Estudo da sismicidade na barragem do Açu no período de 2012 a 2013

The seismic activity in the Northeastern of Brazil has been a constant target of study, since it is the most active region of the country. However, some areas have their earthquakes related to human action, what means they are induced. The Açu dam is a classic example of reservoir-induced seismicity and it has been the subject of several studies. Recently, after a considerable period of inactivity, the LabSis / UFRN recorded events related to the dam, which led to the installation of a network around the reservoir. From the data provided by this network, it was observed that the seismic activity is related to a new epicental area inside the lake. The epicentral parameters and the focal mechanism were determined. It was found that the events were related to the reactivation of a basement structure in a new seismogenic subvertical fault with NE-SW-striking subparallel to the São Rafael Fault. These results were used in the preparation of a scientific paper, which discussed the relationship between this seismicity with the geology of the region and with the reservoir water level. The paper showed that the diffusion of pore pressure was the main mechanism that controlled the triggering of the induced seismicity at the reservoir.

Estudo da sismicidade na barragem do Açu no período de 2012 a 2013

The seismic activity in the Northeastern of Brazil has been a constant target of study, since it is the most active region of the country. However, some areas have their earthquakes related to human action, what means they are induced. The Açu dam is a classic example of reservoir-induced seismicity and it has been the subject of several studies. Recently, after a considerable period of inactivity, the LabSis / UFRN recorded events related to the dam, which led to the installation of a network around the reservoir. From the data provided by this network, it was observed that the seismic activity is related to a new epicental area inside the lake. The epicentral parameters and the focal mechanism were determined. It was found that the events were related to the reactivation of a basement structure in a new seismogenic subvertical fault with NE-SW-striking subparallel to the São Rafael Fault. These results were used in the preparation of a scientific paper, which discussed the relationship between this seismicity with the geology of the region and with the reservoir water level. The paper showed that the diffusion of pore pressure was the main mechanism that controlled the triggering of the induced seismicity at the reservoir.

Globalização da agricultura e concentração fundiária no município de Ipanguaçu-RN

This research talks about the insertion of the borough Ipanguaçu-RN on the agricultural globalization process from 1979 to 2003. At the first moment (1979-1992) with the construction of the Açu´s barrage and the entry of agricultural national enterprises and secondly (1993-2003) with the entry of the multinational Del Monte Fresh Produce enterprise. During all this insertion period the impacts on the local land market. To make the research operational, it was tried to analyze documents of the local registry office and all the local, national and international bibliography about this issue during all the study period. Furthermore, interviews were made. At the ending of this thesis, the results show intensification of the agricultural capitalization on this borough, changing of the productive axis which heads to the external market and the land concentration of this borough. It was concluded that the insertion of this borough in the globalization system will increase the external intervention on Ipanguaçu blocking, then, the access if the local population to the land

Análise do fluxo d’água na barragem Engenheiro Armando Ribeiro Gonçalves - Açu/RN

The solution of partial differential equation of seepage problems is difficult to find analytically, especially for situations that involve great complexity. To overcome this problem, software based on finite differences and finite elements are usually used. This work presents the use of a finite element software, the GEO5, to solve the seepage problem at a dam of very complex section, the dam Eng. Armando Ribeiro Gonçalves, which at the end of its construction suffered rupture of the upstream slope at the central dam and then went through a process of reconstruction and auscultation. The analyses were performed for the operating condition of the reservoir, with an established flow. A numerical model was developed based on the level readings of the reservoir water and their piezometric readings as a proposal for the evaluation and future behavior prediction of the dam on established flow conditions. The use of constitutive models with the aid of computer systems is reflected in a way to predict future risk situations so they can be prevented

Sauvegarde et mise en valeur des sites d'art rupestre et archeologiques : les cas des sites de la vallee du Côa au Portugal et de Markoye au Burkina fase

O Vale do Côa em Portugal, que «ninguém havia situado numa carta», adquiriu renome internacional após suspensão da construção de uma barragem; suspensão essa provocada pela descoberta de gravuras rupestres que foram preservadas, valorizadas e classificadas como Património Mundial da UNESCO. Markoye, no Burkina Faso, esconde uma riqueza de sítios de arte rupestre que não se pode negligenciar. No entanto, apesar de não valorizado e desconhecido do grande público, este monumento oferece um elevado potencial de exploração patrimonial caminhando no sentido do desenvolvimento local. Através do Vale do Côa e de Markoye, este texto expõe simultaneamente os problemas e o interesse de que é preciso preservar e valorizar o produto arqueológico em geral e a arte rupestre em particular, reconhecida como um dos testemunhos mais antigos e mais poderosos da comunicação visual. A experiência portuguesa serve como fonte de inspiração para colocar em prática o projecto de valorização do monumento burkinabé.

Galvanic replacement mediated transformation of Ag nanospheres into dendritic Au--Ag nanostructures in the ionic liquid [BMIM][BF4]

We demonstrate an unusual shape transformation of Ag nanospheres into {111}-oriented Au–Ag dendritic nanostructures by a galvanic replacement reaction in the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]).

Galvanic Replacement of Semiconductor Phase I CuTCNQ Microrods with KAuBr4 to Fabricate CuTCNQ/Au Nanocomposites with Photocatalytic Properties

In this study, the reaction of semiconductor microrods of phase I copper 7,7,8,8-tetracyanoquinodimethane (CuTCNQ) with KAuBr4 in acetonitrile is reported. It was found that the reaction is redox in nature and proceeds via a galvanic replacement mechanism in which the surface of CuTCNQ is replaced with metallic gold nanoparticles. Given the slight solubility of CuTCNQ in acetonitrile, two competing reactions, namely CuTCNQ dissolution and the redox reaction with KAuBr4, were found to operate in parallel. An increase in the surface coverage of CuTCNQ microrods with gold nanoparticles occurred with an increased KAuBr4 concentration in acetonitrile, which also inhibited CuTCNQ dissolution. The reaction progress with time was monitored using UV−visible, FT-IR, and Raman spectroscopy as well as XRD and EDX analysis, and SEM imaging. The CuTCNQ/Au nanocomposites were investigated for their photocatalytic properties, wherein the destruction of Congo red, an organic dye, by simulated solar light was found dependent on the surface coverage of gold nanoparticles on the CuTCNQ microrods. This method of decorating CuTCNQ may open the possibility of modifying this and other metal-TCNQ charge transfer complexes with a host of other metals which may have significant applications.

Synthesis of CuTCNQ/Au microrods by galvanic replacement of semiconducting phase I CuTCNQ with KAuBr4 in aqueous medium

The spontaneous reaction between microrods of an organic semiconductor molecule, copper 7,7,8,8-tetracyanoquinodimethane (CuTCNQ) with [AuBr4]− ions in an aqueous environment is reported. The reaction is found to be redox in nature which proceeds via a complex galvanic replacement mechanism, wherein the surface of the CuTCNQ microrods is replaced with metallic gold nanoparticles. Unlike previous reactions reported in acetonitrile, the galvanic replacement reaction in aqueous solution proceeds via an entirely different reaction mechanism, wherein a cyclical reaction mechanism involving continuous regeneration of CuTCNQ consumed during the galvanic replacement reaction occurs in parallel with the galvanic replacement reaction. This results in the driving force of the galvanic replacement reaction in aqueous medium being largely dependent on the availability of [AuBr4]− ions during the reaction. Therefore, this study highlights the importance of the choice of an appropriate solvent during galvanic replacement reactions, which can significantly impact upon the reaction mechanism. The reaction progress with respect to different gold salt concentration was monitored using Fourier transform infrared (FT-IR), Raman, and X-ray photoelectron spectroscopy (XPS), as well as XRD and EDX analysis, and SEM imaging. The CuTCNQ/Au nanocomposites were also investigated for their potential photocatalytic properties, wherein the destruction of the organic dye, Congo red, in a simulated solar light environment was found to be largely dependent on the degree of gold nanoparticle surface coverage. The approach reported here opens up new possibilities of decorating metal–organic charge transfer complexes with a host of metals, leading to potentially novel applications in catalysis and sensing.

Formation of nanostructured porous Cu-Au surfaces : the influence of cationic sites on (electro)-catalysis

The fabrication of nanostructured bimetallic materials through electrochemical routes offers the ability to control the composition and shape of the final material that can then be effectively applied as (electro)-catalysts. In this work a clean and transitory hydrogen bubble templating method is employed to generate porous Cu–Au materials with a highly anisotropic nanostructured interior. Significantly, the co-electrodeposition of copper and gold promotes the formation of a mixed bimetallic oxide surface which does not occur at the individually electrodeposited materials. Interestingly, the surface is dominated by Au(I) oxide species incorporated within a Cu2O matrix which is extremely effective for the industrially important (electro)-catalytic reduction of 4-nitrophenol. It is proposed that an aurophilic type of interaction takes place between both oxidized gold and copper species which stabilizes the surface against further oxidation and facilitates the binding of 4-nitrophenol to the surface and increases the rate of reaction. An added benefit is that very low gold loadings are required typically less than 2 wt% for a significant enhancement in performance to be observed. Therefore the ability to create a partially oxidized Cu–Au surface through a facile electrochemical route that uses a clean template consisting of only hydrogen bubbles should be of benefit for many more important reactions.

Exploiting the facile oxidation of evaporated gold films to drive electroless silver deposition for the creation of bimetallic Au/Ag surfaces

Gold is often considered as an inert material but it has been unequivocally demonstrated that it possesses unique electronic, optical, catalytic and electrocatalytic properties when in a nanostructured form.[1] For the latter the electrochemical behaviour of gold in aqueous media has been widely studied on a plethora of gold samples, including bulk polycrystalline and single-crystal electrodes, nanoparticles, evaporated films as well as electrodeposited nanostructures, particles and thin films.[1b, 2] It is now well-established that the electrochemical behaviour of gold is not as simple as an extended double-layer charging region followed by a monolayer oxide-formation/-removal process. In fact the so-called double-layer region of gold is significantly more complicated and has been investigated with a variety of electrochemical and surface science techniques. Burke and others[3] have demonstrated that significant processes due to the oxidation of low lattice stabilised atoms or clusters of atoms occur in this region at thermally and electrochemically treated electrodes which were confirmed later by Bond[4] to be Faradaic in nature via large-amplitude Fourier transformed ac voltammetric experiments. Supporting evidence for the oxidation of gold in the double-layer region was provided by Bard,[5] who used a surface interrogation mode of scanning electrochemical microscopy to quantify the extent of this process that forms incipient oxides on the surface. These were estimated to be as high as 20% of a monolayer. This correlated with contact electrode resistance measurements,[6] capacitance measurements[7] and also electroreflection techniques...