Interplay Between Structure, Stoichiometry, and Electron Transfer Dynamics in SILAR-based Quantum Dot-Sensitized Oxides

We quantify the rate and efficiency of picosecond electron transfer (ET) from PbS nanocrystals, grown by successive ionic layer adsorption and reaction (SILAR), into a mesoporous SnO2 support. Successive SILAR deposition steps allow for stoichiometry- and size-variation of the QDs, characterized using transmission electron microscopy. Whereas for sulfur-rich (p-type) QD surfaces substantial electron trapping at the QD surface occurs, for lead-rich (n-type) QD surfaces, the QD trapping channel is suppressed and the ET efficiency is boosted. The ET efficiency increase achieved by lead-rich QD surfaces is found to be QD-size dependent, increasing linearly with QD surface area. On the other hand, ET rates are found to be independent of both QD size and surface stoichiometry, suggesting that the donor–acceptor energetics (constituting the driving force for ET) are fixed due to Fermi level pinning at the QD/oxide interface. Implications of our results for QD-sensitized solar cell design are discussed.

Non-Destructive Evaluation of Ion-Implanted Semiconductor Thin Films Using Photothermal Deflections Spectroscopy

Materials and equipment which fail to achieve the design requirements or projected life due to undetected defects may require expensive repair or early replacement. Such defects may also be the cause of unsafe conditions or catastrophic unexpected failure, and will lead to loss of revenue due to plant shutdown. Non-Destructive Evaluation (NDE) / Non Destructive Testing (NDT) is used for the examination of materials and components without changing or destroying their usefulness. NDT can be applied to each stage of a system’s construction, to monitor the integrity of the system or structure throughout its life.

Carbon nanostructure based electrodes for high efficiency dye sensitized solar cell

Synthesis and functionalization of large-area graphene and its structural, electrical and electrochemical properties has been investigated. First, the graphene films, grown by thermal chemical vapor deposition (CVD), contain three to five atomic layers of graphene, as confirmed by Raman spectroscopy and high-resolution transmission electron microscopy. Furthermore, the graphene film is treated with CF4 reactive-ion plasma to dope fluorine ions into graphene lattice as confirmed by X-ray photoelectron spectroscopy (XPS) and UV-photoemission spectroscopy (UPS). Electrochemical characterization reveals that the catalytic activity of graphene for iodine reduction enhanced with increasing plasma treatment time, which is attributed to increase in catalytic sites of graphene for charge transfer. The fluorinated graphene is characterized as a counter-electrode (CE) in a dye-sensitized solar cell (DSSC) which shows ~ 2.56% photon to electron conversion efficiency with ~11 mAcm−2 current density. Second, the large scale graphene film is covalently functionalized with HNO3 for high efficiency electro-catalytic electrode for DSSC. The XPS and UPS confirm the covalent attachment of C-OH, C(O)OH and NO3- moieties with carbon atoms through sp2-sp3 hybridization and Fermi level shift of graphene occurs under different doping concentrations, respectively. Finally, CoS-implanted graphene (G-CoS) film was prepared using CVD followed by SILAR method. The G-CoS electro-catalytic electrodes are characterized in a DSSC CE and is found to be highly electro-catalytic towards iodine reduction with low charge transfer resistance (Rct ~5.05 Ωcm 2) and high exchange current density (J0~2.50 mAcm -2). The improved performance compared to the pristine graphene is attributed to the increased number of active catalytic sites of G-CoS and highly conducting path of graphene. We also studied the synthesis and characterization of graphene-carbon nanotube (CNT) hybrid film consisting of graphene supported by vertical CNTs on a Si substrate. The hybrid film is inverted and transferred to flexible substrates for its application in flexible electronics, demonstrating a distinguishable variation of electrical conductivity for both tension and compression. Furthermore, both turn-on field and total emission current was found to depend strongly on the bending radius of the film and were found to vary in ranges of 0.8 - 3.1 V/μm and 4.2 - 0.4 mA, respectively.

Fabrication and characterization of a nanostructured TiO2/In2S3-Sb2S3/CuSCN extremely thin absorber (eta) solar cell

CuSCN extremely thin absorber solar cell. Nanostructured TiO2 deposited by screen printing on an ITO substrate was used as an n-type electrode. An ∼80 nm extremely thin layer of the system In2S3-Sb2S3 deposited by successive ionic layer adsorption and a reaction (silar) method was used as an absorber. The voids were filled with p-type CuSCN and the entire assembly was completed with a gold contact. The solar cell fabricated with this heterostructure showed an energy conversion efficiency of 4.9%, which is a promising result in the development of low cost and simple fabrication of solar cells.

Arquiteturas do trigo: espaços de silagem no Alentejo, do século XIX à atualidade

O presente trabalho de investigação apresenta um estudo sistemático da expressão arquitetónica que teve na região do Alentejo a implantação agro-industrial da cultura do trigo, em especial, durante a "Campanha do Trigo", iniciada em 1929 e prosseguida durante o Estado Novo, até 1969. Para tanto, procede ao mapeamento dos elementos edificados, em ligação com os processos de produção, silagem e moagem industrial do trigo, bem como ao seu transporte, estabelecendo uma análise comparativa com outras regiões e países, com o intuito de revelar o impacto destes equipamentos nos diversos territórios e paisagens. Assim, procura-se compreender as relações que se estabeleceram entre a forma arquitetónica do silo (cujo desenho resulta fundamentalmente de uma resposta programática intrinsecamente ligada à sua função primordial - armazenamento do cereal) e os lugares, onde se implantaram e com os quais se procuraram articular, e as paisagens, com as quais perspetivaram dialogar. Para tal, procede-se a descrição do estado atual de cada exemplar das denominadas "arquiteturas do trigo", com o objetivo de gerar, num primeiro nível, o entendimento de cada caso em particular e, posteriormente, estabelecer, por efeito de comparação, um confronto, quer entre os diferentes contextos em que se inserem, quer entre as suas caraterísticas formais, de modo a tirar ilações que possibilitem problematizar o seu uso futuro, equacionando diferentes perspetivas de atuação sobre o edificado. Finalmente procura-se introduzir uma discussão segundo diferentes orientações e posicionamentos, de modo a invocar perspetivas de atuação sobre os silos, que se adequem a cada situação específica, a cada contexto e a cada lugar. É no confronto entre as abordagens enunciadas, que se evidencia, mais do que a pertinência, a emergência social e cultural de uma ação diligente, quer ao nível particular de cada peça silar, quer do sistema, do qual era parte integrante a linha de caminho de ferro, que através do seu traçado permitia interligar todas as peças silares e garantir o seu funcionamento a escala industrial; ABSTRACT: This research presents a systematic study of architectural expression of wheat crop agro-industrial development, in particular the "Wheat Campaign", started in 1929 and continue during the "New State", until 1969. We first proceed to map the built elements related to production processes, silage and wheat industrial grinding, as well as the ways of transportation, establishing a comparative analysis with other countries and regions, in order to reveal the impact of these objects in various territories and landscapes. We seek to understand the relationships between the architectural form of the silo (whose design is mainly a result of an intrinsically programmatic response linked to its primary function - cereal storage) and the places where they are implemented and the landscapes which they sought to communicate and articulate. Secondly, we describe the current status of each copy of the "wheat architectures" in Alentejo, with the main objective of attain, at first, the understanding of each particular case and, then, to establish a connection between the different contexts in which they operate and their formal characteristics, in order to conceive and discuss their future use, equating different perspectives of action in the buildings. Finally seeks to introduce a discussion according to different orientations and positions in order to invoke prospects for action on the grain elevators that are appropriate to each specific situation, every context and every place. It is the clash between the stated approaches, which shows more than the relevance, it shows social and cultural emergence of a diligent action on the particular level of each grain elevator on the system, which was an integral part of the railway, which through its tracing allowed to interconnect all grain elevators and assure its operation on an industrial scale