Efeito da superfície vítrea na resistência mecânica de fibras ópticas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Alkaline-earth aluminosilicate-based glass and glass-ceramic sealants for functional applications

The planar design of solid oxide fuel cell (SOFC) is the most promising one due to its easier fabrication, improved performance and relatively high power density. In planar SOFCs and other solid-electrolyte devices, gas-tight seals must be formed along the edges of each cell and between the stack and gas manifolds. Glass and glass-ceramic (GC), in particular alkaline-earth alumino silicate based glasses and GCs, are becoming the most promising materials for gas-tight sealing applications in SOFCs. Besides the development of new glass-based materials, new additional concepts are required to overcome the challenges being faced by the currently existing sealant technology. The present work deals with the development of glasses- and GCs-based materials to be used as a sealants for SOFCs and other electrochemical functional applications. In this pursuit, various glasses and GCs in the field of diopside crystalline materials have been synthesized and characterized by a wide array of techniques. All the glasses were prepared by melt-quenching technique while GCs were produced by sintering of glass powder compacts at the temperature ranges from 800−900 ºC for 1−1000 h. Furthermore, the influence of various ionic substitutions, especially SrO for CaO, and Ln2O3 (Ln=La, Nd, Gd, and Yb), for MgO + SiO2 in Al-containing diopside on the structure, sintering and crystallization behaviour of glasses and properties of resultant GCs has been investigated, in relevance with final application as sealants in SOFC. From the results obtained in the study of diopside-based glasses, a bilayered concept of GC sealant is proposed to overcome the challenges being faced by (SOFCs). The systems designated as Gd−0.3 (in mol%: 20.62MgO−18.05CaO−7.74SrO−46.40SiO2−1.29Al2O3 − 2.04 B2O3−3.87Gd2O3) and Sr−0.3 (in mol%: 24.54 MgO−14.73 CaO−7.36 SrO−0.55 BaO−47.73 SiO2−1.23 Al2O3−1.23 La2O3−1.79 B2O3−0.84 NiO) have been utilized to realize the bi-layer concept. Both GCs exhibit similar thermal properties, while differing in their amorphous fractions, revealed excellent thermal stability along a period of 1,000 h. They also bonded well to the metallic interconnect (Crofer22APU) and 8 mol% yttrium stabilized zirconium (8YSZ) ceramic electrolyte without forming undesirable interfacial layers at the joints of SOFC components and GC. Two separated layers composed of glasses (Gd−0.3 and Sr−0.3) were prepared and deposited onto interconnect materials using a tape casting approach. The bi-layered GC showed good wetting and bonding ability to Crofer22APU plate, suitable thermal expansion coefficient (9.7–11.1 × 10–6 K−1), mechanical reliability, high electrical resistivity, and strong adhesion to the SOFC componets. All these features confirm the good suitability of the investigated bi-layered sealant system for SOFC applications.

Análise combinada dos efeitos dos revestimentos nas propriedades de fibras ópticas comerciais

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Consolidação da metodologia de manutenção centrada em confiabilidade em uma planta de celulose e papel

o setor de manutenção, em geral, é visto como uma das áreas mais propícias à implementação de melhorias na qualidade da gestão e dos serviços. Nesse campo, a Manutenção Centrada em Confiabilidade (MCC) tem apresentado bons resultados. A MCC é uma metodologia que permite determinar racionalmente o que deve ser feito para assegurar que um equipamento continue a cumprir suas funções em seu contexto operacional, determinando tarefas de manutenção, necessárias para manter o sistema funcionando, ao invés de restaurar o equipamento a uma condição ideal. A metodologia de implementação da MCC descrita neste trabalho contempla as seguintes etapas: (i) preparação do estudo; (ii) seleção do sistema e subsistemas funcionais; (iii) análise das funções e falhas funcionais; (iv) seleção dos itens críticos do subsistema; (v) coleta e análise de informações; (vi) análise de modos de falha e efeitos; (vii) seleção das tarefas de manutenção preventiva; e (viii) elaboração do plano de manutenção. o objetivo deste trabalho é consolidar as definições e etapas para implementação da MCC no setor de preparação de polpa da fábrica de pasta químico-mecânica (FPQM) da Celulose Irani S.A. Inicialmente, foi feita uma abordagem sobre os métodos de manutenção, discorrendo em específico sobre aqueles voltados à MCC. Em seguida, são apresentadas as definições, as principais ferramentas utilizadas pela MCC e a sistemática de implementação da MCC na visão de vários autores. Posteriormente, foi realizado um estudo de caso em que foram determinadas as tarefas de manutenção para manter as funções dos itens fisicos da FPQM. Nas etapas de implementação, são geradas informações sobre os subsistemas e são determinadas as funções, as falhas funcionais, os modos de falha, a causa e o efeito da falha e se faz a descrição do realizado em cada etapa, esclarecendo e ampliando a compreensão do leitor, diante da MCC. Os resultados obtidos demonstram que a metodologia da MCC é um processo contínuo e sua aplicação deve ser reavaliada conforme a experiência operacional for acumulada, e que, apesar da ausência de informações históricas sobre falhas de itens fisicos, a MCC permite definir planos de manutenção e aprimorar o conhecimento acerca do sistema em estudo.

Análise de confiabilidade de uma bomba centrífuga: aplicação na injeção de água para recuperação de petróleo

The oil industry`s need to produce with maximum efficiency, not to mention the safety and the environment aspects, encourages the optimization of processes. It makes them look for a level of excellence in acquisition of equipment, ensuring the quality without prejudice security of facilities and peoples. Knowing the reliability of equipment and that this stands for a system is fundamental to the production strategy to seeks the maximum return on investment. The reliability analysis techniques have been increasingly applied in the industry as strategy for predicting failures likelihood ensuring the integrity of processes. Some reliability theories underlie the decisions to use stochastic calculations to estimate equipment failure. This dissertation proposes two techniques associating qualitative (through expertise opinion) and quantitative data (European North Sea oil companies fault database, Ored) applied on centrifugal pump to water injection system for secondary oil recovery on two scenarios. The data were processed in reliability commercial software. As a result of hybridization, it was possible to determine the pump life cycle and what impact on production if it fails. The technique guides the best maintenance policy - important tool for strategic decisions on asset management.

Avaliação da confiabilidade utilizando programação orientada a objeto: aplicação em um sistema elétrico interligado a uma central de cogeração

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Análise de confiabilidade aplicada aos ensaios de óleos lubrificantes para motores de tratores

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Desenvolvimento de um sistema de instrumentação de medição de vibração mecânica em máquina rotativas, em tempo real, embarcado em FPGA

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análise da confiabilidade do ensaio de identificação de ligas através de espectrometria por fluorescência de raios x

In chemical industry, petrochemical and oil refinery may be found situations that working pressures and very high temperatures, and alloys that comprise such equipment must have specific characteristics such. As a way to ensure that the materials are as designed, companies have some specific techniques, and one of them is X-ray fluorescence spectrometry, which allows its application in devices small and lightweight, which ensures its portability in field use. This technique however, has some shortcomings such as the impossibility of detecting carbon and other elements of low atomic number which can generate false identifications of elements that are not in the league or non-detection of existing elements. Therefore, this study investigated the reliability of this method using the apparatus Niton XL3t 800 and may conclude that their results are reliable and can be used to assist in ensuring the operational integrity of the production units of these companies

Aplicação dos conceitos de RCM e a ferramenta FMEA no aumento de confiabilidade em equipamentos de uma indústria química

The growing demand for quality at competitive prices and fast production process put to the test function in the industrial Maintenance. The need for equipment with high availability to fit this fierce competitiveness makes maintenance becomes essentially reliable. Despite this current context, many companies still have an old view of maintenance, focused only on corrective services, and proposals for change are often neglected due to the sense of urgency day to day. Thus, this study aims to demonstrate through theoretical applicability of simple tool, but of great value in increasing reliability within the maintenance sector of an industry, applying the concepts of Reliability Centered Maintenance – RCM and Analysis tool Failure Modes and Effects – FMEA in equipment of a chemical company directly involved in the manufacturing process of the brake fluid, which this product is used in vehicles around the country. That way, you can identify the types, occurrence and criticality of each failure and evaluate assertively decision making for each device, avoiding unnecessary downtime and potential failures of the same

Analise de defeitos em motores através de vibração mecânica: estudo de caso

Revolving machines are among the most used equipment in general industry and therefore expenditures on this equipment class are a significant portion of the total amount spent by the company. If there is an unscheduled stop of some of this equipment, industrial plants can lose huge amounts of money caused by interrupted production and parts delay. Others may increase significantly maintenance costs due to consequences elsewhere not affected before. Even plant and people safety can be in danger if there is an operation interruption without a backup system start. This work is focused on a rotating system case study which is monitored by vibration analysis that shows that is possible to determine when is the most appropriate time for equipment intervention without any reliability loss just by using a simple and cheap system which is not much used because professionals are not aware to its utility. Industrial facilities were evaluated by fail detection and historical analysis in some equipment in order to show feasibility of vibration analysis through a before-during-after process. The plant evaluated is part of a chemical multinational located in Guaratinguetá-SP. At this time, that plant had around 650 critical equipment monthly monitored and no unscheduled shutdown was registered in one year period due to equipment monitoring

Análise da confiabilidade de equipamentos em uma indústria química com aplicações de ferramentas da melhoria contínua

The constant search for improvements and the survival of organizations makes the strategic guidelines are deployed and executed at the operational levels. This work is the approach to critical analysis of the equipment of a chemical industry through a case study based on the classification of each equipment manufactures through qualitative and quantitative analysis on the pillars of maintenance costs, loss of production, MTBF, contribution margin, Health Safety and Environment (SHE). From this study and future data collection, along with the flow diagram show the main equipment that should be special attention. To this can be prepared an action plan with deadlines and responsible. With the results one can measure the maintenance costs, loss of production and technical availability of the plant, with future gains

Gestão da Manutenção Centrada na Confiabilidade em Pontes Rolantes

The objective of this work is to perform a study applying the methodology of Reliability Centered Maintenance - MCC to a group of cranes belonging to Amsted -Maxion in Cruzeiro - SP. The work consists of a presentation of maintenance, the reasons why more and more people worry about maintenance, making a presentation on the types of maintenance, its peculiar characteristics and then do a study where you identified the functionality required by the equipment under study, identified failure modes and their probable causes, and then detail the effects and consequences of these failures. With that evaluate the criticality of these failures and identify the most significant consequences that affect safety, availability or cost of equipment operation and allow a selection of the most appropriate tasks for the identified failure modes. We will also present best crane equipment, its main components, verify that there was or not improvement in the machine after the application of MCC and make a current analysis of maintenance in Amsted -Maxion

Alteração do índice biespectral antes e após estimulação elétrica ou mecânica em cães anestesiados pelo isofluorano

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Análise de confiabilidade de um moto-ventilador centrífugo: aplicação no sistema de pressurização de subestação industrial para garantia da segurança operacional na indústria petroquímica

The need of the oil industry to ensure the safety of the facilities, employees and the environment, not to mention the search for maximum efficiency of its facilities, makes it seeks to achieve a high level of excellence in all stages of its production processes in order to obtain the required quality of the final product. Know the reliability of equipment and what it stands for a system is of fundamental importance for ensuring the operational safety. The reliability analysis technique has been increasingly applied in the oil industry as fault prediction tool and undesirable events that can affect business continuity. It is an applied scientific methodology that involves knowledge in engineering and statistics to meet and or analyze the performance of components, equipment and systems in order to ensure that they perform their function without fail, for a period of time and under a specific condition. The results of reliability analyzes help in making decisions about the best maintenance strategy of petrochemical plants. Reliability analysis was applied on equipment (bike-centrifugal fan) between the period 2010-2014 at the Polo Petrobras Guamaré Industrial, situated in rural Guamaré municipality in the state of Rio Grande do Norte, where he collected data field, analyzed historical equipment and observing the behavior of faults and their impacts. The data were processed in commercial software reliability ReliaSoft BlockSim 9. The results were compared with a study conducted by the experts in the field in order to get the best maintenance strategy for the studied system. With the results obtained from the reliability analysis tools was possible to determine the availability of the centrifugal motor-fan and what will be its impact on the security of process units if it will fail. A new maintenance strategy was established to improve the reliability, availability, maintainability and decreased likelihood of Moto-Centrifugal Fan failures, it is a series of actions to promote the increased system reliability and consequent increase in cycle life of the asset. Thus, this strategy sets out preventive measures to reduce the probability of failure and mitigating aimed at minimizing the consequences.