial e índice de refração. A relação entre a pressão interna, volume molar de excesso, refração molar, e a interação molecular dos sistemas binários é examinada.
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A solubilidade de compostos pesados em fase gasosa contendo um componente supercrítico (equilíbrio sólido-gás) foi analisada, adotando-se a equação de estado de Peng-Robinson para representar os sistemas sólido-gás estudados. A modelagem foi aplicada para vários sistemas binários (monossólido/monossolvente) e multissólido/multissolvente. Para cada sistema, fez-se a estimação dos parâmetros pertinentes, os parâmetros de interação binária, obtidos por regressão não linear a partir dos dados experimentais de equilíbrio sólido-gás correspondentes. Tendo como base os dados binários, foi realizada uma análise de seletividade/ capacidade de sistemas do tipo 2 sólidos-1solvente, comparando-os com dados experimentais, e fez-se a comparação com os sistemas ternários experimentais.
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In the present work are established initially the fundamental relationships of thermodynamics that govern the equilibrium between phases, the models used for the description of the behavior non ideal of the liquid and vapor phases in conditions of low pressures. This work seeks the determination of vapor-liquid equilibrium (VLE) data for a series of multicomponents mixtures of saturated aliphatic hydrocarbons, prepared synthetically starting from substances with analytical degree and the development of a new dynamic cell with circulation of the vapor phase. The apparatus and experimental procedures developed are described and applied for the determination of VLE data. VLE isobarics data were obtained through a Fischer s ebulliometer of circulation of both phases, for the systems pentane + dodecane, heptane + dodecane and decane + dodecane. Using the two new dynamic cells especially projected, of easy operation and low cost, with circulation of the vapor phase, data for the systems heptane + decane + dodecane, acetone + water, tween 20 + dodecane, phenol + water and distillation curves of a gasoline without addictive were measured. Compositions of the equilibrium phases were found by densimetry, chromatography, and total organic carbon analyzer. Calibration curves of density versus composition were prepared from synthetic mixtures and the behavior excess volumes were evaluated. The VLE data obtained experimentally for the hydrocarbon and aqueous systems were submitted to the test of thermodynamic consistency, as well as the obtained from the literature data for another binary systems, mainly in the bank DDB (Dortmund Data Bank), where the Gibbs-Duhem equation is used obtaining a satisfactory data base. The results of the thermodynamic consistency tests for the binary and ternary systems were evaluated in terms of deviations for applications such as model development. Later, those groups of data (tested and approved) were used in the KijPoly program for the determination of the binary kij parameters of the cubic equations of state original Peng-Robinson and with the expanded alpha function. These obtained parameters can be applied for simulation of the reservoirs petroleum conditions and of the several distillation processes found in the petrochemistry industry, through simulators. The two designed dynamic cells used equipments of national technology for the determination of VLE data were well succeed, demonstrating efficiency and low cost. Multicomponents systems, mixtures of components of different molecular weights and also diluted solutions may be studied in these developed VLE cells
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In the present work are established initially the fundamental relationships of thermodynamics that govern the equilibrium between phases, the models used for the description of the behavior non ideal of the liquid and vapor phases in conditions of low pressures. This work seeks the determination of vapor-liquid equilibrium (VLE) data for a series of multicomponents mixtures of saturated aliphatic hydrocarbons, prepared synthetically starting from substances with analytical degree and the development of a new dynamic cell with circulation of the vapor phase. The apparatus and experimental procedures developed are described and applied for the determination of VLE data. VLE isobarics data were obtained through a Fischer's ebulliometer of circulation of both phases, for the systems pentane + dodecane, heptane + dodecane and decane + dodecane. Using the two new dynamic cells especially projected, of easy operation and low cost, with circulation of the vapor phase, data for the systems heptane + decane + dodecane, acetone + water, tween 20 + dodecane, phenol + water and distillation curves of a gasoline without addictive were measured. Compositions of the equilibrium phases were found by densimetry, chromatography, and total organic carbon analyzer. Calibration curves of density versus composition were prepared from synthetic mixtures and the behavior excess volumes were evaluated. The VLE data obtained experimentally for the hydrocarbon and aqueous systems were submitted to the test of thermodynamic consistency, as well as the obtained from the literature data for another binary systems, mainly in the bank DDB (Dortmund Data Bank), where the Gibbs-Duhem equation is used obtaining a satisfactory data base. The results of the thermodynamic consistency tests for the binary and ternary systems were evaluated in terms of deviations for applications such as model development. Later, those groups of data (tested and approved) were used in the KijPoly program for the determination of the binary kij parameters of the cubic equations of state original Peng-Robinson and with the expanded alpha function. These obtained parameters can be applied for simulation of the reservoirs petroleum conditions and of the several distillation processes found in the petrochemistry industry, through simulators. The two designed dynamic cells used equipments of national technology for the determination Humberto Neves Maia de Oliveira Tese de Doutorado PPGEQ/PRH-ANP 14/UFRN of VLE data were well succeed, demonstrating efficiency and low cost. Multicomponents systems, mixtures of components of different molecular weights and also diluted solutions may be studied in these developed VLE cells
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Pós-graduação em Ciências Farmacêuticas - FCFAR
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Para misturas nas quais existem interações entre moléculas diferentes aparece um parâmetro energético de interação ajustável na relação das variáveis. As grandezas termodinâmicas de excesso dão informação qualitativa dos possíveis tipos de interação. Duas grandezas importantes neste sentido são o volume de excesso e a entalpia de excesso. Neste artigo se estudam diferentes métodos, regressão com mínimos quadrados e por minimização do valor absoluto e relativo dos resíduos, para determinar a possibilidade de aplicação dos mesmos no cálculo de parâmetros de interação molecular em modelos termodinâmicos de soluções. Usam-se dados experimentais de volume molar de excesso para todo o intervalo de frações molares de 10 sistemas binários formados por acetonitrila + um álcool primário (do metanol ao n-decanol). Comparam-se os valores calculados e os dados experimentais das grandezas, e são feitas análises dos resultados.