Studies on Ilmenite of Chavara and Manavalakurichi Deposites, Southwest Coast of India

The present work attempts to trace the variation in the physical and chemical behavior of ilmenite, since its release from country rocks and subsequent transportation to the coast through the progressive weathering environments of laterite, sedimentary rocks, rivers and estuarine systems. Since the hinterland of the study area consists of crystalline and sedimentary rocks and their weathered forms (laterites), the contribution of each lithological system to the beach placer is attempted. The results of the study show that the most magnetic fraction contains more content of altered phases than the relatively unweathered fractions. The fractions separated above 0.35A define a high grade of ilmenite ore enriched in Ti content. The lattice volume generally decreases with alteration. The magnetic studies revels that the Chavara ilmenite are found to be made up to low magnetic crops with about 46% of the bulk ilmenite constituted by fractions separated at above 0.35A. In the Manavalakurichi ilmenite on the other hand, around 91% of the beach ilmenite is made of fractions separated at or below 0.3A

Mineralogical And Sedimentological Studies Of Innershelf And Beach Sediments Along The Coast Between Paravur And Kovalam, South Kerala, India

Continental shelf is of particular significance in marine geology , because it links the two basically different structural zones in the earth's crust; the continents and ocean basins. The shelf area has much wider importance in many fields of activity such as scientific, economic, social, political and strategic. The pace of development has ultimately put pressure on mankind to look for exploitable resources and accessibility to the continental shelf area and beyond. Added to the above, the developmental activities in the coastal area would readily and directly influence the innershelf sediments. This situation demands a thorough geological knowledge of the continental shelf area. Moreover, a successful management of the continental shelf zone requires an optimum data base on the physico-chemical nature of the shelf sediments. Although sedimentological studies were carried out along the western continental shelf of India, a well documented systematic study of the inner shelf off Trivandrum coast is still found to be lacking. Considering the physiographic settings and the vicinity of two renowned placer deposits at Chavara and Manavalakurichi, such a sedimetological inventory has become all the more vital. In view of the above, a research programme has been drawn up to account the salient sedimentological and mineralogical aspects of the innershelf and beach sediments between Paravur and Kovalam, Trivandrum district, Kerala (latitudes 8° 7'00" to 8° 47'45" and longitudes 76°43'00" to 77° 40'45"). The findings are presented in six chapters formatted to address the aim of this research.

Petrography, Geochemistry and Diagenesis of Coral Deposits of Kavaratti and Minicoy Islands, Lakshadweep, India

In the present thesis the petrographic, geochemical and digenetic variability of the sediments in the islands of Kavaratti and Minicoy has been investigated .The beach profile studies show that in the Kavaratti lagoon beach, the slope is steeper in the southern and south central part than in the northern end’s marginal deposition is taking place in the northern end of the Kavaratti island, whereas a marginal erosion is observed at the southern end. In Minicoy the slope of the lagoon beach is gentle in the south and is slightly steeper at the northern part of the beach. The southern and northern beach sections show a marginal deposition. Based on the mineralogical and geochemical studies it is concluded that the main digenetic changes observed is the transformation of aragonite to LMC.The transformation takes place mainly in the vadose zone and is caused by the abundance of fresh water infiltration.

Ilmenite FeTiO3 nanoflowers and their pseudocapacitance

Pronounced and stable pseudocapacitance has been found in flowerlike FeTiO3 nanostructures that were synthesized from ball-milled ilmenite (natural mineral) under mild hydrothermal conditions. Each nanoflower is composed of many thin petals with a thickness of 5–20 nm and a width of 100–200 nm. The formation of these flowerlike nanostructures is attributed to a dissolution–precipitation mechanism involving an intermediate sodium-containing phase. Electrochemical properties of the obtained FeTiO3 nanostructures are evaluated in aqueous electrolytes. The capacitance of 122 ± 14.5 F/g is measured in 1 M KOH aqueous electrolyte at the current rate of 500 mA/g, and 50 ± 6 F/g is retained at 5 A/g. The material has good long-term cycling stability. According to our data, FeTiO3 nanostructures show functionality as an electrode material for supercapacitors.

Partial melting within the lower crust – Constraints from bulk rock geochemical data and trace element mineral analyses of granulites and migmatites from Central Finland

This PhD thesis concerns geochemical constraints on recycling and partial melting of Archean continental crust. A natural example of such processes was found in the Iisalmi area of Central Finland. The rocks from this area are Middle to Late Archean in age and experienced metamorphism and partial melting between 2.7-2.63 Ga. The work is based on extensive field work. It is furthermore founded on bulk rock geochemical data as well as in-situ analyses of minerals. All geochemical data were obtained at the Institute of Geosciences, University of Mainz using X-ray fluorescence, solution ICP-MS and laser ablation-ICP-MS for bulk rock geochemical analyses. Mineral analyses were accomplished by electron microprobe and laser ablation ICP-MS. Fluid inclusions were studied by microscope on a heating-freezing-stage at the Geoscience Center, University Göttingen. Part I focuses on the development of a new analytical method for bulk rock trace element determination by laser ablation-ICP-MS using homogeneous glasses fused from rock powder on an Iridium strip heater. This method is applicable for mafic rock samples whose melts have low viscosities and homogenize quickly at temperatures of ~1200°C. Highly viscous melts of felsic samples prevent melting and homogenization at comparable temperatures. Fusion of felsic samples can be enabled by addition of MgO to the rock powder and adjustment of melting temperature and melting duration to the rock composition. Advantages of the fusion method are low detection limits compared to XRF analyses and avoidance of wet-chemical processing and use of strong acids as in solution ICP-MS as well as smaller sample volumes compared to the other methods. Part II of the thesis uses bulk rock geochemical data and results from fluid inclusion studies for discrimination of melting processes observed in different rock types. Fluid inclusion studies demonstrate a major change in fluid composition from CO2-dominated fluids in granulites to aqueous fluids in TTG gneisses and amphibolites. Partial melts were generated in the dry, CO2-rich environment by dehydration melting reactions of amphibole which in addition to tonalitic melts produced the anhydrous mineral assemblages of granulites (grt + cpx + pl ± amph or opx + cpx + pl + amph). Trace element modeling showed that mafic granulites are residues of 10-30 % melt extraction from amphibolitic precursor rocks. The maximum degree of melting in intermediate granulites was ~10 % as inferred from modal abundances of amphibole, clinopyroxene and orthopyroxene. Carbonic inclusions are absent in upper-amphibolite facies migmatites whereas aqueous inclusion with up to 20 wt% NaCl are abundant. This suggests that melting within TTG gneisses and amphibolites took place in the presence of an aqueous fluid phase that enabled melting at the wet solidus at temperatures of 700-750°C. The strong disruption of pre-metamorphic structures in some outcrops suggests that the maximum amount of melt in TTG gneisses was ~25 vol%. The presence of leucosomes in all rock types is taken as the principle evidence for melt formation. However, mineralogical appearance as well as major and trace element composition of many leucosomes imply that leucosomes seldom represent frozen in-situ melts. They are better considered as remnants of the melt channel network, e.g. ways on which melts escaped from the system. Part III of the thesis describes how analyses of minerals from a specific rock type (granulite) can be used to determine partition coefficients between different minerals and between minerals and melt suitable for lower crustal conditions. The trace element analyses by laser ablation-ICP-MS show coherent distribution among the principal mineral phases independent of rock composition. REE contents in amphibole are about 3 times higher than REE contents in clinopyroxene from the same sample. This consistency has to be taken into consideration in models of lower crustal melting where amphibole is replaced by clinopyroxene in the course of melting. A lack of equilibrium is observed between matrix clinopyroxene / amphibole and garnet porphyroblasts which suggests a late stage growth of garnet and slow diffusion and equilibration of the REE during metamorphism. The data provide a first set of distribution coefficients of the transition metals (Sc, V, Cr, Ni) in the lower crust. In addition, analyses of ilmenite and apatite demonstrate the strong influence of accessory phases on trace element distribution. Apatite contains high amounts of REE and Sr while ilmenite incorporates about 20-30 times higher amounts of Nb and Ta than amphibole. Furthermore, trace element mineral analyses provide evidence for magmatic processes such as melt depletion, melt segregation, accumulation and fractionation as well as metasomatism having operated in this high-grade anatectic area.

Chemical composition of minerals and rocks from the Sierra Leone segment of the Mid-Atlantic Ridge and from the Markov depression, Central Atlantic

Silicic Fe-Ti-oxide magmatic series was the first recognized in the Sierra Leone axial segment of the Mid-Atlantic Ridge near 6°N. The series consists of intrusive rocks (harzburgites, lherzolites, bronzitites, norites, gabbronorites, hornblende Fe-Ti-oxide gabbronorites and gabbronorite-diorites, quartz diorites, and trondhjemites) and their subvolcanic (ilmenite-hornblende dolerites) and, possibly, volcanic analogues (ilmenite-bearing basalts). Deficit of most incompatible elements in the rocks of the series suggests that parental melts derived from a source that had already been melted. Correspondingly, these melts could not be MORB derivatives. Origin of the series is thought to be related to melting of the hydrated oceanic lithosphere during emplacement of an asthenospheric plume (protuberance on the surface of large asthenospheric lens beneath MAR). Genesis of different melts was supposedly controlled by ascent of a chamber of hot mantle magmas thought this lithosphere in compliance with the zone melting mechanism. Melt acquired fluid components from heated rocks at peripheries of the plume and became enriched in Fe, Ti, Pb, Cu, Zn, and other components mobile in fluids.

Chemical and mineral composition of rocks and sediments from the Amirante Arc

New geological and geophysical data on the Amirante Arc, which locates to the south of the Seychelles Islands, are presented. These data were obtained by Pacific Oceanological Institute during the 33-rd cruise of R/V Professor Bogorov in 1990. The Amirante Arc represents a seamount chain, which has submeridional strike and total length about 400 km. To the west of the Amirante Arc there are a deep sea trench and a back-arc basin, i.e. this area is characterized by structural elements associated with the subduction zone of Western Pacific type. According to our data the Amirante Arc is composed by tholeiites of ocean plateau type. This facts are evidences that the Amirante Arc differs from typical Pacific island arcs. This gives an opportunity to distinguish a special type of oceanic structures, i.e. non-volcanic (amagmatic) ridges. The Amirante Ridge has been probably formed as a result of oceanic crust heaping due to horizontal displacements of its blocks in the process of spreding ridge formation in the Indian Ocean during Cretaceous-Paleogene.

Geochemistry of ash and pumice of ODP Hole 132-810C

Air-fall volcanic ash and pumice were recovered from 22 intervals in upper Miocene-Pleistocene nannofossil oozes cored in Hole 810C on Shatsky Rise, northwest Pacific. Shatsky Rise is near the eastern limit of ash falls produced by explosive volcanism in arc systems in northern Japan and the Kuriles, more than 1600 km away. Electron probe analyses establish that the ash beds and pumice pebbles are andesitic to rhyolitic in composition, and belong to both tholeiitic and high-alumina lineages similar to tephra from Japanese volcanoes. High-speed winds in the polar-front and subtropical jets are evidently what propelled the ash for such a distance. The pumice arrived by flotation, driven from the same directions by winds, waves, and currents. It is not ice-rafted debris from the north. One thick pumice bed probably was deposited when a large pumice mat passed over Shatsky Rise. Far more abundant ash occurs in sediments cored at DSDP Sites 578 through 580, about 500 km west of Shatsky Rise. Most of the ash and pumice at Shatsky Rise can be correlated with specific ash beds at 1, 2, or all 3 of these sites by interpolating to precisely determined magnetic reversal sequences in the cores. Most of the correlations are to thick ash layers (5.7 +/- 3.0 cm) at one or more sites. These must represent extremely large eruptions that spread ash over very wide areas. Whereas several of the thicker correlative ashes fell from elongate east-trending plumes directed from central Japan, the majority of them - dating from about 2 Ma - came from the North Honshu and Kurile arc systems to the northwest. This direction probably was in response to both long-term and seasonal fluctuations in the location and velocity of the polar-front jet, and to more vigorous winter storm fronts originating over glaciated Siberia.

Geochemistry of boninite and harzburgite of ODP Leg 125 basement samples

Holes drilled into the volcanic and ultrabasic basement of the Izu-Ogasawara and Mariana forearc terranes during Leg 125 provide data on some of the earliest lithosphere created after the start of Eocene subduction in the Western Pacific. The volcanic basement contains three boninite series and one tholeiite series. (1) Eocene low-Ca boninite and low-Ca bronzite andesite pillow lavas and dikes dominate the lowermost part of the deep crustal section through the outer-arc high at Site 786. (2) Eocene intermediate-Ca boninite and its fractionation products (bronzite andesite, andesite, dacite, and rhyolite) make up the main part of the boninitic edifice at Site 786. (3) Early Oligocene intermediate-Ca to high-Ca boninite sills or dikes intrude the edifice and perhaps feed an uppermost breccia unit at Site 786. (4) Eocene or Early Oligocene tholeiitic andesite, dacite, and rhyolite form the uppermost part of the outer-arc high at Site 782. All four groups can be explained by remelting above a subduction zone of oceanic mantle lithosphere that has been depleted by its previous episode of partial melting at an ocean ridge. We estimate that the average boninite source had lost 10-15 wt% of melt at the ridge before undergoing further melting (5-10%) shortly after subduction started. The composition of the harzburgite (<2% clinopyroxene, Fo content of about 92%) indicates that it underwent a total of about 25% melting with respect to a fertile MORB mantle. The low concentration of Nb in the boninite indicates that the oceanic lithosphere prior to subduction was not enriched by any asthenospheric (OIB) component. The subduction component is characterized by (1) high Zr and Hf contents relative to Sm, Ti, Y, and middle-heavy REE, (2) light REE-enrichment, (3) low contents of Nb and Ta relative to Th, Rb, or La, (4) high contents of Na and Al, and (5) Pb isotopes on the Northern Hemisphere Reference Line. This component is unlike any subduction component from active arc volcanoes in the Izu-Mariana region or elsewhere. Modeling suggests that these characteristics fit a trondhjemitic melt from slab fusion in amphibolite facies. The resulting metasomatized mantle may have contained about 0.15 wt% water. The overall melting regime is constrained by experimental data to shallow depths and high temperatures (1250? C and 1.5 kb for an average boninite) of boninite segregation. We thus envisage that boninites were generated by decompression melting of a diapir of metasomatized residual MORB mantle leaving the harzburgites as the uppermost, most depleted residue from this second stage of melting. Thermal constraints require that both subducted lithosphere and overlying oceanic lithosphere of the mantle wedge be very young at the time of boninite genesis. This conclusion is consistent with models in which an active transform fault offsetting two ridge axes is placed under compression or transpression following the Eocene plate reorganization in the Pacific. Comparison between Leg 125 boninites and boninites and related rocks elsewhere in the Western Pacific highlights large regional differences in petrogenesis in terms of mantle mineralogy, degree of partial melting, composition of subduction components, and the nature of pre-subduction lithosphere. It is likely that, on a regional scale, the initiation of subduction involved subducted crust and lithospheric mantle wedge of a range of ages and compositions, as might be expected in this type of tectonic setting.