Apuntes biográficos del Sr. D. Felipe Senillosa,

Mode of access: Internet.

Bromination of Intermolecular Chelate Linkage Isomers of 3-Oximino-4,9-Dimethyl (or 4,7,9-Trimethyl)-5,8-Diazadodeca-4,8-Diene-2,11-Dionato Nickel(II)

The reaction of the title complexes (FIG. 1) with N-bromosuccinimide or bromine in chloroform yields isomeric bromo complexes on substitution of the γ-CH carbon proton by bromine. The brominated products have been characterised by ir, pmr, electronic absorption spectra, conductivity and magnetic susceptibility measurements. The linkage isomerisation of the brominated products in chloroform has been shown to depend on the diamine residue.

On the synthesis and structures of the complexes [RuCl(L)(dppb)(N-N)]PF(6) (L = CO, py or 4-NH(2)py; dppb=1,4-bis(diphenylphosphino)butane; N-N=2,2 `-bipyridine or 1,10-phenanthroline) and [(dppb)(CO)Cl(2)-Ru-pz-RuCl(2)(CO)(dppb)] (pz = pyrazine)

The ""Ru(P-P)"" unit (P-P = diphosphine) is recognized to be an important core in catalytic species for hydrogenation of unsaturated organic substrates. Thus, in this study we synthesized six new complexes containing this core, including the binuclear complex [(dppb)(CO)Cl(2)Ru-pz-RuCl(2)(CO)(dPPb)] (pz = pyrazine) which can be used as a precursor for the synthesis of cationic carbonyl species of general formula [RuCl(CO)(dppb)(N-N)]PF(6) (N-N = diimine). Complexes with the formula (RuCl(py)(dppb)(N-N)]PF(6) were synthesized by exhaustive electrolysis of these carbonyl compounds or from the precursors [RuCl(2)(dppb)(N-N)]. The new complexes were characterized by microanalysis, conductivity measurements, IR and (31)P{(1)H)} NMR spectroscopy, cyclic voltammetry and X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

Modulation of trans-to-cis photoisomerization and photoluminescence of 1,2-bis(4-pyridyl)ethylene or 4-styrylpyridine coordinated to fac-tricarbonyl(5-chloro-1,10-phenathroline)rhenium(I)

Photochemical and photophysical properties of fac-[Re(CO)(3)(Clphen)(trans-L)](+) complexes, Clphen = 5-chloro-1,10-phenathroline and L = 1,2-bis(4-pyridyl)ethylene, bpe, or 4-styrylpyridine, stpy, were investigated to complement the understanding of intramolecular energy transfer process in tricarbonyl rhenium(I) complexes having an electron withdrawing group attached to polypyridyl ligands. These new compounds were synthesized, characterized and the photoisomerization quantum yields were accurately determined by (1)H NMR spectroscopy. The true quantum yields for fac-[Re(CO)(3)(Clphen) (trans-bpe)](+) were constant (Phi = 0.55) at all investigated irradiation wavelengths. However, for fac-[Re(CO)(3)(Clphen)(trans-stpy)](+), similar true quantum yields were observed only at higher energy irradiation (Phi(313 nm) = 0.53 and Phi(365 nm) = 0.57), but it decreased significantly at 404 nm (Phi = 0.41). These results indicated different deactivation pathways for the trans-stpy complex photoisomerization. Quantum yields decreased as the (3)IL(trans-L) and (3)MLCT(Re -> NN) excited states become closer and the behavior was discussed in terms of the excited state energy gaps. Additionally, luminescence properties of photoproducts, fac-[Re(CO)(3)(Clphen)(cis-L)](+), were also investigated in different environments to analyze the relative energy of the (3)MLCT(Re -> Clphen) excited state for each compound. (C) 2011 Elsevier B.V. All rights reserved.

Kitāb Mukālamāt ʻArabīyah : manuscript, [ca. 1783]

المقالة الأولى في حروف العربية ووضعهم في الكلام أول ذلك علىيد اليمين على جانب الشمال... :Incipit

Kitāb Sawāṭiʻ al-anwār fī maʻrifat awqāt al-ṣalawāt wa-al-asḥār / min taʼlīf al-Fāḍil al-Kāmil Mawlawī Muḥammad Ghawth : manuscript, 1873 or 4

According to the colophon (f. 68v), copy completed in 1290 AH [1873 or 74 AD].

Hādhā Risālah fī ṣadāq Sayyidatinā Fāṭimah al-Zahrāʼ bint Sayyid al-Mursalīn / lil-Fāḍil al-ʻAllāmah Imām al-ʻulamāʼ Mawlawī Ṣibghat Allāh Qāḍī al-Mulk : manuscript, 1863 or 4

Title from f. 1r.

Zafer-nâme / li-Karaçelebizade Abdülaziz Efendi : manuscript, 1723 or 4

A historical account of the Yerevan and Baghdad campaigns of Murād IV (r. 1623-1640). Composed in eight chapters. Book begins in 1044 AH [1635 AD] with the army setting out from Üsküdar and ends in 1049 AH [1640 AD] with the sultna's return to Istanbul after conclusion of Kasrışirin Treaty.

Risale-yi hüsn-i hat : manuscript, 1603 or 4

Written in one column, 9 lines per page, in black and red. First ten leaves framed within one golden line (ff. 1r-10v).

Hādhā Risālah fī bayān ḥadīth ikhtilāf al-ummah / min al-Fāḍil al-ʻAllāmah Imām al-ʻulamāʼ Mawlawī Ṣibghat Allāh Qāḍī al-Mulk : manuscript, 1863 or 4

Title from f. 13r.

Tariff; or, Rates of duties payable on goods ... imported into the U.S. of America after the 3d of March 1833 ...

Mode of access: Internet.

Hādhihi Ḥāshiyat al-ʻālim al-himām wa-al-ʻallāmah al-Imām al-Shaykh Ibrāhīm al-Bājūrī ʻalá matn al-Shamāʼil al-Muḥammadīyah ʻalá ṣāḥibihā afḍal al-ṣalāh wa-azká al-taḥīyah lil-Imām al-muḥaqqiq wa-al-muḥaddith al-mudaqqiq Muḥammad ibn ʻĪsá al-Tirmidhī.

Mode of access: Internet.

Ḥāshiyat ... Ibrāhīm al-Bājūrī al-musammāh bi-al-Mawāhib al-ladunīyah ʻalá al-Shamāʼil al-Muḥammadīyah [microform] /

Caption title.