Ab initio studies on the tri- and diphosphate fragments of adenosine triphosphate

Pyrophosphate prototypes such as methyl triphosphate and methyl diphosphate molecules in their different protonation states have been investigated at high levels of quantum chemical calculations. The optimized geometries, the thermochemistry of the hydrolysis and the molecular orbitals contributing to the high energy of these compounds have been analyzed. These investigations provide insights into the ``high energy'' character of ATP molecule. Further, the dependence of vibrational frequencies on the number of phosphate groups and the charged states has also been presented. These results can aid the interpretation of spectra obtained by experiments on complexes containing pyrophosphate prototypes. (c) 2005 Elsevier B.V. All rights reserved.

一种开放混合实时系统的开放自适应调度算法

开放计算环境下的实时与非实时任务不确定并发,以及多种实时约束混合的复杂约束系统,即开放混合实时系统的需求越来越广泛.通过引入接收控制、调度服务器、自适应调节机制,提出一种开放环境下的自适应实时系统调度架构——OARtS(open adaptive real-time scheduling).它能适应开放计算环境的不确定性,有控制地接受实时任务运行;可根据系统空闲计算带宽变化,自适应地调节任务的实时等级,使得系统运行在最优的实时性能上;对于软实时任务,可根据其计算带宽需求变化,自适应地调节其计算带宽分配,以适应任务执行时间时变引起的实时不确定性.

Fine structure of alpha decay to rotational states of heavy nuclei

To gain a better insight into alpha-decay fine structure, we calculate the relative intensities of alpha decay to 2(+) and 4(+) rotational states in the framework of the generalized liquid drop model (GLDM) and improved Royer's formula. The calculated relative intensities of a decay to 2(+) states are in good agreement with the experimental data. For the relative intensities of alpha decay to 4(+) states, a good agreement with experimental data is achieved for Th and U isotopes. The formula we obtain is useful for the analysis of experimental data of alpha-decay fine structure. In addition, some predicted relative intensities which are still not measured are provided for future experiments.

La colaboración y la cooperación asistida por ordenador en la didáctica de las matemáticas.

Resumen tomado del autor

Possible effects of sodium chloride treatment on quality of effluents from Alabama channel Catfish ponds

Channel catfish ponds are treated with salt (sodium chloride) to increase chloride concentration and prevent nitrite toxicity in fish. A survey indicated that most farmers try to maintain chloride concentration of 50 to 100 mg/L in ponds by annual salt applications. Averages and standard deviations for selected water quality variables in salt-treated ponds were as follows: chloride, 87.2 ± 37.5 mg/L; total dissolved solids (TDS), 336 ± 96 mg/L; specific conductance, 512 ± 164 μmhos/cm. Maximum values were 189 mg/L for chloride, 481 mg/L for TDS, and 825 μmhos/cm for specific conductance. Good correlations between specific conductance values and both chloride and TDS concentrations suggest that specific conductance can be a rapid method for estimating concentrations of these two variables in surface water. The maximum limit for chloride concentration in Alabama streams allowed by the Alabama Department of Environmental Management is 230 mg/L. The usual recommended upper limit of TDS for protection of aquatic life in freshwater streams is 1,000 mg/L. Based on the observed relationship between TDS concentration and specific conductance in Alabama catfish ponds, 1,000 mg/L TDS corresponds to 1,733 μmhos/cm specific conductance. It is unlikely that effluents from salt-treated catfish ponds would violate the in-stream chloride standard of 230 mg/L or harm aquatic life in streams. Nevertheless, chloride concentrations in ponds should be measured before salt application as a safe guard against excessive salt application and chloride concentrations above the in-stream chloride standard.

Flashlight Europe N°2–February 2015. “Europe must now get involved in a very big way”

More than three years after al-Gaddafi was overthrown, Libya has still not returned to some semblance of normality. In many places, the Libyan state exists only on paper. No less than two governments and dozens of rival tribes, all with their own militias and armed to the teeth, are trying to come to power. In the midst of this chaos “IS,” the terrorist organization, has now entered the fray. Evidence of this is provided by the brutal murder of 21 Egyptian Copts, which could trigger off a civil war that will pose a threat to the entire region and to Europe. Mirco Keilberth, an expert on Libya, explains what is going on.