Open-cell photoacoustic investigation of the thermal effusivity of liquid crystals

We report the use of an open photoacoustic cell configuration for the evaluation of thermal effusivity of liquid crystals. Initially, the method is calibrated using water and glycerol as transparent liquid samples, and the role of thermal conductivity of these liquids on the photoacoustic signal amplitude is discussed. To demonstrate the application of the present method for the evaluation of thermal effusivity of liquid crystals, we have used certain multicomponent nematic liquid crystal mixtures, namely BL001, BL002, BL032, and BL035. Each of these liquid crystal mixtures contains four to nine components and are primarily based on the cyanobiphenyl structure. The measured values of thermal effusivity of BL001 and BL002 were found to be almost the same, but differ from those of BL032 and BL035, which implies a difference in composition of the latter two from the former two mixtures.

Photoacoustic investigation of doped InP using open cell configuration

An open cell photoacoustic (PA) configuration has been employed to evaluate the thermal diffusivity of intrinsic InP as well as InP doped with tin and iron. Thermal diffusivity data have been evaluated from variation of phase of PA signal as a function of modulation frequency. In doped samples, we observe a reduced value for thermal diffusivity in comparison with intrinsic InP. We also observed that, while the phase of the PA signal varies linearly with the square root of chopping frequency for doped samples, the intrinsic material does not exhibit such behaviour in the experimental frequency range. These results have been interpreted in terms of the heat generation and phonon assisted heat diffusion mechanisms in semiconductors.

Effect of Te doping on thermal diffusivity of Bi2Se3 crystals: A study using open cell photoacoustic technique

An open cell configuration has been employed for the photoacoustic measurement of the thermal diffusivity of undoped Bi2Se3 crystals and Bi2Se3 crystals doped with various concentrations of Te. The amplitude of the photoacoustic signal obtained under heat transmission configuration as a function of chopping frequency is used to evaluate the numerical value of thermal diffusivity, α. Doped samples show a substantial reduction in the value of α compared to undoped samples. The variations in the thermal diffusivity of the doped samples are explained in terms of the phonon assisted heat transfer mechanism. It is seen that α is very sensitive to structural variations arising from doping. The experimentally observed results are correlated with X-ray diffraction studies.

A geometric study of liquid retention in open-cell metal foams

Open-cell metal foams show promise as an emerging novel material for heat exchanger applications. The high surface-area-to-volume ratio suggests increased compactness and decrease in weight of heat exchanger designs. However, the metal foam structure appears conducive to condensate retention, which would degenerate heat transfer performance. This research investigates the condensate retention behavior of aluminum open-cell metal foams through the use of static dip tests and geometrical classification via X-ray Micro-Computed Tomography. Aluminum open-cell metal foam samples of 5, 10, 20, and 40 pores per inch (PPI), all having a void fraction greater than 90%, were included in this investigation. In order to model the condensate retention behavior of metal foams, a clearer understanding of the geometry was required. After exploring the ideal geometries presented in the open literature, X-ray Micro-Computed Tomography was employed to classify the actual geometry of the metal foam samples. The images obtained were analyzed using specialized software from which geometric information including strut length and pore shapes were extracted. The results discerned a high variability in ligament length, as well as features supporting the ideal geometry known as the Weaire-Phelan unit cell. The static dip tests consisted of submerging the metal foam samples in a liquid, then allowing gravity-induced drainage until steady-state was reached and the liquid remaining in the metal foam sample was measured. Three different liquids, water, ethylene glycol, and 91% isopropyl alcohol, were employed. The behaviors of untreated samples were compared to samples subjected to a Beomite surface treatment process, and no significant differences in retention behavior were discovered. The dip test results revealed two distinct regions of condensate retention, each holding approximately half of the total liquid retained by the sample. As expected, condensate retention increased as the pores sizes decreased. A model based on surface tension was developed to predict the condensate retention in the metal foam samples and verified using a regular mesh. Applying the model to both the ideal and actual metal foam geometries showed good agreement with the dip test results in this study.

Open-cell Metallic Foams for the Electrochemical Conversion of Biomass-derived Compounds

The electrochemical conversion is a sustainable way for the production of added-value products, operating in mild conditions, using in-situ generated hydrogen/oxygen by water and avoiding the use of high H2/O2 pressures. The aim of this work is to investigate the electrocatalytic conversion of 5-hydroxymetilfurfural (HMF) and D-glucose, in alkaline media, using metallic open-cell foams based-catalysts. The electrochemical hydrogenation of HMF to 2,5-bis(hydroxymethyl)furan (BHMF) was performed using nanostructured Ag, deposited by galvanic displacement (GD) or electrodeposition (ED), on Cu foam, obtaining AgCu bimetallic nanoparticles (ED) or dendrites (GD) which enhanced electroactive surface area, charge and mass transfer, than bare foams. In diluted 0.02M HMF solutions, Ag/Cu samples selectively produce BHMF; the large surface area enhanced the productivity, compared to their 2D counterparts. Furthermore, at more concentrated solutions (0.05 – 0.10M) a gradually decrease of selectivity is observed. The performances of the electrodes is stable during the catalytic tests but a Cu-enrichment of particles occurred. The performances of Ni foam-based catalysts, obtained by calcination of Ni foam or by electrodeposition of Ni-hydroxide/Ni and Ni particle/Ni, were firstly investigated for the selective electrochemical oxidation of D-glucose toward gluconic acid (GO) and glucaric acid (GA). Then, the calcined catalyst was chosen to study the influence of the reaction conditions on the reaction mechanism. The GO and GA selectivities increase with the charge passed, while the formation of by-products from C-C cleavage/retro-aldol process is maximum at low charge. The fructose obtained from glucose isomerization favours the formation of by-products. The best glucose/NaOH ratio is between 0.5 and 0.1: higher values suppress the OER, while lower values favour the formation of low molecular weight products. The increases of the potential enhance the GO selectivity, nevertheless higher GA selectivity is observed at 0.6 – 0.7V vs SCE, confirmed by catalytic test performed in gluconate (30-35% GA selectivity).

Use of an open photoacoustic cell for the thermal characterisation of liquid crystals

In this paper, we describe the use of an open cell photoacoustic configuration for the evaluation of the thermal effusivity of liquid crystals. The feasibility, precision and reliability of the method are initially established by measuring the thermal effusivities of water and glycerol, for which the effusivity values are known accurately. In order to demonstrate the use of the present method in the thermal characterization of liquid crystals, we have measured the thermal effusivity values in various mesophases of 4-cyano-4 - octyloxybiphenyl (8OCB) and 4-cyano-4 -heptyloxybiphenyl (7OCB) liquid crystals using a variable temperature open photoacoustic cell. A comparison of the measured values for the two liquid crystals shows that the thermal effusivities of 7OCB in the nematic and isotropic phases are slightly less than those of 8OCB in the corresponding phases

Use of an open photoacoustic cell for the thermal characterisation of liquid crystals

In this paper, we describe the use of an open cell photoacoustic configuration for the evaluation of the thermal effusivity of liquid crystals. The feasibility, precision and reliability of the method are initially established by measuring the thermal effusivities of water and glycerol, for which the effusivity values are known accurately. In order to demonstrate the use of the present method in the thermal characterization of liquid crystals, we have measured the thermal effusivity values in various mesophases of 4-cyano-4 - octyloxybiphenyl (8OCB) and 4-cyano-4 -heptyloxybiphenyl (7OCB) liquid crystals using a variable temperature open photoacoustic cell. A comparison of the measured values for the two liquid crystals shows that the thermal effusivities of 7OCB in the nematic and isotropic phases are slightly less than those of 8OCB in the corresponding phases

Use of an open photoacoustic cell for the thermal characterisation of liquid crystals

In this paper, we describe the use of an open cell photoacoustic configuration for the evaluation of the thermal effusivity of liquid crystals. The feasibility, precision and reliability of the method are initially established by measuring the thermal effusivities of water and glycerol, for which the effusivity values are known accurately. In order to demonstrate the use of the present method in the thermal characterization of liquid crystals, we have measured the thermal effusivity values in various mesophases of 4-cyano-4 - octyloxybiphenyl (8OCB) and 4-cyano-4 -heptyloxybiphenyl (7OCB) liquid crystals using a variable temperature open photoacoustic cell. A comparison of the measured values for the two liquid crystals shows that the thermal effusivities of 7OCB in the nematic and isotropic phases are slightly less than those of 8OCB in the corresponding phases

Coalbed methane sorption related to coal composition

Gas sorption by coal is closely related to its physical and chemical properties, which are, in turn, governed by coal type and rank. The role of coal type (sensu maceral composition) is not fully established but it is clear that coal type may affect both adsorption capacity and desorption rate. Adsorption capacity is closely related to micropore (pores <2 nm) development, which is rank and maceral dependent. Adsorption isotherms indicate that in most cases bright (vitrinite-rich) coals have a greater adsorption capacity than their dull (often inertinite-rich) equivalents. However, no differences, or even the opposing trend, may be observed in relation to coal type. Desorption rate investigations have been performed using selected bright and dull coal samples in a high pressure microbalance. Interpretation of results using unipore spherical and bidisperse pore models indicate the importance of the pore structure. Bright, vitrinite-rich coals usually have the slowest desorption rates which is associated with their highly microporous structure. However, rapid desorption in bright coals may be related to development of extensive, unmineralised fracture systems. Both macro-and micro-pore systems are implicated in the more rapidly desorbing dull coals. Some dull, inertinite-rich coals may rapidly desorb due to a predominance of large, open cell lumina. Mineral matter is essentially nonadsorbent to coal gases and acts as a simple diluent. However, mineral-rich coals may be associated with more rapid desorption. Coal rank and type (maceral composition) per se do not appear to be the critical factors in controlling gas sorption, but rather the influence they exert over pore structure development. (C) 1998 Elsevier Science B.V.

Produção e caracterização de espumas cerâmicas obtidas a partir de lodo de anodização de alumínio

Ceramic foams were produced from a sludge generated in the aluminum anodizing process by using an industrial polyurethane foam (replication method) with open cell sizes of 10 ± 5 ppi (porosity = 97%) which were impregnated with suspensions containing 50-61 wt.% alumina, 1 wt.% citric acid, 6 wt.% bentonite and fired at 1600 ºC for 2 h. The aluminum anodizing sludge shows a high alumina content (87.5 wt.%) and a low particle size (~1.7 mm) after calcination and milling. The obtained filters show porosity of approximately 70%, filtration capability (mass water flow) of 1.7 kg/s and mechanical strength under compression of 2.40 MPa.

Photoacoustic studies on thermal parameters of liquid crystal mixtures

Complete thermal characterization of liquid crystal mixtures in the smectic phase consisting of various relative volume fractions of cholesterol and 1-hexadecanol have been carried out using the photoacoustic technique. Thermal diffusivity values of these liquid crystal mixtures are evaluated using the open cell photoacoustic technique whereas the thermal effusivity value is measured using the conventional photoacoustic technique. From the measured values of these transient thermophysical parameters, the thermal conductivity and heat capacity of the sample under investigation are calculated. Analyses of the results show that all the thermophysical parameters depend strongly on the volume fraction of the constituents. Results are interpreted in terms of enhanced hydrogen bonding and the consequent enhancement in cohesive thermal energy transport with increasing volume fraction of 1-hexadecanol

Photoacoustic studies on thermal parameters of liquid crystal mixtures

Complete thermal characterization of liquid crystal mixtures in the smectic phase consisting of various relative volume fractions of cholesterol and 1-hexadecanol have been carried out using the photoacoustic technique. Thermal diffusivity values of these liquid crystal mixtures are evaluated using the open cell photoacoustic technique whereas the thermal effusivity value is measured using the conventional photoacoustic technique. From the measured values of these transient thermophysical parameters, the thermal conductivity and heat capacity of the sample under investigation are calculated. Analyses of the results show that all the thermophysical parameters depend strongly on the volume fraction of the constituents. Results are interpreted in terms of enhanced hydrogen bonding and the consequent enhancement in cohesive thermal energy transport with increasing volume fraction of 1-hexadecanol

Photoacoustic studies on thermal parameters of liquid crystal mixtures

Complete thermal characterization of liquid crystal mixtures in the smectic phase consisting of various relative volume fractions of cholesterol and 1-hexadecanol have been carried out using the photoacoustic technique. Thermal diffusivity values of these liquid crystal mixtures are evaluated using the open cell photoacoustic technique whereas the thermal effusivity value is measured using the conventional photoacoustic technique. From the measured values of these transient thermophysical parameters, the thermal conductivity and heat capacity of the sample under investigation are calculated. Analyses of the results show that all the thermophysical parameters depend strongly on the volume fraction of the constituents. Results are interpreted in terms of enhanced hydrogen bonding and the consequent enhancement in cohesive thermal energy transport with increasing volume fraction of 1-hexadecanol