Color and structural analysis of CoxZn7-xSb2O12 pigments

The polymeric precursor method was successfully used to synthesize CoxZn7-xSbO12 (x = 0-7) powders. Pigments were evaluated using colorimetry, X-ray diffraction, UV-vis and infrared spectroscopy. The optical band gap values vary with the Co2+ substitution. These results suggest that the concomitant presence of Co and Zn in the spinel lattice leads to the rupture of the Vegard law, as well as other properties of the studied system, such as unit cell volume. The Co-richer samples display a higher absorbance than the Co-lean samples. The high absorption of the Co7Sb2O12 sample at most of the visible region makes this compound a candidate for a black pigment. It was shown that color depends on the site where the chromophore ion is located, in agreement with the ligand field theory. (c) 2006 Elsevier Ltd. All rights reserved.

The influence of temperature on the color of TiO2:Cr pigments

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Absorption and luminescent excitation spectra of F and M centers in Kcl and NaF

Luminescent excitation spectra were measured for the F and M centers in KCl; in particular, for the F band, M band, and the M2 transition. In all 3 cases, the spectra were nearly double-Gaussian in shape, and the efficiency for luminescence was nearly independent of the wavelength of the exciting light. A comparison of the absorption spectrum with the excitation spectrum of the F-band region of crystals with M centers present and oriented provided further evidence for the existence of the M2 transition of van Doorn and Haven and of Okamoto, and against the energy transfer theory of Lambe and Compton. The efficiency for luminescence of the M center upon M-band excitation was equal to the efficiency for F centers in pulse-annealed crystals of low F-center concentrations. The ratio of the efficiencies of the Ml to M2 transitions was 1.2 ± .25. The oscillator strengths of 3 of the M-center transitions in KCl relative to the oscillator strength for the F center were found to be in better agreement with the results reported by Okamoto, than with the results reported by Delbecq. The polarization of luminescence of M centers in KCl was measured at right angles to the exciting light, and was found to agree with the predictions of the van Doorn-Haven model of the M center. In NaF crystals having no absorption bands to the red side of the M band, the absorption and excitation spectra of the M band were accurately double-Gaussian over a wide range of wavelengths; the efficiency of luminescence of the M center was independent of the wavelength of the exciting light in that range; and the polarization of luminescence upon M-band excitation agreed well with the calculations based on the van DoornHaven model of the M center, In crystals in which the F band was bleached sufficiently to make it smaller in absorption height than the M band, several new color centers appeared on the red side of the M band, in contrast to the results reported by Blum; in these crystals, the polarization of luminescence of the M center upon M-band excitation disagreed strongly with theory, even though the absorptions for the new color centers were small compared to the M-band absorption.

Photo-Induced Dipole Relaxation Current in Natural Amethyst

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Production of defects in ZBLAN, ZBLAN : Tm3+ and ZBLAN : Cr3+ glasses by ultra-short pulses laser interaction

In this work we have studied pure and thulium- and chromium-doped ZBLAN glasses irradiated by ultra-short laser pulses. A Ti:sapphire CPA system was used, producing a 500 Hz train of pulses, centered at 830 nm, with 375 mu J of energy and 50 fs of duration (FWHM). The beam was focused by a 20 Him lens, producing a converging beam with a waist of 12 pin. The absorption spectra before and after laser irradiation were obtained showing production of color centers in pure, thulium-doped and chromium-doped ZBLAN glasses. A damage threshold of 9.56 TW/cm(2) was determined for ZBLAN. (C) 2007 Elsevier Ltd. All rights reserved.

Investigação das propriedades ópticas, elétricas e estruturais em ametista

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Lifetime of silica final lenses subject to HiPER irradiation conditions

The goal of the European laser fusion project, is to build an engineering facility for repetitive laser operation (HiPER 4a) and later a fusion reactor (HiPER 4b). A key aspect for laser fusion energy is the final optics. At the moment, it is based on silica transmission lenses located 8 m away from the chamber center. Lens lifetime depends on the irradiation conditions. We have used a 48 MJ shock ignition target for calculations. We have studied the thermo-mechanical effects of ions and X-rays on the lenses. Ions lead to lens melting and must therefore be mitigated. On the other hand, X-rays (~1% of the energy) does not produce either a significant temperature rise or detrimental stresses. Finally, we calculated the neutron flux and gamma dose rate on the lenses. Next, based on a simple model we studied the formation of color centers in the sample, which lead to optical absorption. Calculations show that simultaneous neutron and gamma irradiation does not significantly increase the optical absorption during the expected lifetime of the HiPER 4a facility. Under severe conditions (HiPER 4b), operation above 800 K or lens refreshing by thermal annealing treatments seem to assure adequate behavior.

Ionoluminescence on α-quartz: mechanisms and modeling

Ionoluminescence of α - quartz exhibits two dominant emission bands peaking at 1.9 eV. (NBOHCs) and 2.7 eV (STEs. The evolution of the red emission yield does not show a correlation with the concentrations of neither the NBOHC nor with that of other color centers. The blue emission yield closely follows the amorphization kinetics independently measured by RBS/C spectrometry. A simple theoretical model has been proposed; it assumes that the formation and recombination of STEs are the primary event and both, the light emissions and the lattice structural damage are a consequence this phenomenon. The model leads to several simple mathematical equations that can be used to simulate the IL yields and provide a reasonable fit to experimental kinetic data.

Large scale fabrication of nitrogen vacancy-embedded diamond nanostructures for single-photon source applications

Some color centers in diamond can serve as quantum bits which can be manipulated with microwave pulses and read out with laser, even at room temperature. However, the photon collection efficiency of bulk diamond is greatly reduced by refraction at the diamond/air interface. To address this issue, we fabricated arrays of diamond nanostructures, differing in both diameter and top end shape, with HSQ and Cr as the etching mask materials, aiming toward large scale fabrication of single-photon sources with enhanced collection efficiency made of nitrogen vacancy (NV) embedded diamond. With a mixture of O2 and CHF3 gas plasma, diamond pillars with diameters down to 45 nm were obtained. The top end shape evolution has been represented with a simple model. The tests of size dependent single-photon properties confirmed an improved single-photon collection efficiency enhancement, larger than tenfold, and a mild decrease of decoherence time with decreasing pillar diameter was observed as expected. These results provide useful information for future applications of nanostructured diamond as a single-photon source.

Color Dependence on Thickness in Topaz Crystal from Brazil

It is well known that crystals of topaz from the Eastern Brazilian Pegmatite Province may turn blue by the irradiation with Co-60 gamma rays followed by heat treatment. Also, it is known that the sensation of color changes with the thickness of these crystals. The dependence of the color, given by 1931 CIE chromaticity coordinates, with the thickness of the crystal was analyzed. The absorbance used in the calculation of these coordinates was given by the sum of Gaussian lines. The parameters of these lines were determined through the decomposition of the optical absorption spectra in the ultraviolet and visible regions. The decomposition revealed several lines, whose assignment was made considering studies in spodumene and beryl crystals and highly accurate quantum mechanical calculations. The transmittance becomes very narrow with increasing thickness, and the CIE chromaticity coordinates converge to the borderline of the CIE Chromaticity Diagram at the wavelength of maximum transmittance. Furthermore, the purity of color increases with increasing thickness, and the dominant wavelength reaches the wavelength of maximum transmittance.

Mercado de trabajo y condicionamiento por color de piel en grandes centros urbanos de la Argentina

La discriminación por aspecto físico, y más en particular, el trato diferenciado hacia personas cuyos rasgos remiten a un origen entendido como indígena o no-europeo, constituye un problema escasamente tratado en los estudios de la desigualdad en la Argentina. Esta carencia, sumada a la falta de una articulación en las explicaciones de estos mecanismos relacionados con las desigualdades derivadas de las condiciones de clase, con frecuencia opacan el estudio del fenómeno profundizando sus efectos de invisibilidad. En este sentido, se mantienen ocultas las dificultades que afrontan quienes poseen estos rasgos para sobreponerse a prejuicios que reeditan cotidianamente principios racistas que asocian los rasgos nativos con la delincuencia, la falta de capacidades y saberes y, en términos generales, con la inferioridad socialmente entendida. En este artículo se investiga la incidencia del trato desigual basado en el aspecto físico -en particular, en el color de piel- sobre los logros laborales en una muestra de 2.500 personas de grandes centros urbanos de la Argentina en el año 2007. La discriminación por rasgos físicos, como efecto de la persistencia de principios operativos basados en la racialización de las interacciones sociales, pone de manifiesto la continuidad de principios jerárquicos, simbólicos y materiales que obstruyen la posibilidad de una mayor igualdad en el desarrollo cotidiano de las condiciones de vida de las personas

Mercado de trabajo y condicionamiento por color de piel en grandes centros urbanos de la Argentina

La discriminación por aspecto físico, y más en particular, el trato diferenciado hacia personas cuyos rasgos remiten a un origen entendido como indígena o no-europeo, constituye un problema escasamente tratado en los estudios de la desigualdad en la Argentina. Esta carencia, sumada a la falta de una articulación en las explicaciones de estos mecanismos relacionados con las desigualdades derivadas de las condiciones de clase, con frecuencia opacan el estudio del fenómeno profundizando sus efectos de invisibilidad. En este sentido, se mantienen ocultas las dificultades que afrontan quienes poseen estos rasgos para sobreponerse a prejuicios que reeditan cotidianamente principios racistas que asocian los rasgos nativos con la delincuencia, la falta de capacidades y saberes y, en términos generales, con la inferioridad socialmente entendida. En este artículo se investiga la incidencia del trato desigual basado en el aspecto físico -en particular, en el color de piel- sobre los logros laborales en una muestra de 2.500 personas de grandes centros urbanos de la Argentina en el año 2007. La discriminación por rasgos físicos, como efecto de la persistencia de principios operativos basados en la racialización de las interacciones sociales, pone de manifiesto la continuidad de principios jerárquicos, simbólicos y materiales que obstruyen la posibilidad de una mayor igualdad en el desarrollo cotidiano de las condiciones de vida de las personas

Mercado de trabajo y condicionamiento por color de piel en grandes centros urbanos de la Argentina

La discriminación por aspecto físico, y más en particular, el trato diferenciado hacia personas cuyos rasgos remiten a un origen entendido como indígena o no-europeo, constituye un problema escasamente tratado en los estudios de la desigualdad en la Argentina. Esta carencia, sumada a la falta de una articulación en las explicaciones de estos mecanismos relacionados con las desigualdades derivadas de las condiciones de clase, con frecuencia opacan el estudio del fenómeno profundizando sus efectos de invisibilidad. En este sentido, se mantienen ocultas las dificultades que afrontan quienes poseen estos rasgos para sobreponerse a prejuicios que reeditan cotidianamente principios racistas que asocian los rasgos nativos con la delincuencia, la falta de capacidades y saberes y, en términos generales, con la inferioridad socialmente entendida. En este artículo se investiga la incidencia del trato desigual basado en el aspecto físico -en particular, en el color de piel- sobre los logros laborales en una muestra de 2.500 personas de grandes centros urbanos de la Argentina en el año 2007. La discriminación por rasgos físicos, como efecto de la persistencia de principios operativos basados en la racialización de las interacciones sociales, pone de manifiesto la continuidad de principios jerárquicos, simbólicos y materiales que obstruyen la posibilidad de una mayor igualdad en el desarrollo cotidiano de las condiciones de vida de las personas

Photochemically induced nuclear spin polarization in reaction centers of photosystem II observed by 13C-solid-state NMR reveals a strongly asymmetric electronic structure of the P680.+ primary donor chlorophyll

We report 13C magic angle spinning NMR observation of photochemically induced dynamic nuclear spin polarization (photo- CIDNP) in the reaction center (RC) of photosystem II (PS2). The light-enhanced NMR signals of the natural abundance 13C provide information on the electronic structure of the primary electron donor P680 (chlorophyll a molecules absorbing around 680 nm) and on the pz spin density pattern in its oxidized form, P680⨥. Most centerband signals can be attributed to a single chlorophyll a (Chl a) cofactor that has little interaction with other pigments. The chemical shift anisotropy of the most intense signals is characteristic for aromatic carbon atoms. The data reveal a pronounced asymmetry of the electronic spin density distribution within the P680⨥. PS2 shows only a single broad and intense emissive signal, which is assigned to both the C-10 and C-15 methine carbon atoms. The spin density appears shifted toward ring III. This shift is remarkable, because, for monomeric Chl a radical cations in solution, the region of highest spin density is around ring II. It leads to a first hypothesis as to how the planet can provide itself with the chemical potential to split water and generate an oxygen atmosphere using the Chl a macroaromatic cycle. A local electrostatic field close to ring III can polarize the electronic charge and associated spin density and increase the redox potential of P680 by stabilizing the highest occupied molecular orbital, without a major change of color. This field could be produced, e.g., by protonation of the keto group of ring V. Finally, the radical cation electronic structure in PS2 is different from that in the bacterial RC, which shows at least four emissive centerbands, indicating a symmetric spin density distribution over the entire bacteriochlorophyll macrocycle.

Variables Associated With The Performance Of Centers For Dental Specialties In Brazil.

The aim of this study was to evaluate the performance of the Centers for Dental Specialties (CDS) in the country and associations with sociodemographic indicators of the municipalities, structural variables of services and primary health care organization in the years 2004-2009. The study used secondary data from procedures performed in the CDS to the specialties of periodontics, endodontics, surgery and primary care. Bivariate analysis by χ2 test was used to test the association between the dependent variable (performance of the CDS) with the independents. Then, Poisson regression analysis was performed. With regard to the overall achievement of targets, it was observed that the majority of CDS (69.25%) performance was considered poor/regular. The independent factors associated with poor/regular performance of CDS were: municipalities belonging to the Northeast, South and Southeast regions, with lower Human Development Index (HDI), lower population density, and reduced time to deployment. HDI and population density are important for the performance of the CDS in Brazil. Similarly, the peculiarities related to less populated areas as well as regional location and time of service implementation CDS should be taken into account in the planning of these services.