998 resultados para 13627-011


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This series of research vignettes is aimed at sharing current and interesting research findings from our team and other international researchers. In this vignette, Dr Martie-Louise Verreynne from the University of Queensland Business School summarises the findings from a paper written in conjunction with Sarel Gronum, that examines how much innovation is enough and does it really matter. They found that innovation does matter, however careful consideration of the innovation - performance relationship is important.

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C 15H 1602 (a synthetic precursor to dodecahedrane), monoclinic, P21/n, a = 12.171 (5), b = 6.976(5), c = 13.868 (3) A, B = 102.56 (3) ° , Z = 4, D m = 1.30, D c = 1.318 g cm -3, F(000) = 488, g(Mo K¢t) = 0.92 cm- 1. Intensity data were collected on a Nonius CAD-4 diffractometer and the structure was solved by direct methods. Full-matrix least-squares refinement gave R = 0.077 (R w = 0.076) for 1337 observed reflections. All the five-membered rings are cis fused and have envelope (C s symmetry) conformations.

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O presidente da Assembleia Nacional Constituinte (ANC) Ulysses Guimarães (PSDB-SP) preside a cerimônia em homenagem ao segundo aniversário de morte de Tancredo Neves. Imagem de Risoleta Neves, esposa de Tancredo Neves, em plenário. O Deputado Pimenta da Veiga (PMDB-MG) discursa em nome do PMDB. O Deputado Aécio Neves (PMDB-MG) agradece a homenagem póstuma ao avô. As três Subcomissões da Educação, Cultura e Esportes; da Ciência e da Comunicação; da Família, do Menor e do Idoso que fazem parte da Comissão da Família, Educação e Cultura, Esporte, Ciência e Tecnologia e da Comunicação reuniram-se para tratar de questões como o livro didático, a destinação de verbas governamentais para o ensino público e privado e da educação pré-escolar. O Senador João Calmon (PMDB-ES) acredita numa projeção da educação. A Subcomissão da Família, do Menor e do Idoso recebeu Comba Marques Porto, representante do Conselho dos Direitos da Mulher, que relatou sobre a natureza da sociedade conjugal. A Deputada Rita Camata (PMDB-ES), em entrevista, aborda também a questão da sociedade conjugal. O Ministro Chefe da Casa Civil, Marco Maciel, esteve presente na Subcomissão do Poder Executivo.

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Recent measurements on dendrochronologically-dated wood from the Southern Hemisphere have shown that there are differences between the structural form of the radiocarbon calibration curves from each hemisphere. Thus, it is desirable, when possible, to use calibration data obtained from secure dendrochronologically-dated wood from the corresponding hemisphere. In this paper, we outline the recent work and point the reader to the internationally recommended data set that should be used for future calibration of Southern Hemisphere 14C dates.

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Dark brown sediment with clasts ranging from small to large in size. Clast shape ranges from angular to sub-rounded. Rotation structures are common throughout the sample. They can mainly be seen surrounding clasts of all sizes. Lineations and comet structures are also abundant. Minor amounts of grain stacking/crushing can also be seen.

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High purity Al single crystals of the (011)[011] orientation have been deformed in plane strain compression in a channel die. Deformation was carried out at a strain rate of 0.01 s−1 to true strains of 0.5 and 1.0, and at temperatures of 25, 200 and 300 °C. The as-deformed microstructure has been characterized using electron backscattered diffraction (EBSD) and X-ray diffraction (XRD). No recrystallization was detected after deformation, and the deformation texture analysis showed that the stability of the orientation decreased with increasing temperature, contrary to reports for other orientations.

Annealing was carried out for various times at 300 °C. Nucleation of recrystallization exhibited periodicity, with distinct bands of recrystallized grains forming parallel to the transverse direction. This recrystallized microstructure has been examined using EBSD. A model is proposed to account for the origin of the periodicity of nucleation and the retention of rods or cylinders of unrecrystallized material after significant annealing times.

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Atomistic simulations of molecular adsorption onto inorganic substrates under aqueous conditions can be used to guide the rational design of new materials, fabricated using biomimetic methods. The success of such work depends critically on the model used. Here, we investigate the impact of using a rigid structural model of the (0 1 1) ?-quartz surface, over a fully flexible model, on the calculated free energy change in the adsorption of a single molecule of benzene (a simple analogue of the amino acid phenylalanine) from liquid water. Subtle differences in the mobility of the adsorbate close to the surface result in the free energy of adsorption being overestimated by the rigid model, relative to the fully flexible case. Moreover, we find that the distribution of bound configurations of the adsorbate at their respective free energy minima is different between the two models.

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OBJECTIVE Little information is available on the early course of hypertension in type 1 diabetes. The aim of our study, therefore, was to document circadian blood pressure profiles in patients with a diabetes duration of up to 20 years and relate daytime and nighttime blood pressure to duration of diabetes, BMI, insulin therapy, and HbA1c. RESEARCH DESIGN AND METHODS Ambulatory profiles of 24-h blood pressure were recorded in 354 pediatric patients with type 1 diabetes (age 14.6 +/- 4.2 years, duration of diabetes 5.6 +/- 5.0 years, follow-up for up to 9 years). A total of 1,011 profiles were available for analysis from patients not receiving antihypertensive medication. RESULTS Although daytime mean systolic pressure was significantly elevated in diabetic subjects (+3.1 mmHg; P < 0.0001), daytime diastolic pressure was not different from from the height- and sex-adjusted normal range (+0.1 mmHg, NS). In contrast, both systolic and diastolic nighttime values were clearly elevated (+7.2 and +4.2 mmHg; P < 0.0001), and nocturnal dipping was reduced (P < 0.0001). Systolic blood pressure was related to overweight in all patients, while diastolic blood pressure was related to metabolic control in young adults. Blood pressure variability was significantly lower in girls compared with boys (P < 0.01). During follow-up, no increase of blood pressure was noted; however, diastolic nocturnal dipping decreased significantly (P < 0.03). Mean daytime blood pressure was significantly related to office blood pressure (r = +0.54 for systolic and r = +0.40 for diastolic pressure); however, hypertension was confirmed by ambulatory blood pressure measurement in only 32% of patients with elevated office blood pressure. CONCLUSIONS During the early course of type 1 diabetes, daytime blood pressure is higher compared with that of healthy control subjects. The elevation of nocturnal values is even more pronounced and nocturnal dipping is reduced. The frequency of white-coat hypertension is high among adolescents with diabetes, and ambulatory blood pressure monitoring avoids unnecessary antihypertensive treatment.