Paleoenvironment evolution of the East Philippine Sea recorded in the new-type ferromanganese crust since the terminal Late Miocene

From systemic research of microstructure, geochemistry, uranium-series and Be-10 isotope dating on a new-type deepwater ferromanganese crust from the East Philippine Sea, the paleoenvironment evolution of the target area since the terminal Late Miocene was recovered. The vertical section changes of microstructure and chemical composition are consistent in the studied crust, which indicate three major accretion periods and corresponding paleoenvironment evolution of the crust. The bottom crust zone was formed in the terminal Late Miocene (5.6 Ma) with loose microstructure, high detritus content and high growth rate. Reductions of mineral element content, accretion rate and positive Ce-anomaly degree at 4.6 Ma indicate temporal warming, which went against the crust accretion and finally formed an accretion gap in the terminal Middle Pliocene (2.8-2.7 Ma). The more active Antarctic bottom seawaters in the Late Pliocene (2.7 Ma) facilitated the fast transfer to the top pure crust zone. Hereafter, with the further apart of volcanic source and the keeping increase of eolian material (1.0 Ma), although surrounding conditions were still favorable, mineral element content still shows an obvious reducing trend. It thereby offers new carrier and data for the unclear paleoceanographic research of the target area since the terminal Late Miocene.

Microfossils detected in a block of ancient dense clay coated with a ferromanganese crust, Clarion-Clipperton Province, East Equatorial Pacific

The area in study is characterized by a regional stratigraphic hiatus from Early Miocene to Quaternary. Deposits from Late Eocene to Early Miocene occur on the bottom surface or under a thin sedimentary cover. Ferromanganese nodules, mostly of Oligocene age, formed on surface layers of Tertiary or Quaternary sediments. A detailed micropaleontological study of a block of dense ancient clay coated with a ferromanganese crust was carried out. Composition of found radiolarian and diatomaceous complexes proved that the crust formed in Quaternary on an eroded surface of Late Oligocene clay. In Quaternary Neogene sediments were eroded and washed away by bottom currents. It is likely that the erosion began 0.9-0.7 Ma at the beginning of the "Glacial Pleistocene". The erosion could be initiated by loosening and resuspension of surface sediments resulting from seismic activity generated by strong earthquakes in the Central America subduction zone. The same vibration maintained residual nodules at the seafloor surface. Thus, for the area in study a common reason and a common Quaternary interval for formation of the following features is supposed: a regional stratigraphic hiatus, formation of residual nodule fields, and position of ancient nodules on the surface of Quaternary sediments.

Chemical composition and description of a ferromanganese crust, sample 89D, obtained during R/V Capricorne cruise ARCANTE 1

A manganese oxide encrustation (2.5 kg) was dredged, in an island arc setting, downslope of Bertrand bank, a seamount culminating at 70-m depth and located NNE of Grande-Terre, Guadeloupe, and SE of Antigua, West Indies. A thorough texturai analysis indicated a rhythmic precipitation and growth polarity as well as mineralogical ( 10 A tektomanganate) and geochemical (low concentrations of Ni, Cu, Co, Zn, Pb and REE) criteria, point to a submarine hydrothermal origin for most of the sample. The crust was coated with a fine ferromanganese oxide cortex deposited iii a "normal" oceanic environment; it also included micritic fillings, a main pyroclastic zone near the top of the crust, and a Mg-Al sulphate deposit. Planktonic foraminifera coeval with the precipitation of the manganese oxide indicate an age of ca. 3 m. y. (upper Pliocene); i.e., more than 20 m. y. after the cessation of the volcanic activity of the Lesser Antilles outer arc that was responsible for the buildup of the Bertrand seamount. Furthermore, the genesis of the crust is not linked to the activity of the contemporaneous inner arc (Miocene to Present), particularly of its nearmost segment (Basse Terre, Guadeloupe-Montserrat) located about 50 km to the West. The authors suggest that the manganese oxide is the result of convective circulation of sea water through a faulted system occurring in an area of intense seismic activity. The remobilization of chemical elements (Mn, S, etc.) within the seamount volcanic core bas probably affected a substratum that was still hydrothermally altered during the previous volcanic activity of the outer arc. The authors insist on the interest in using texturai analysis for Fe/Mn oxide investigations.

Chemical composition of a ferromanganese crust recovred during the GH74-5 cruise of the R/V Hakurei-Maru

Data comes from the NGDC database, https://www.ngdc.noaa.gov/.

(Table 1, page 641) Hf isotope time series for the uppermost part of a ferromanganese crust from the San Pablo ferro-manganese pavement

The Hf isotope composition of seawater does not match that expected from dissolution of bulk continental crust. This mismatch is generally considered to be due to retention of unradiogenic Hf in resistant zircons during incomplete weathering of continental crust. During periods of intense glacial weathering, zircons should break down more efficiently, resulting in the release of highly unradiogenic Hf to the oceans. We test this hypothesis by comparing Nd and Hf isotope time series obtained from NW Atlantic ferromanganese crusts. Both isotope systems show a decrease associated with the onset of northern hemisphere glaciation. The observed changes display distinct trajectories in epsilon Nd- epsilon Hf space, which differ from previously reported arrays of bulk terrestrial material and seawater. Such patterns are consistent with the release of highly unradiogenic Hf from very old zircons, facilitated by enhanced mechanical weathering.

Chemical composition of manganese nodules and a ferromanganese crust using different methods

In the 1960s and 1970s, the Kennecott Corporation conducted a number of activities in the evaluation of manganese nodule deposits as well as in their possible hydrometallurgy.

(Table 1, page 146) Iron, manganese and nickel contents of 21 ferromanganese nodules from Combe D'Izame and Mont Peyroux, Montagne Noire

Ferromanganese nodules (equivalent to Recent manganese nodules) are described from the Upper Devonian griotte (red pelagic limestone) of the Montagne Noire (S. France) and the Cephalopodenkalk of the Rheinisches Schiefergebirge, West Germany. They occur as encrustations, commonly exhibiting colloform structures, around skeletal material and limestone clasts. The nodules are associated with encrusting foraminifera and a development in the sublittoral environment is envisaged. Chemically, the ferromanganese nodules are depleted in manganese relative to iron, compared with Recent nodules, a loss which is attributed to diagenetic migration of manganese. Electron probe studies show that manganese covaries positively with calcium, but negatively with iron and silicon. Diagenetic enrichment of hematite occurs in the griotte at hardground horizons where two periods of mineralization can be established. The Devonian ferromanganese nodules show that solution of nodules has not occurred on burial.