999 resultados para Biotecnologia - Industria
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Phenol and cresols represent a good example of primary chemical building blocks of which 2.8 million tons are currently produced in Europe each year. Currently, these primary phenolic building blocks are produced by refining processes from fossil hydrocarbons: 5% of the world-wide production comes from coal (which contains 0.2% of phenols) through the distillation of the tar residue after the production of coke, while 95% of current world production of phenol is produced by the distillation and cracking of crude oil. In nature phenolic compounds are present in terrestrial higher plants and ferns in several different chemical structures while they are essentially absent in lower organisms and in animals. Biomass (which contain 3-8% of phenols) represents a substantial source of secondary chemical building blocks presently underexploited. These phenolic derivatives are currently used in tens thousand of tons to produce high cost products such as food additives and flavours (i.e. vanillin), fine chemicals (i.e. non-steroidal anti-inflammatory drugs such as ibuprofen or flurbiprofen) and polymers (i.e. poly p-vinylphenol, a photosensitive polymer for electronic and optoelectronic applications). European agrifood waste represents a low cost abundant raw material (250 millions tons per year) which does not subtract land use and processing resources from necessary sustainable food production. The class of phenolic compounds is essentially constituted by simple phenols, phenolic acids, hydroxycinnamic acid derivatives, flavonoids and lignans. As in the case of coke production, the removal of the phenolic contents from biomass upgrades also the residual biomass. Focusing on the phenolic component of agrifood wastes, huge processing and marketing opportunities open since phenols are used as chemical intermediates for a large number of applications, ranging from pharmaceuticals, agricultural chemicals, food ingredients etc. Following this approach we developed a biorefining process to recover the phenolic fraction of wheat bran based on enzymatic commercial biocatalysts in completely water based process, and polymeric resins with the aim of substituting secondary chemical building blocks with the same compounds naturally present in biomass. We characterized several industrial enzymatic product for their ability to hydrolize the different molecular features that are present in wheat bran cell walls structures, focusing on the hydrolysis of polysaccharidic chains and phenolics cross links. This industrial biocatalysts were tested on wheat bran and the optimized process allowed to liquefy up to the 60 % of the treated matter. The enzymatic treatment was also able to solubilise up to the 30 % of the alkali extractable ferulic acid. An extraction process of the phenolic fraction of the hydrolyzed wheat bran based on an adsorbtion/desorption process on styrene-polyvinyl benzene weak cation-exchange resin Amberlite IRA 95 was developed. The efficiency of the resin was tested on different model system containing ferulic acid and the adsorption and desorption working parameters optimized for the crude enzymatic hydrolyzed wheat bran. The extraction process developed had an overall yield of the 82% and allowed to obtain concentrated extracts containing up to 3000 ppm of ferulic acid. The crude enzymatic hydrolyzed wheat bran and the concentrated extract were finally used as substrate in a bioconversion process of ferulic acid into vanillin through resting cells fermentation. The bioconversion process had a yields in vanillin of 60-70% within 5-6 hours of fermentation. Our findings are the first step on the way to demonstrating the economical feasibility for the recovery of biophenols from agrifood wastes through a whole crop approach in a sustainable biorefining process.
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A fundamental assumption for by-product from winery industy waste-management is their economic and commercial increase in value. High energetic value recovery from winery industry is an attractive economic solution to stimulate new sustainable process. Approach of this work is based about physic and biological treatment with grape stalks and grape marc to increase polysaccharides components of cell wall and energetic availability of this by-products. Grape stalks for example have a high percentage of lignin and cellulose and can’t be used, whitout pretreatment, for an anaerobic digestion process. Our findings show enzymatic and thermo-mechanical pre-treatments in combined application for optimise hydrolytic mechanism on winemaking wastes which represents 0,9 milion ton/year in Italy and on straw, cereal by-products with high lignin content. A screening of specifically industrial enzymatic complex for the hydrolysis lignocellulosic biomass were tested using the principal polysaccharides component of the vegetal cells. Combined thermo-mechanical and enzymatic pretreatment improve substrates conversion in batch test fermentation experiment. The conservation of the grape stalks, at temperature above 0°C, allow the growth of spontaneus fermentation that reduce their polysaccharides content so had investigated anarobic condition of conservation. The other objective of this study was to investigate the capability of a proprietary strain of L.buchneri LN 40177 to enhance the accessibility of fermentable forage constituents during the anaerobic conservation process by releasing the enzyme ferulate esterase. The time sequence study by batch tests showed that the L. buchneri LN-40177 inoculated grape stalk substrate was more readily available in the fermenter. In batch tests with grape stalk, after mechanical treatment, the L. buchneri LN41077 treated substrate yielded on average 70% more biogas per kg/DM. Thermo-mechanical, enzymatic and biological treatment with L. buchneri LN-40177 can increase the biogas production from low fermented biomasses and the consequent their useful in anaerobic biodigesters for agro-bioenergy production.
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Discurso inaugural del VII Congreso Latinoamericano y del Caribe de Bioética de la Federación Latinoamericana y del Caribe de Instituciones de Bioética (FELAIBE), en la ciudad de Mendoza, 22 de junio de 2009.
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In this article an index decomposition methodology is used to estimate the effect of intersectorial and intrasectorial changes in explaining the 38% reduction in industrial energy intensity in the Basque Autonomous Community from 1982 to 2001. Period-wise additive decomposition results show that (1) the decline is fully explained by intrasectorial changes and that (2) intersectorial changes have not contributed to reduce but to increase the energy intensity of the Basque industrial sector. However, timeseries decomposition analysis shows that (1) four different phases can be distinguished in the evolution of energy intensity of the Basque industry from 1982 to 2001 and (2) that the evolution of the “Iron and Steel” sector is determinant when explaining those phases. Moreover, the analysis stresses the necessity to disaggregate the “Iron and Steel” sector in order to be able to distinguish purely technological effects from the rest of intrasectorial changes.
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[ES] El presente trabajo tiene por objeto el estudio del nivel de endeudamiento, el coste de la deuda y las rentabilidades de la industria del calzado de la Comunidad Autónoma de La Rioja por sectores y tamaños. De acuerdo con la Economía Industrial, que considera el sector de actividad como el principal determinante de los resultados de las organizaciones, se analiza si las variables estudiadas son distintas en función de su pertenencia al sector del calzado en comparación con el de la industria agroalimentaria, por ser éste el más importante de la economía de la región. Por otro lado, de acuerdo con la Teoría de los Recursos y Capacidades, que considera que son los factores internos los que explican las diferentes rentabilidades, estudiaremos un recurso interno como es el tamaño, viendo su influencia sobre las variables comentadas. Por último, los resultados del estudio conjunto de la pertenencia a un sector de actividad por tamaños homogéneos nos permiten afirmar que el coste de la deuda de las pequeñas empresas es significativamente distinto en función de dicho sector de pertenencia.
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573 p.: graf.
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[ES] Este trabajo propone una serie de factores como determinantes del nivel de expansión internacional de la industria vitivinícola chilena: i) tamaño de la empresa; ii) gestión de la calidad; iii) tecnologías de la información y la comunicación; iv) planificación de la gestión internacional, y finalmente, v) adaptación de la estrategia de marketing internacional. El contraste empírico sobre la base de datos de exportación de la industria vitivinícola chilena entre los años 2004 y 2007, permitió confirmar seis de las siete hipótesis planteadas. Este estudio concluye con un apartado destinado a resumir las principales contribuciones teóricas y prácticas, así como las limitaciones y futuras líneas de investigación.
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[ES] La necesidad de determinar los requerimientos del cliente y satisfacerlos se ha convertido en el principal objetivo de las empresas. Gestionar esa actividad, comúnmente asociada al departamento de marketing, ha llegado a ser el fin de cualquier sistema de calidad, y por ende, del resto de departamentos de la organización. A través de un estudio de casos, este trabajo pretende identificar cuales son las prácticas de marketing habituales en la industria del mueble, y plantear un marco de actuación idóneo de acuerdo con los procedimientos establecidos en las normas de calidad ISO 9000:2000.
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[ES] El sector de la construcción tiene, en España, una notable importancia, por su aportación al PIB (del entorno del 10%) y al empleo (en torno al 10%) y porque aglutina un amplio tejido empresarial. El deterioro de la situación económica y la saturación del mercado residencial han llevado a una fuerte contracción de la actividad constructiva, después una larga época de crecimiento.
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[ES] Las redes virtuales de fabricación global (RVFGs) están formadas por empresas independientes las cuales establecen entre sí relaciones de tipo horizontal y vertical, pudiendo incluso ser competidores, donde no es necesario mantener internamente grandes recursos fabriles sino gestionar y compartir eficientemente los recursos de la red.
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Notas sobre las condiciones de la pesca, economía pesquera y comentarios adiciones durante la excursión realizada por Lahille durante setiembre a octubre de 1895, a localidades marítimas y cuerpos de agua dulce de la provincia de Buenos Aires.
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Documento com duas páginas-de-rosto, em português e francês. Título em francês : Rapport présenté a Son Ex. M. le Ministre de l'Industrie, de la Voirie et des Travaux Publics
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La investigación contable más reciente defiende el comportamiento “pegadizo” de los costos, es decir su reacción no proporcional ante variaciones en el nivel de actividad. El presente estudio replica el modelo de Anderson, Banker y Janakiraman (2003) sobre una muestra de empresas españolas (sector industrial del mueble y sector de hostelería y restauración)y comprueba que los costos aumentan un 0,92% cuando las ventas lo hacen en un 1%, y disminuyen un 0,82% ante un declinamiento del 1% de las ventas. Se comprueba así que su magnitud está en línea con la hipótesis de la teoría de los costos pegadizos. Además, se demuestra la idoneidad del modelo en su aplicación a diferentes muestras de empresas, independientemente del sector de actividad de pertenencia.
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Trata-se do "Relatório Cruls", referente à 1ª Missão Cruls (1892-1893), durante o governo Floriano Peixoto