Polymer product engineering utilising oscillatory baffled reactors

The Oscillatory baffled reactor (OBR) can be used to produce particles with controlled size and morphology, in batch or continuous flow. This is due to the effect of the superimposed oscillations that radially mixes fluid but still allows plug-flow (or close to plug flow) behaviour in a continuous system. This mixing, combined with a close to a constant level of turbulence intensity in the reactor, leads to tight droplet and subsequent product particle size distributions. By applying population balance equations together with experimental droplet size distributions, breakage rates of droplets can be determined and this is a useful tool for understanding the product engineering in OBRs. (C) 2002 Elsevier Science B.V All rights reserved.

Bio-based composites from stone groundwood applied to new product development

This paper deals with the product design, engineering, and material selection intended for the manufacturing of an eco-friendly chair. The final product is expected to combine design attributes with technical and legal feasibility with the implementation of new bio-based materials. Considering the industrial design, a range of objectives and trends were determined after setting the market requirements, and the final concept was proposed and modeled. The product geometry, production technology, and legal specifications were the input data for product engineering. The material selection was based on the technical requirements. Polypropylene (PP) composite materials based on coupled-fiberglass, sized-fiberglass, and coupled-stone ground wood reinforcements were prepared and characterized. Final formulations based on these PP composites are proposed and justified

The use of participant-observation protocol in an industrial engineering research

Based on literature, this article aims to present the "participant-observation" research protocol, and its practical application in the industrial engineering field, more specifically within the area of design development, and in the case shown by this article, of interiors' design. The main target is to identify the concept of the method, i.e., from its characteristics to structure a general sense about the subject, so that the protocol can be used in different areas of knowledge, especially those ones which are committed with the scientific research involving the expertise from researchers, and subjective feelings and opinions of the users of an engineering product, and how this knowledge can be benefic for product design, contributing since the earliest stage of design.

Grafting of functional brushes on the surface of 5-Fluorouracil molecularly imprinted polymer particles through RAFT polymerization

The grafting of functional brushes on the surface of molecularly imprinted polymer (MIP). particles hás been explored in the last few years to synthesize materiais combining high molecular recognition capabilities and stimulation triggered by changes in the surrounding environment [1, 2]. In the present work, MIP particles for 5-fluorouracil (a drug used in câncer treatment) were produced by precipitation polymerization in acetonitrile, using either MAA or HEMA as imprinting fünctional monomers, and m the presence of different kinds of RAFT agents. In a second step, taking advantage of the RAFT groups present in the surface of the particles, different kinds of fiinctional polymer brushes were grafted on the MIPs considering a "grafting from" process in the presence of a RAFT agent.

In vitro characterization of a collagen scaffold enzymatically cross-linked with a tailored elastin-like polymer

Collagen, the main structural component of the extracellular matrix (ECM), provides tensile stiffness to different structures and organs against rupture. However, collagen tissue-engineered implants are hereto still lacking in mechanical strength. Attempts to create stiffer scaffolds have resulted in increased brittleness of the material, reducing the versatility of the original component. The hypothesis behind this research is that the introduction of an elastic element in the scaffold will enhance the mechanical properties of the collagen-based scaffolds, as elastin does in the ECM to prevent irreversible deformation. In this study, an elastin-like polymer (ELP) designed and synthesized using recombinant DNA methodology is used with the view to providing increased proteolytic resistance and increased functionality to the scaffolds by carrying specific sequences for microbial transglutaminase cross-linking, endothelial cell adhesion, and drug delivery. Evaluation of the effects that cross-linking ELP-collagen has on the physicochemical properties of the scaffold such as porosity, presence of cross-linking, thermal behavior, and mechanical strength demonstrated that the introduction of enzymatically resistant covalent bonds between collagen and ELP increases the mechanical strength of the scaffolds in a dose-dependent manner without significantly affecting the porosity or thermal properties of the original scaffold. Importantly, the scaffolds also showed selective behavior, in a dose (ELP)-dependent manner toward human umbilical vein endothelial cells and smooth muscle cells when compared to fibroblasts.

Thermal diffusivity of polymers by modified angstrom method

The nature of the molecular structure of plastics makes the properties of such materials markedly temperature dependent. In addition, the continuous increase in the utilization of polymeric materials in many specific applications has demanded knowledge of their physical properties, both during their processing as raw material, as well as over the working temperature range of the final polymer product. Thermal conductivity, thermal diffusivity and specific heat, namely the thermal properties, are the three most important physical properties of a material that are needed for heat transfer calculations. Recently, among several different methods for the determination of the thermal diffusivity and thermal conductivity, transient techniques have become the preferable way for measuring thermal properties of materials. In this work, a very simple and low cost variation of the well known Angstrom method is employed in the experimental determination of the thermal diffusivity of some selected polymers. Cylindrical shaped samples 3 cm diameter and 7 cm high were prepared by cutting from long cylindrical commercial bars. The reproducibility is very good, and the results obtained were checked against results obtained by the hot wire technique, laser flash technique, and when possible, they were also compared with data found in the literature. Thermal conductivity may be then derived from the thermal diffusivity with the knowledge of the bulk density and the specific heat, easily obtained by differential scanning calorimetry. (C) 2009 Elsevier Ltd. All rights reserved.

Bone cell responses to the composite of Ricinus communis polyurethane and alkaline phosphatase

The aim of this study was to evaluate the response of osteoblastic cells to the composite of Ricinus cominunis polyurethane (RCP) and alkaline phosphatase (ALP) incubated in synthetic body fluid (SBF). RCP pure (RCPp) and RCP blended with ALP 6 mg/mL polymer (RCP+ALP) were incubated in SBF for 17 days. Four groups of RCP were tested: RCPp, RCP+ALP, and RCPp and RCP+ALP incubated in SBF (RCPp/SBF and RCP+ALP/SBF). Stem cells from rat bone marrow were cultured in conditions that allowed osteoblastic differentiation on RCP discs and were evaluated: cell adhesion, culture growth, cell viability, total protein content, ALP activity, and bone-like nodule formation. Data were compared by ANOVA or Kruskal-Wallis test. The group RCP-A P was highly cytotoxic and, therefore, was not considered here. Cell adhesion (p = 0.14), culture growth (p = 0.39), viability (p = 0.46) and total protein content (p = 0.12) were not affected by either RCP composition or incubation in SBE ALP activity was affected (p = 0.0001) as follows: RCPp < RCPp/SBF < RCP+ALP/SBF. Bone-like nodule formation was not observed on all evaluated groups. The composite RCP+ALP prior to SBF incubation is cytotoxic and must not be considered as biomaterial, but the incorporation of ALP to the RCP followed by SBF incubation could be a useful alternative to improve the biological properties of the RCP. (c) 2007 Wiley Periodicals, Inc.

Consolidating preservative-treated wood: Combined mechanical performance of boron and polymeric products in wood degraded by Coniophora puteana

When timber elements in heritage buildings are moderately degraded by fungi and assuming underlying moisture problems have been solved, two actions can be taken: i) use a biocide to stop fungal activity; ii) consolidate the degraded elements so that the timber keeps on fulfilling its structural and decorative functions. The aim of this work is to investigate the mechanical performance of maritime pine wood degraded by fungi after being treated with a biocide followed by impregnation with a polymer product. Three commercially available products were used: a boron water-based biocide, an acrylic consolidant and an epoxy-based consolidant. Treated and consolidated specimens were subjected to mechanical tests: axial compression test (NP 618), static surface hardness (ISO 3350) and bending test (NP 619). Sets of replicates were subjected to an evaporation ageing test (EN 73) after application of the products and also tested for mechanical behaviour. An increase in mechanical strength was observed for both consolidants with no significant influence from the previous use of biocide product. The specimens subjected to ageing showed a slightly better general mechanical performance.

Análise e optimização de processos numa empresa do sector automóvel

Trabalho de Projeto

Jännitevälipiiritaajuusmuuttajan moottorikaapelin maksimipituuden määrittely

Työssä tutkitaan, kuinka pitkää moottorikaapelia on jännitevälipiiritaajuusmuuttajan kanssa mahdollista käyttää niin, että määritellyt reunaehdot vielä toteutuvat. Tavoitteena on tuottaa tietoa myynnille, markkinoinnille, tuotehallinnalle sekä tuoteylläpidolle siitä, miten taajuus-muuttaja toimii pidemmillä moottorikaapeleilla kuin valmistaja suosittelee. Tutkitut moottori-kaapelipituudet olivat 175…1025 metriä ja tutkitut laitteet nimellislähtövirroiltaan 2,4...25 A. Työssä aihetta käsitellään jänniteheijastusten näkökulmasta. Lisäksi tutkitaan moottorikaapelin pituuden vaikutusta taajuusmuuttajan eri komponenttien lämpenemiseen. Taajuusmuuttajan toiminnallisuutta arvioidaan moottorin suunnanvaihtojen avulla sekä turvallista toimintaa oikosulkutestein. Tutkittujen taajuusmuuttajien kohdalla on mahdollista käyttää taajuusmuuttajavalmistajan suositusta pidempiä moottorikaapeleita. Moottoriliittimien ylijännitteitä aiheuttavat jännite-heijastukset eivät aiheuttaneet raja-arvoja ylittäviä huippujännitteitä tutkituilla laitekokoon-panoilla. Myös lämpötilannousu oli maltillista tai jopa vähäistä taajuusmuuttajasta mitatuilla komponenteilla. Moottorisäätö havaittiin toimintakykyiseksi pidemmilläkin moottorikaape-leilla, tosin moottorin vääntömomentti heikkeni moottorikaapelien pituutta kasvatettaessa. Virranmittaus toimi hyvin myös pitkillä kaapeleilla, tuottaen vikalaukaisun kaikissa tehdyissä oikosulkutilanteissa. Moottorin ja taajuusmuuttajan melutaso nousivat moottorikaapelien pi-tuutta kasvatettaessa, vaikkakin moottorin käynti oli tasaista ja katkotonta Moottorikaapelin pituutta voidaan kasvattaa 325 metriin kaikissa tutkituissa laitteissa ilman, että mikään tutkittu ominaisuus vielä olennaisesti heikkenisi. Vielä 525 metrin moottorikaape-leita on mahdollista käyttää, mutta tällöin vääntömomentin tuotto on jo heikompaa.

Takuiden ja teknisen tuen käsittelyprosessin analysointi ja kehittäminen

Diplomityö liittyy taajuusmuuttajien takuuhuoltoprosessiin. Tutkitaan prosessin toimintaa, sen tehokkuutta, sekä sen yhteydessä tapahtuvaa viestintää. Keskitytään prosessin ylimpään tasoon ja erityisesti vaativampiin tapauksiin, joissa takuuaikana käydään useita kertoja asiakkaan tiloissa tekemässä huoltotoimenpiteitä. Useat perättäiset vikaantumiset asettavat myös viestinnän koetukselle. Lähtökohtana on saada kokonaiskuva, mitä prosessissa tapahtuu siitä lähtien kun taajuusmuuttaja on toimitettu ja ensimmäinen yhteydenotto tulee Helsingin tehtaalle vikatilanteessa. Tutkitaan mitä tapahtuu tehtaan ja paikallisen yhtiön välillä toimituksesta aina siihen asti, kun viimeinen korjauskäynti on tehty kyseisellä työmaalla. Koko prosessi kuvataan, mutta varsinaiset kehitystoimet keskittyvät kuitenkin Product Engineering & Quality -osastoon. Työssä käytettäviä tutkimusmetodeja ovat kirjallisuus, prosessikuvaukset ja haastattelut. Työn tuloksena saadaan yleinen prosessin nykytilan kuvaus, korjauskäyntikohtainen arvovirtauskaavio ja löydetään mahdolliset parannuskohteet prosessiin. Viestintään saadaan systematiikkaa soveltaen kriisiviestinnän ja kriisinhallinnan kirjallisuutta. Näiden avulla päästään tehokkaampaan, ammattimaisempaan ja resursseja paremmin hyödyntävään tapaan toimia. Pitkällä aikavälillä myös asiakkaan luottamus kasvaa ja asiakassuhde säilyy entistä paremmin.

Morphological, mechanical and thermal properties of nylon 6/ABS blends using glycidyl methacrylate-methyl methacrylate copolymers

Nylon6 is an attractive polymer for engineering applications because it has reactive functionality through amine and carboxyl end groups that are capable of reacting. For this reason, it has been used a lot in polymeric blends. Blends of nylon6/ABS (acrylonitrile-butadiene-styrene) were produced using glycidyl methacrylate-methyl methacrylate (GMA-MMA) copolymers as compatibilizer. The binary blends were immiscible and exhibited poor mechanical properties that stemmed from the unfavorable interactions among their molecular segments. This produced an unstable coarse phase morphology and weak interfaces between the phases in the solid state. The presence of the copolymer in the blends clearly led to a more efficient dispersion of the ABS phase and consequently optimized Izod impact properties. However, the compatibilized blend showed poor toughness at room temperature and failed in a brittle manner at subambient temperatures. © 2005 Springer Science + Business Media, Inc.

Carboxymethyl lignin as stabilizing agent in aqueous ceramic suspensions

Identifying new uses for residues of industries that process large quantities of biomass, as in bioethanol production, is essential for a sustainable development with reduced impact on the environment, which is the reason why many efforts have been devoted to find noble uses for lignins. in this study, a lignin obtained from sugarcane bagasse in a bioethanol producing plant was carboxymethylated to yield the water-soluble carboxymethyl lignin (CML), which was then used as stabilizing agent in aqueous alumina (Al2O3) suspensions. CML had a degree of substitution 0.46 +/- 0.01, in relation to the C9 unit of lignin, and behaved as a polyelectrolyte in a large pH range owing to the dissociation of carboxylic groups. The action of CML as stabilizing agent of alumina aqueous suspensions was investigated using viscometry, zeta potential, and photon correlation spectroscopy (PCS) measurements, mainly as a function of pH and time. Overall, the results showed that CML had a good performance as a deflocculating agent, because it led to dispersions with low viscosity and small change in particle size as a function of time. The positive effect from the addition of CML was confirmed in the morphological features of the material obtained from the alumina suspensions after elimination of water, as indicated by scanning electron microscopy. The stabilization of alumina suspensions afforded by CML opens the way for similar applications of modified lignins, whose electrical and structural properties may be tuned for specific uses in various industries, including the ceramic industry. (C) 2011 Elsevier B.V. All rights reserved.

The Crystallization Kinetics of Polylactic Acid (Pla) Processed Through Solid-State/Melt Extrusion

Polylactic acid (PLA) is a bio-derived, biodegradable polymer with a number of similar mechanical properties to commodity plastics like polyethylene (PE) and polyethylene terephthalate (PETE). There has recently been a great interest in using PLA to replace these typical petroleum-derived polymers because of the developing trend to use more sustainable materials and technologies. However, PLA¿s inherent slow crystallization behavior is not compatible with prototypical polymer processing techniques such as molding and extrusion, and in turn inhibits its widespread use in industrial applications. In order to make PLA into a commercially-viable material, there is a need to process the material in such a way that its tendency to form crystals is enhanced. The industry standard for producing PLA products is via twin screw extrusion (TSE), where polymer pellets are fed into a heated extruder, mixed at a temperature above its melting temperature, and molded into a desired shape. A relatively novel processing technique called solid-state shear pulverization (SSSP) processes the polymer in the solid state so that nucleation sites can develop and fast crystallization can occur. SSSP has also been found to enhance the mechanical properties of a material, but its powder output form is undesirable in industry. A new process called solid-state/melt extrusion (SSME), developed at Bucknell University, combines the TSE and SSSP processes in one instrument. This technique has proven to produce moldable polymer products with increased mechanical strength. This thesis first investigated the effects of the TSE, SSSP, and SSME polymer processing techniques on PLA. The study seeks to determine the process that yields products with the most enhanced thermal and mechanical properties. For characterization, percent crystallinity, crystallization half time, storage modulus, softening temperature, degradation temperature and molecular weight were analyzed for all samples. Through these characterization techniques, it was observed that SSME-processed PLA had enhanced properties relative to TSE- and SSSP-processed PLA. Because of the previous findings, an optimization study for SSME-processed PLA was conducted where throughput and screw design were varied. The optimization study determined PLA processed with a low flow rate and a moderate screw design in an SSME process produced a polymer product with the largest increase in thermal properties and a high retention of polymer structure relative to TSE-, SSSP-, and all other SSME-processed PLA. It was concluded that the SSSP part of processing scissions polymer chains, creating defects within the material, while the TSE part of processing allows these defects to be mixed thoroughly throughout the sample. The study showed that a proper SSME setup allows for both the increase in nucleation sites within the polymer and sufficient mixing, which in turn leads to the development of a large amount of crystals in a short period of time.

Ansätze zur Verbesserung von Qualität und Wirtschaftlichkeit bei generativen Verfahren durch Optimierung des Pre-Processes

Mittels generativer Fertigung ist es heute möglich die, Entwicklungszeit und Ferti-gungsdauer von Prototypen, Produkten und Werkzeugen zu verkürzen. Neben dieser Zeitersparnis sind die im Vergleich zu konventionellen Fertigungsverfahren unwe-sentlichen Geometriebeschränkungen für den Anwender von besonderem Interesse. Dieses Alleinstellungsmerkmal der generativen Fertigung macht es möglich auch komplexe Geometrie wirtschaftlich herzustellen. Voraussetzung für eine wirtschaftli-che und fehlerminimierte Fertigung ist hierbei eine möglichst optimale Prozessvorbe-reitung (Pre-Processing). Dabei sind insbesondere die Schritte der Bauteilorientie-rung, der Stützkonstruktionserzeugung, der Schichtzerlegung sowie der Bauraum-ausnutzung von Interesse. Auch wenn diese Punkte wesentlich zur Qualität und Wirtschaftlichkeit beitragen, sind die Erkenntnisse für den unerfahrenen Anwender nur unzureichend dokumentiert, wodurch eine möglichst effiziente Fertigung zu-nächst ausgeschlossen werden kann. Anhand unterschiedlicher Beispiele sollen dem Anwender hier die Möglichkeiten zur Optimierung dieser Pre-Processing Schritte er-läutert werden. In diesem Rahmen werden die aktuellen Forschungsergebnisse des Lehrstuhls Rechnereinsatz in der Konstruktion, Institut für Produkt Engineering der Universität Duisburg-Essen in Bezug auf die Optimierung der Bauteilorientierung, der variablen Schichtzerlegung und der Optimierung der Bauraumausnutzung vorgestellt.