Uranium chemistry of oceanic basalts

Measurements of uranium concentration and the 234U/238 U activity ratio in oceanic basalts which have undergone low-temperature seafloor alteration indicate that uranium uptake is a pervasive occurrence but that the various phases involved behave differently with respect to this process. Palagonite exhibits uranium contents 8-20 times higher than unaltered glass coupled with low 234U/238U, suggesting ongoing preferential leaching of 234U. Altered crystalline interiors of several old basalts have 234U/238U > 1, indicative of recent uranium exchange with seawater. The data also provide evidence for uranium sources with 234U/238U higher than the seawater value of 1.14. Manganese crusts on basalts of a variety of ages have isotopic ratios indicating that they either are recent deposits or also have experienced continuing uranium exchange with seawater.

Positronium impact excitation of hydrogen molecule to B-1 Sigma(+)(u) and b(3)Sigma(+)(u) states

Calculation for the electronic excitation of the ground state of H-2 to B (1) Sigma(u)(+) and b(3) Sigma(u)(+) states by positronium- (Ps) atom impact has been carried out using the first Born approximation considering discrete Ps excitations up to n = 6 and Ps ionization in the final state. To include the effect of electron exchange, we propose an alternative approximation scheme in the light of the Rudge approach, which takes into account the composite nature of the Ps-atom projectile.

The GEOTRACES Intermediate Data Product 2014

The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEls) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-sigma data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes.

Stochastic Simulations Suggest that HIV-1 Survives Close to Its Error Threshold

The use of mutagenic drugs to drive HIV-1 past its error threshold presents a novel intervention strategy, as suggested by the quasispecies theory, that may be less susceptible to failure via viral mutation-induced emergence of drug resistance than current strategies. The error threshold of HIV-1, mu(c), however, is not known. Application of the quasispecies theory to determine mu(c) poses significant challenges: Whereas the quasispecies theory considers the asexual reproduction of an infinitely large population of haploid individuals, HIV-1 is diploid, undergoes recombination, and is estimated to have a small effective population size in vivo. We performed population genetics-based stochastic simulations of the within-host evolution of HIV-1 and estimated the structure of the HIV-1 quasispecies and mu(c). We found that with small mutation rates, the quasispecies was dominated by genomes with few mutations. Upon increasing the mutation rate, a sharp error catastrophe occurred where the quasispecies became delocalized in sequence space. Using parameter values that quantitatively captured data of viral diversification in HIV-1 patients, we estimated mu(c) to be 7 x 10(-5) -1 x 10(-4) substitutions/site/replication, similar to 2-6 fold higher than the natural mutation rate of HIV-1, suggesting that HIV-1 survives close to its error threshold and may be readily susceptible to mutagenic drugs. The latter estimate was weakly dependent on the within-host effective population size of HIV-1. With large population sizes and in the absence of recombination, our simulations converged to the quasispecies theory, bridging the gap between quasispecies theory and population genetics-based approaches to describing HIV-1 evolution. Further, mu(c) increased with the recombination rate, rendering HIV-1 less susceptible to error catastrophe, thus elucidating an added benefit of recombination to HIV-1. Our estimate of mu(c) may serve as a quantitative guideline for the use of mutagenic drugs against HIV-1.

Geochemistry and paleontology of sediment core GeoB3359-3

A geochemical and paleontological reconstruction of paleoproductivity, upwelling intensity and sea surface temperature (SST) off central Chile at 35°S (GeoB3359-3) reveals marked changes from the Last Glacial Maximum (LGM) through the Early Holocene. Surface-water productivity was determined by the interaction between the atmospheric (the Southern Westerlies) and oceanographic (the Antarctic Circumpolar Current, ACC) systems from the LGM through early Termination I (TI). The northward shift of the climate zones during the LGM brought the ACC, as the main macronutrient source, closer to the GeoB3359-3, SST lowered, and surface water productivity and accumulation rates of biogenic components enhanced. With the poleward return of the Southern Westerlies and the ACC, the subtropical high-pressure system became the dominant atmospheric component southward till 35°S during the late TI and Early Holocene and caused surface water productivity to increase through enhanced upwelling.

Fission track age determinations of rocks from north Greenland

Apatite fission track (FT) ages and length characteristics of samples obtained from Cambrian to Paleocene-aged sandstones collected along the margin of Nares Strait in Ellesmere Island in the Canadian Arctic Archipelago are dominated by a thermal history related to Paleogene relative plate movements between Greenland and Ellesmere Island. A preliminary inverse FT thermal model for a Cambrian (Archer Fiord Formation) sandstone in the hanging wall of the Rawlings Bay thrust at Cape Lawrence is consistent with Paleocene exhumational cooling, likely as a result of erosion of the thrust. This suggests that thrusting at Cape Lawrence occurred prior to the onset of Eocene compression, likely due to transpression during earlier strikeslip along the strait. Models for samples from volcaniclastic sandstones of the Late Paleocene Pavy Formation (from Cape Back and near Pavy River), and a sandstone from the Late Paleocene Mount Lawson Formation (at Split Lake, near Makinson Inlet) are also consistent with minor burial heating following known periods of basaltic volcanism in Baffin Bay and Davis Strait (c. 61-59 Ma), or related tholeiitic volcanism and intrusive activity (c. 55-54 Ma). Thermal models for samples from sea level dykes from around Smith Sound suggest a period of Late Cretaceous - Paleocene heating prior to final cooling during Paleocene time. These model results imply that Paleocene tectonic movements along Nares Strait were significant, and provide limited support for the former existence of the Wegener Fault. Apatite FT data from central Ellesmere Island suggest however, that cooling there occurred during Early Eocene time (c. 50 Ma), which was likely a result of erosion of thrusts during Eurekan compression. This diachronous cooling suggests that Eurekan deformation was partitioned at discrete intervals across Ellesmere Island, and thus it is likely that displacements along the strait were much less than the 150 km that has been previously suggested for the Wegener Fault.

Controls of sediment dynamics on the Galician slope reconstructed from three sediment cores (GeoB11035-1, GeoB130206-1, GeoB13071-1)

Controls of sediment dynamics at the Galician continental slope (NW Iberia) during the past 30 ka were reconstructed from three new gravity cores (GeoB11035-1, 130206-1, 13071-1) based on sedimentological (e.g. sortable silt, IRD), micropalaeontological (e.g. coccoliths), geochemical (AMS 14C, XRF) and geophysical (e.g. magnetic susceptibility) diagnostics. The data are consistent with existing regional knowledge that, during marine isotope stages 3-1, variations in detrital input, marine productivity and sea level were the essential drivers of sediment availability on the slope, whereas deep-water current velocities controlled sediment deposition: (1) the period prior to 30 cal ka BP is characterized by minor but systematic variations in various proxies which can be associated with D-O cycles; (2) between 30 and 18 cal ka BP, high detrital input and steady slope-parallel currents led to constant sedimentation; (3) from the LGM until 10 cal ka BP, the shelf-transgressive sea-level rise increased the detrital particle flux; sedimentation was influenced by significantly enhanced deep-water circulation during the Bølling/Allerød, and subsequent slowing during the Younger Dryas; (4) an abrupt and lasting change to hemipelagic sedimentation at ca. 10 cal ka BP was probably due to Holocene warming and decelerated transgression; (5) after 5 cal ka BP, additional input of detrital material to the slope is plausibly linked to the evolution of fine-grained depocentres on the Galician shelf, this being the first report of this close shelf-slope sedimentary linkage off NW Iberia. Furthermore, there is novel evidence of the nowadays strong outer shelf Iberian Poleward Current becoming established at about 15.5 cal ka BP. The data also demonstrate that small-scale morphologic features and local pathways of sediment export from the neighbouring shelf play an important role for sediment distribution on the NW Iberian slope, including a hitherto unknown sediment conduit off the Ría de Arousa. By implication, the impact of local morphology on along- and down-slope sediment dynamics is more complex than commonly considered, and deserves future attention.

Chronology and petrology in MIS4-2 of DSDP Site 94-609

Ice-rafting evidence for a '1500-year cycle' sparked considerable debate on millennial-scale climate change and the role of solar variability. Here, we reinterpret the last 70,000 years of the subpolar North Atlantic record, focusing on classic DSDP Site 609, in the context of newly available raw data, the latest radiocarbon calibration (Marine09) and ice core chronology (GICC05), and a wider range of statistical methodologies. A ~1500-year oscillation is primarily limited to the short glacial Stage 4, the age of which is derived solely from an ice flow model (ss09sea), subject to uncertainty, and offset most from the original chronology. Results from the most well-dated, younger interval suggest that the original 1500 ± 500 year cycle may actually be an admixture of the ~1000 and ~2000 cycles that are observed within the Holocene at multiple locations. In Holocene sections these variations are coherent with 14C and 10Be estimates of solar variability. Our new results suggest that the '1500-year cycle' may be a transient phenomenon whose origin could be due, for example, to ice sheet boundary conditions for the interval in which it is observed. We therefore question whether it is necessary to invoke such exotic explanations as heterodyne frequencies or combination tones to explain a phenomenon of such fleeting occurrence that is potentially an artifact of arithmetic averaging.

Radiocarbon dating on cold-water corals, grain size, Corg, and benthic foraminfera assemblage of two sediment cores from the Ionian Sea

Continuous sedimentary records from an eastern Mediterranean cold-water coral ecosystem thriving in intermediate water depths (~600 m) reveal a temporary extinction of cold-water corals during the Early to Mid Holocene from 11.4-5.9 cal kyr BP. Benthic foraminiferal assemblage analysis shows low-oxygen conditions of 2 ml l**-1 during the same period, compared to bottom-water oxygen values of 4-5 ml l**-1 before and after the coral-free interval. The timing of the corals' demise coincides with the sapropel S1 event, during which the deep eastern Mediterranean basin turned anoxic. Our results show that during the sapropel S1 event low oxygen conditions extended to the rather shallow depths of our study site in the Ionian Sea and caused the cold-water corals temporary extinction. This first evidence for the sensitivity of cold-water corals to low oceanic oxygen contents suggests that the projected expansion of tropical oxygen minimum zones resulting from global change will threaten cold-water coral ecosystems in low latitudes in the same way that ocean acidification will do in the higher latitudes.

Sedimentation processes in the Mar del Plata Canyon (Southwest Atlantic) reconstructed from three sediment cores (GeoB13832-2, GeoB13833-2, GeoB13862-1)

The Mar del Plata Canyon is located at the continental margin off northern Argentina in a key intermediate and deep-water oceanographic setting. In this region, strong contour currents shape the continental margin by eroding, transporting and depositing sediments. These currents generate various depositional and erosive features which together are described as a Contourite Depositional System (CDS). The Mar del Plata Canyon intersects the CDS, and does not have any obvious connection to the shelf or to an onshore sediment source. Here we present the sedimentary processes that act in the canyon and show that continuous Holocene sedimentation is related to intermediate-water current activity. The Holocene deposits in the canyon are strongly bioturbated and consist mainly of the terrigenous "sortable silt" fraction (10-63 µm) without primary structures, similarly to drift deposits. We propose that the Mar del Plata Canyon interacts with an intermediate-depth nepheloid layer generated by the northward-flowing Antarctic Intermediate Water (AAIW). This interaction results in rapid and continuous deposition of coarse silt sediments inside the canyon with an average sedimentation rate of 160 cm/kyr during the Holocene. We conclude that the presence of the Mar del Plata Canyon decreases the transport capacity of AAIW, in particular of its deepest portion that is associated with the nepheloid layer, which in turn generates a change in the contourite deposition pattern around the canyon. Since sedimentation processes in the Mar del Plata Canyon indicate a response to changes of AAIW contour-current strength related to Late Glacial/Holocene variability, the sediments deposited within the canyon are a great climate archive for paleoceanographic reconstructions. Moreover, an additional involvement of (hemi) pelagic sediments indicates episodic productivity events in response to changes in upper ocean circulation possibly associated with Holocene changes in intensity of El Niño/Southern Oscillation.

Age model, raw data and interpolated raw data from proxy records of sediment cores GeoB6007-1 and GeoB6007-2

Here we present a 1200 yr long benthic foraminiferal Mg/Ca based temperature and oxygen isotope record from a ~900 m deep sediment core off northwest Africa to show that atmosphere-ocean interactions in the eastern subpolar gyre are transferred at central water depth into the eastern boundary of the subtropical gyre. Further we link the variability of the NAO (over the past 165 yrs) and solar irradiance (Late Holocene) and their control on subpolar mode water formation to the multidecadal variability observed at mid-depth in the eastern subtropical gyre. Our results show that eastern North Atlantic central waters cooled by up to ~0.8± 0.7 °C and densities decreased by Sigma theta=0.3±0.2 during positive NAO years and during minima in solar irradiance during the Late Holocene. The presented records demonstrate the sensitivity of central water formation to enhanced atmospheric forcing and ice/freshwater fluxes into the eastern subpolar gyre and the importance of central water circulation for cross-gyre climate signal propagation during the Late Holocene.

Analytical results from sediment core MD03-2698

It is well established that orbital scale sea-level changes generated larger transport of sediments into the deep-sea during the last glacial maximum than the Holocene. However, the response of sedimentary processes to abrupt millennial-scale climate variability is rather unknown. Frequency of distal turbidites and amounts of advected detrital carbonate are estimated off the Lisbon-Setúbal canyons, within a chronostratigraphy based on radiometric ages, oxygen isotopes and paleomagnetic key global anomalies. We found that: 1) Higher frequency of turbidites concurred with Northern Hemisphere coldest temperatures (Greenland Stadials [GS], including Heinrich [H] events). But more than that, an escalating frequency of turbidites starts with the onset of global sea-level rising (and warming in Antarctica) and culminates during H events, at the time when rising is still in its early-mid stage, and the Atlantic Meridional Overturning Circulation (AMOC) is re-starting. This short time span coincides with maximum gradients of ocean surface and bottom temperatures between GS and Antarctic warmings (Antarctic Isotope Maximum; AIM 17, 14, 12, 8, 4, 2) and rapid sea-level rises. 2) Trigger of turbidity currents is not the only sedimentary process responding to millennial variability; land-detrital carbonate (with a very negative bulk d18O signature) enters the deep-sea by density-driven slope lateral advection, accordingly during GS. 3) Possible mechanisms to create slope instability on the Portuguese continental margin are sea-level variations as small as 20 m, and slope friction by rapid deep and intermediate re-accommodation of water masses circulation. 4) Common forcing mechanisms appear to drive slope instability at both millennial and orbital scales.