Protactinium���试管壁上的吸附

用~(233)Pa做示踪剂,分别使用ABS树脂、有机玻璃、聚乙烯和普通玻璃试管做吸附材料,研究了在不同浓度的HCL溶液中~(233)Pa在试管壁上的吸附。结果显示,~(233)Pa在试管壁上的吸附随盐酸浓度的增加而减少。当HCL浓度≥0．5mol/L时,同ABS树脂和有机玻璃比较,~(233)Pa在玻璃试管壁上的吸附最少。当HCL浓度≤0．25mol/L时,~(233)Pa在玻璃试管壁上的吸附反而比在ABS树脂和有机玻璃试管壁上的大。若~(233)Pa的HCL溶液在聚乙烯、ABS树脂和玻璃试管中存放较长的时间(24h),聚乙烯试管壁对~(233)Pa的吸附量最少。

Solvent extraction study of protactinium(V) with methyl-iso-butyl carbinol and methyl-iso-butyl ketone

In order to study the extraction pattern of protactinium in different types of extracting agents and compare the similarity of patterns of extraction with dubnium and thereby unraveling its chemistry, solvent extraction of protactinium(V) with methyl-iso-butyl carbinol (MIBC) and methyl-iso-butyl ketone (MIBK) was studied using Pa-233 as a radiotracer. The extraction efficiencies of Pa were determined as a function of shaking time, concentrations of mineral acids, and extractant concentrations using the two extractants. The results show that MIBK is more suitable for the extraction of protactinium than MIBC in benzene. Furthermore, the effect of the F anion is also discussed.

Liquid-liquid extraction of protactinium(V) using tri-iso-octylamine

Solvent extraction of protactinium with tri-iso-octyl-amine (TIOA) in xylene, benzene, carbon tetrachloride and chloroform from HCl, HF, HNO3, HClO4 and H2SO4 media was studied using Pa-233 as a radiotracer. The extraction efficiencies of protactinium were determined as a function of shaking time, concentrations of mineral acids in aqueous phase, extractant concentrations and diluents in organic phase. The extraction mechanism was discussed. The results show that the extracted species in the organic phase is [(R3N-H)(n)Pa(OH)(x)Cl-y(5-x-y)].

Beryllium, thorium and protactinium isotope ratios in sediments from the Galapagos microplate

Biogenic particle fluxes from highly productive surface waters, boundary scavenging, and hydrothermal activity are the main factors influencing the deposition of radionuclides in the area of the Galapagos microplate, eastern Equatorial Pacific. In order to evaluate the importance of these three processes throughout the last 100 kyr, concentrations of the radionuclides 10Be, 230Th, and 231Pa, and of Mn and Fe were measured at high resolution in sediment samples from two gravity cores KLH 068 and KLH 093. High biological productivity in the surface waters overlying the investigated area has led to 10Be and 231Pa fluxes exceeding production during at least the last 30 kyr and probably the last 100 kyr. However, during periods of high productivity at the up welling centers off Peru and extension of the equatorial high-productivity zone, a relative loss of 10Be and 231Pa may have occurred in these sediment cores because of boundary scavenging. The effects of hydrothermal activity were investigated by comparing the 230Thex concentrations to the Mn/Fe ratios and by comparing the fluxes of 230Th and 10Be which exceed production. The results suggest an enhanced hydrothermal influence during isotope stages 4 and 5 and to a lesser extent during isotope stage 1 in core KLH 093. During isotope stages 2 and 3, the hydrothermal supply of Mn was deposited elsewhere, probably because of changes in current regime or deep water oxygenation. A strong increase of the Mn/Fe ratio at the beginning of climatic stage 1 which is not accompanied by an increase of the 230Thex concentration is interpreted to be an effect of Mn remobilization and reprecipitation in the sediment.

Uranium, Thorium and Protactinium isotopes of ODP Site 172-1063

Ocean circulation may have undergone reductions and reinvigorations in the past closely tied to regional climate changes. Measurements of 231Pa/230Th ratios in a sediment core from the Bermuda Rise have been interpreted as evidence that the Atlantic Meridional Overturning Circulation (AMOC) was weakened or completely eliminated during a period of catastrophic iceberg discharges (Heinrich-Event 1, H1). Here we present new data from the Bermuda Rise that show further 231Pa/230Th peaks during Heinrich-2 (H2) and Heinrich-3 (H3). Additionally, a tight correlation between diatom abundances (biogenic silica) and 231Pa/230Th is discovered in this core. Our results redirect the interpretation of 231Pa/230Th from the Bermuda Rise as a proxy for ocean circulation towards a proxy that reacts highly sensitive to changes of particle composition and water mass properties.