Relationship between static and dynamic elastic modulus of calcarenite heated at different temperatures: the San Julián's stone

The San Julián’s stone is the main material used to build the most important historical buildings in Alicante city (Spain). This paper describes the analysis developed to obtain the relationship between the static and the dynamic modulus of this sedimentary rock heated at different temperatures. The rock specimens have been subjected to heating processes at different temperatures to produce different levels of weathering on 24 specimens. The static and dynamic modulus has been measured for every specimen by means of the ISRM standard and ultrasonic tests, respectively. Finally, two analytic formulas are proposed for the relationship between the static and the dynamic modulus for this stone. The results have been compared with some relationships proposed by different researchers for other types of rock. The expressions presented in this paper can be useful for the analysis, using non-destructive techniques, of the integrity level of historical constructions built with San Julián’s stone affected by fires.

Temperature influence on the physical and mechanical properties of a porous rock: San Julian's calcarenite

This work discusses the results from tests which were performed in order to study the effect of high temperatures in the physical and mechanical properties of a calcarenite (San Julian's stone). Samples, previously heated at different temperatures (from 105 °C to 600 °C), were tested. Non-destructive tests (porosity and ultrasonic wave propagation) and destructive tests (uniaxial compressive strength and slake durability test) were performed over available samples. Furthermore, the tests were carried out under different conditions (i.e. air-cooled and water-cooled) in order to study the effect of the fire off method. The results show that uniaxial compressive strength and elastic parameters (i.e. elastic modulus and Poisson's ratio), decrease as the temperature increases for the tested range of temperatures. A reduction of the uniaxial compressive strength up to 35% and 50% is observed in air-cooled and water-cooled samples respectively when the samples are heated to 600 °C. Regarding the Young's modulus, a fall over 75% and 78% in air-cooled and water-cooled samples respectively is observed. Poisson's ratio also declines up to 44% and 68% with the temperature in air-cooled and water-cooled samples respectively. Slake durability index also exhibits a reduction with temperature. Other physical properties, closely related with the mechanical properties of the stone, are porosity, attenuation and propagation velocity of ultrasonic waves in the material. All exhibit considerable changes with temperature.

Efects of mineral suspension and dissolution on strength and compressibility of soft carbonate rocks

© 2014 Elsevier B.V.Calcarenites are highly porous soft rocks formed of mainly carbonate grains bonded together by calcite bridges. The above characteristics make them prone to water-induced weathering, frequently featuring large caverns and inland natural underground cavities. This study is aimed to determine the main physical processes at the base of the short- and long-term weakening experienced by these rocks when interacting with water. We present the results of microscale experimental investigations performed on calcarenites from four different sites in Southern Italy. SEM, thin sections, X-ray CT observations and related analyses are used for both the interpretation-definition of the structure changes, and the identification-quantification of the degradation mechanisms. Two distinct types of bonding have been identified within the rock: temporary bonding (TB) and persistent bonding (PB). The diverse mechanisms linked to these two types of bonding explain both the observed fast decrease in rock strength when water fills the pores (short-term effect of water), identified with a short-term debonding (STD), and a long-term weakening of the material, when the latter is persistently kept in water-saturated conditions (long-term effect of water), identified with a long-term debonding (LTD). To highlight the micro-hydro-chemo-mechanical processes of formation and annihilation of the TB bonds and their role in the evolution of the mechanical strength of the material, mechanical tests on samples prepared by drying partially saturated calcarenite powder, or a mix of glass ballotini and calcarenite powder were conducted. The long-term debonding processes have also been investigated, using acid solutions in order to accelerate the reaction rates. This paper attempts to identify and quantify differences between the two types of bonds and the relative micro-scale debonding processes leading to the macro-scale material weakening mechanisms.

Sequence stratigraphy related distribution of diagenetic alterations In Miocene deltaic and shoreface arenites, the Suez Rift, EGYPT.

The distribution of eogenetic alterations in shoreface-offshore and coarse-grained deltaic, calcarenite to hybrid arenites of the Mheiherrat Formation (lower Rudeis), Early Miocene, the Gulf of Suez, Egypt) can be constrained within a sequence stratigraphic framework. The bioclast-rich, shoreface (trangressive systems tract; TST) and shoreface (highstand systems tract; HST) arenites, particularly those below the parasequence boundaries and maximum flooding surface, are cemented by grain-coating microcrystalline, circumgranular isopacheous acicular and columnar, and coarse-crystalline calcite (δ18OVPDB = -3.6 to -0.3 ‰; δ13CVPDB = -2.3 to -0.7 ‰), non-Ferro an dolomite (δ18OVPDB = -3.9 to +0.9‰; δ13CVPDB = -2.5 ‰ to -0.7 ‰), and pyrite. Zeolite, palygorskite and gypsum occur in the HST shoreface arenites, being enhanced by aird climatic condations. The coarse-grained deltaic LST deposits are pervasively cemented by coarse-crystalline, pore-filling calcite and small amounts of microcrystalline calcite (δ18OVPDB = -4.4 to -2.3 ‰; δ13CVPDB = -2.8 to -1.3 ‰) and non-ferroan dolomite (δ18OVPDB = -4.8 to -2.5 ‰; δ13CVPDB = -3.3 to -1.5 ‰). Thus, this study demonstrates that changes in pore-water chemistry, which induced changes in the texture, composition and extent of cementation in the Miocene arenites was controlled by changes in the relative sea level and by the paleo-climatic conditions during deposition of the HST arenites.

Sequence stratigraphy related distribution of diagenetic alterations In Miocene deltaic and shoreface arenites, the Suez Rift, EGYPT.. Available from: https://www.researchgate.net/publication/264545153_Sequence_stratigraphy_related_distribution_of_diagenetic_alterations_In_Miocene_deltaic_and_shoreface_arenites_the_Suez_Rift_EGYPT [accessed Apr 15, 2015].

Interpretação tectono-estratigráfica do reservatório Quissamã (Eo-meso-albiano) nos campos de Pampo, Bicudo e Bonito, Bacia de Campos

Hydrocarbon accumulations occur in marine carbonate reservoirs of Quissamã Formation (early to midlle Albian), southwest Campos Basin. We investigated Pampo, Bicudo and Bonito fields, in order to understand the tectono-structural framework of oncolite/bioclast coarse-grained calcarenite reservoir and the calcilutite-marl-shale sealing interval (Late Albian to Turonian). The database of eleven wells from those fields allowed to elaborate structural sections correlating the Macaé Group – both Quissamã reservoir and Outeiro seal, the latter corresponding to the tectonic deepening phase of basin evolution. Based on density and electric logs, it was prepared structural sections of the carbonate reservoirs with consequent identification of porous zones and oil-water contacts. An extensive 3-D seismic database (~300 Km2) allowed to map three reflectors which represent the limiting units of Macaé Group

Mapeamento da ilha da Trindade, Atlântico Sul

The area chosen for this study is the island of Trinidade, which is located 1167 km off the Brazilian coast, in parallel Victory at 20 ° 30'S and 29 º 19'W, being the most easterly point of our continent. The isolation of oceanic island of Trinidade leaves no noticeable that she is part of a large submarine volcanic chain oriented east-west lineament known as Vitória- Trindade. Along with the island of Martin Vaz, who is Federal Territory is administered by the Navy of Brazil. Both correspond to Source alkaline volcanic islands. The area of the island of Trinidad has approximately 10 km2. Geologically consisting ankaratritic spills, spills tannbuschiticos, volcanic tuff spills analcite-ankaratrite, phonolite spills, spills nefelinite, pyroclastics, spills grazinite, tinguaitos, olivine-analcitito, calcarenite dunes and wind according to Almeida (1961). The island has its base on the ocean floor, at 5,800 m depth. It is the only place still recognizes preserved volcanic necks and plugs, as well as remnants of a volcano in Brazil. Magmatism occurred here a sodium alkali-silica subsaturated where his wrist was last 50,000 years according to Almeida (1961). It is a place with restricted access due to their distance from the coast, his contribution and hard to be an exclusive area of the Navy. On the island with peaks occur up to 620 meters high, and its rugged mountainous terrain and difficult access to very specific points, as the peak of Desire, peak Fazendinha, Monument and other points on the island. Because of its location far from the coast, its small infrastructure, difficulty of landing and restricted access by sea, the island of Trinidad offers no possibility of tourism, being a military outpost, and scientific basis of great importance, which conduct research in area of marine biology, oceanography, geology and others

Macroturbidites of ODP Hole 103-641C

Barremian through uppermost Aptian strata from ODP Hole 641C, located upslope of a tilted fault block on the Galicia margin (northwest Spain), are syn-rift sediments deposited in the bathyal realm and are characterized by rapid sedimentation from turbidity currents and debris flows. Calcarenite and calcirudite turbidites contain shallow-water carbonate, terrigenous, and pelagic debris, in complete or partial Bouma sequences. These deposits contain abraded micritized bioclasts of reefal debris, including rudist fragments. The youngest turbidite containing shallow-water carbonate debris at Site 641 defines the boundary between syn-rift and post-rift sediments; this is also the boundary between Aptian and Albian sediments. Some Aptian turbidites are partially silicified, with pore-filling chalcedony and megaquartz. Adjacent layers of length-fast and -slow chalcedony are succeeded by megaquartz as the final pore-filling stage within carbonate reef debris. Temperatures of formation, calculated from the oxygen isotopic composition of the authigenic quartz, are relatively low for formation of quartz but are relatively warm for shallow burial depths. This quartz cement may be interpreted as a rift-associated precipitate from seawater-derived epithermal fluids that migrated along a fault associated with the tilted block and were injected into the porous turbidite beds. These warm fluids may have cooled rapidly and precipitated silica at the boundaries of the turbidite beds as a result of contact with cooler pore waters. The color pattern in the quartz cement, observed by cathodoluminescence and fluorescence techniques, and changes in the trace lement geochemistry mimic the textural change of the different quartz layers and indicates growth synchronism of the different quartz phases. Fluorescence petrography of neomorphosed low-Mg-calcite bioclasts in the silicified turbidites shows extensive zonation and details of replacive crystal growth in the bioclasts that are not observed by cathodoluminescence. Fluorescence microscopy also reveals a competitive growth history during neomorphism of the adjacent crystals in an altered carbonate bioclast. Barremian-Aptian background pelagic sediments from Hole 641C have characteristics similar to pelagic sediments from the Blake-Bahama Formation described by Jansa et al. (1979) from the western North Atlantic. Sediments at this site differ from the Blake-Bahama Formation type locality in that the Barremian-Aptian pelagic sediments have a higher percentage of dark calcareous claystone and some turbidites are silicified at Site 641. The stable isotopic composition of the pelagic marlstones from Site 641 is similar to those of other Berriasian-Aptian pelagic sediments from the Atlantic.

Study of the foundations, bearing soil and stability of the minaret-tower of Cordobas Mosque

This research in Cordoba's mosque tower main objective was to analyze and characterize the foundations and the underlying soil, calculating the stability of the monument as well as the settlement and deformations performed, using traditional calculation methods and also by finite elements, and to determine differences between both, as well as the stability factor of the Minaret Tower. The works done to study the soil, were drill bores and dynamic penetration tests, classification of samples by size, Atterberg limits, physical and chemical analysis, showing the typical geotechnical composition of the Guadalquivir valley: an alluvial material composed by sand, gravels and silt clays. To study the foundations, inclined bore samples were extracted with 10-65º, showing calcarenite stone ashlars and lime concrete alternating with stone and brick masonry.

Estudio de la fluencia de una calcarenita: la Piedra de San Julián (Alicante)

La fluencia de las rocas tiene gran importancia en la evaluación del comportamiento a largo plazo de elementos construidos con estos materiales. En este trabajo, se ha caracterizado física y mecánicamente una calcarenita porosa bien conocida localmente como Piedra de San Julián. Se han realizado ensayos de compresión uniaxial de 96 h. a carga constante. Se ha utilizado un modelo de fluencia bien conocido, el Código-modelo CEB-FIP 2010, usado para modelizar otro material pétreo (hormigón). Además, se ha propuesto un modelo reológico. El objetivo principal de este trabajo es investigar la posibilidad de aprovechar la gran experiencia acumulada en el estudio del hormigón, con el fin de obtener un enfoque para el comportamiento de la roca, para tiempos de prueba muy largos difíciles de implementar en laboratorio. Se propone una función de fluencia adaptada a la roca estudiada dependiente sólo de sus características elásticas y mecánicas.

Propiedades físicas y mecánicas de una calcarenita: la Piedra de San Julián

En este trabajo se estudian las características físico-mecánicas de la Piedra de San Julián y su comportamiento frente a procesos de calentamiento a temperaturas similares a las alcanzadas en un incendio, así como la puesta a punto y validación de métodos dinámicos no destructivos para el dictamen del estado de desgaste del material. El enfoque está orientado a los parámetros que más interesan en la utilización de la Piedra como material de construcción. Dado que esta Tesis se realiza por compendio de artículos, por razones prácticas y necesidades de publicación, el contenido de la misma está dividido en tres grandes bloques, como son: fluencia, exposición a altas temperaturas y relación entre módulos estáticos y dinámicos. Para el estudio de la fluencia o deformabilidad a largo plazo bajo carga constante se han realizado ensayos de carga estáticos de larga duración. Por otra parte, se ha efectuado un análisis del comportamiento reológico del hormigón en las distintas normativas, especialmente en el Código Modelo FIB (2010), y se ha buscado un paralelismo entre las previsiones del Código y los resultados obtenidos en los ensayos. Al mismo tiempo se han probado varios modelos reológicos que reproduzcan de forma precisa el comportamiento de la fluencia según el Código y los ensayos. Esto ha permitido ajustar una función, adaptando las especificaciones del Código modelo, que describe la deformación en el tiempo de la Piedra de San Julián. La validez teórica de esta ecuación alcanza períodos temporales similares a los existentes para los ensayos realizados con hormigón. El modelo reológico que se ha obtenido por ajuste de todo el período anterior, consta de cuatro celdas de Kelvin y predice igualmente la deformación por fluencia de la roca. La correcta evaluación de las deformaciones a largo plazo es necesaria siempre que se estudie la intervención en edificaciones históricas, bien sea variando la distribución de cargas, o simplemente realizando obras de mantenimiento de cierto calado. La influencia de la temperatura alcanzada y del proceso de enfriamiento utilizado, se ha analizado sobre 55 muestras de roca calentando a temperaturas de hasta 600 ºC y enfriando por dos métodos: al aire y mediante inmersión en agua, ambas a temperatura ambiente. Los parámetros controlados antes y después del proceso térmico han sido: porosidades abierta y total velocidad de propagación de ondas ultrasónicas, módulo de elasticidad, coeficiente de Poisson, resistencia a compresión uniaxial (UCS) y durabilidad según el ensayo de sequedad, humedad y desmoronamiento, Slake Durability Test (SDT). Como conclusiones más notables cabe destacar: la UCS disminuye en un 35% y en un 5O% según el enfriamiento se haya realizado al aire o por inmersión, mientras que el módulo de elasticidad se reduce entre un 75% y un 80%. Las conclusiones obtenidas son importantes para la determinación del daño estructural producido en un incendio, así como para evaluar la influencia del método de extinción. Por otra parte, pueden servir para estimar indirectamente la temperatura máxima alcanzada en un incendio, de cara a la determinación de los posibles efectos sobre otros elementos constructivos. Para la relación entre módulos estáticos y dinámicos se han estudiado 24 muestras con diferentes grados de deterioro. Con los datos obtenidos en los ensayos se han analizado estadísticamente quince modelos de relación con diferentes combinaciones de variables, y se ha construido la correspondiente matriz de correlación. El coeficiente de determinación más alto corresponde a una relación lineal entre ambos módulos. La determinación del módulo de elasticidad por medios no destructivos y de fácil implementación es muy útil cuando se trata de dictaminar sobre el envejecimiento de un material estructural de este tipo. El valor del módulo con respecto al de la roca intacta es un indicador de las características resistentes y grado de debilitamiento del material. Sin embargo, el módulo bajo cargas gravitatorias -estáticas- difiere en general del obtenido dinámicamente, de una manera diferente según el material que se analice. Aquí se ha obtenido una expresión, que correlaciona con un alto valor del coeficiente de determinación ambos módulos, para la roca estudiada. Los parámetros, relaciones y modelos estudiados y propuestos en esta tesis, suponen un importante avance científico de gran utilidad para la conservación y restauración del patrimonio de edificios y otras obras de carácter histórico-cultural construidas con la Piedra de San Julián. Asimismo, las conclusiones obtenidas y los medios y métodos empleados podrán ser extrapolados a otros materiales similares con las adaptaciones oportunas.

The deterioration of Circular Mausoleum, Roman Necropolis of Carmona, Spain

The Circular Mausoleum tomb in the Roman Necropolis of Carmona was carved on a calcarenite sequence in an ancient quarry located in the town of Carmona, Southern Spain. This rock-cut tomb, representative of Roman burial practices, currently suffers from serious deterioration. A detailed survey over several years permitted the identification of the main tomb's pathologies and damaging processes, which include loss of material (scaling, flaking, granular disintegration), surface modifications (efflorescences, crusts and deposits) and extensive biological colonization. The results obtained in this study indicated that anthropogenic changes were largely responsible and enhanced the main alteration mechanisms observed in the Circular Mausoleum. Based on the deterioration diagnosis, effective corrective actions were proposed. This study shows that any conservative intervention in the interior of the tomb should be preceded by accurate in situ measurements and laboratory analyses to ascribe the source of the deterioration damages and thus designing effective treatments.

The influence of rock fabric in the durability of two sandstones used in the Andalusian Architectural Heritage (Montoro and Ronda, Spain)

Natural stone has been a popular and reliable building material throughout history appearing in many historic monuments and in more recent buildings. Research into the intrinsic properties of specific stones is important because it gives us a greater understanding of the factors that limit and act on them. This can help prevent serious problems from occurring in our buildings bringing both esthetic benefits and financial savings. To this end, the main objective of this research has been to study the influence of the fabric and the mineral composition of two types of sandstone on their durability. The first is a red continental sandstone from the Buntsandstein Age called “Molinaza Roja”, which is quarried in Montoro (Cordoba). The second is quarried in Ronda (Malaga) and is sold under the trade name of “Arenisca Ronda”. It is a light pink-whitish calcarenite deposited during the Late Tortonian to Late Messinian. We characterized their petrological and petrophysical properties by studying their rock fabrics, porous systems and mechanical properties. In order to obtain a complete vision of the behavior of their rock fabrics, we also carried out two decay tests, the salt crystallization and the freeze–thaw tests. We then measured the effects on the textures of the altered samples during and after the decay tests and we evaluated the changes in the porous system. By comparing the results between intact and altered samples, we found that Arenisca Ronda is less durable because it has a high quantity of expandable clays (smectites) and a high percentage of pores in the 0.1–1 μm range, in which the pressure produced by salt crystallization is strongest. In Molinaza Roja the decay agents caused significant sanding due to loss of cohesion between the clasts, especially during the salt crystallization test. In both stones, the anisotropies (oriented textures) have an important role in their hydric and dynamic behavior and also affect their mechanical properties (especially in the compression resistance). No changes in color were detected.