73 resultados para 15B


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We report the discovery of a low-density exoplanet transiting an 11th magnitude star in the Southern hemisphere. WASP-15b, which orbits its host star with a period P = 3.7520656 ± 0.0000028 d, has a mass M p = 0.542 ± 0.050 M J and radius R p = 1.428 ± 0.077 R J, and is therefore one of the least dense transiting exoplanets so far discovered (?p = 0.247 ± 0.035 g cm-3). An analysis of the spectrum of the host star shows it to be of spectral type around F5, with an effective temperature T eff = 6300 ± 100 K and [Fe/H] = -0.17 ± 0.11.

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Rearrangement of a homobrendane derivative 8a to perhydro-1,4-methanoindenesy stem 9a could be brought about either by p-toluenesulfonic acid or boron trifluoride etherate. Similarly, rearrangement of 8b-d led to the formation of perhydro-1,4-methanoindened erivatives 9b-d. On the basis of the location of substituents in the starting material and the product, a probable mechanistic pathway has been suggested. The appropriate modification of the peripheral functionalities in 9 led to efficient total syntheses of (f)-copacamphor (15a),(f)-ylangocamphor (16a), and their homologues 15b and 16b.